The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Reactivity-Guided Interface Design in Na Metal Solid-State Batteries
Open accessAbstract
Solid-state batteries provide substantially increased safety and improved energy density when energy-dense alkali metal anodes are applied. However, most solid-state electrolytes react with alkali metals, causing a continuous increase of the cell impedance. Here, we employ a reactivity-driven strategy to improve the interfacial stability between a Na 3 SbS 4 solid-state electrolyte and sodium metal. First-principles calculations identify a protective hydrate coating for Na 3 SbS 4 that leads to the generation of passivating decomposition products upon contact of the electrolyte with sodium metal. The formation of this protective coating, a newly discovered hydrated phase, is achieved experimentally through exposure of Na 3 SbS 4 to air. The buried interface is characterized using post-operando synchrotron X-ray depth profiling, providing spatially resolved evidence of the multilayered phase distribution in the Na metal symmetric cell consistent with theoretical predictions. We identify hydrates as promising for improving the metal/electrolyte interfacial stability in solid-state batteries and suggest a general strategy of interface design for this purpose.
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Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
Jain, A., Ong, S. P., Hautier, G., Chen, W., Richards, W. D., Dacek, S., Cholia, S., Gunter, D., Skinner, D., Ceder, G., et al. (2013) · APL Materials · doi:10.1063/1.4812323 · Cited by 13,094
Self-citationPython Materials Genomics (pymatgen): A robust, open-source python library for materials analysis
Ong, S. P., Richards, W. D., Jain, A., Hautier, G., Kocher, M., Cholia, S., Gunter, D., Chevrier, V. L., Persson, K. A., & Ceder, G. (2013) · Computational Materials Science · doi:10.1016/j.commatsci.2012.10.028 · Cited by 4,534
Self-citationA solid future for battery development
Janek, J., & Zeier, W. G. (2016) · Nature Energy · doi:10.1038/nenergy.2016.141 · Cited by 3,979
Interface Stability in Solid-State Batteries
Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04082 · Cited by 1,652
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Cited by
Designing solid-state electrolytes for safe, energy-dense batteries
Zhao, Q., Stalin, S., Zhao, C.-Z., & Archer, L. A. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0165-5 · Cited by 2,372
Tian, Y., Zeng, G., Rutt, A., Shi, T., Kim, H., Wang, J., Koettgen, J., Sun, Y., Ouyang, B., Chen, T., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00767 · Cited by 1,614
Self-citationInterfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes
Banerjee, A., Wang, X., Fang, C., Wu, E. A., & Meng, Y. S. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00101 · Cited by 1,526
Huang, J., Wu, K., Xu, G., Wu, M., Dou, S., & Wu, C. (2023) · Chemical Society Reviews · doi:10.1039/d2cs01029a · Cited by 304
Chemo-Mechanical Challenges in Solid-State Batteries
Lewis, J. A., Tippens, J., Cortes, F. J. Q., & McDowell, M. T. (2019) · Trends in Chemistry · doi:10.1016/j.trechm.2019.06.013 · Cited by 257
Metadata
- Authors
- Tian, Y., Sun, Y., Hannah, D. C., Xiao, Y., Liu, H., Chapman, K. W., Bo, S.-H., & Ceder, G.
- Venue
- Joule
- Publisher
- Elsevier BV
- Published
- 2019-04
- Volume
- 3
- Issue
- 4
- Pages
- 1037-1050
- ISSN
- 2542-4351 (ISSN-L)
- OpenAlex
- W2913692887
- Cited by
- 172
- References
- 4
- FWCI
- 7.93
- Type
- journal article
- Language
- en
- Open access
- hybrid
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