The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
A General Method to Probe Oxygen Evolution Intermediates at Operating Conditions
Open accessAbstract
Summary Reducing high overpotential for the oxygen evolution reaction (OER) is an important challenge for the utilization of clean and renewable energy resources. An obstacle that badly impedes the design of efficient OER catalysts is the weak understanding of the oxygen intermediates. Because of the aqueous reaction environment of OER, direct detection of oxygen intermediates is very challenging. Herein, we develop a general method for operando probing OER intermediates under real working conditions. We proved that the electrochemically generated oxygen intermediates of OER, e.g., OH*, are electrophiles, which could be probed by reaction with nucleophiles such as alcohol molecules. The exceptional generality of this method is demonstrated in different reaction mediums (alkaline and acid) and on various types of materials (oxides and hydroxides). The new insights of the surface chemistry on OER catalysts from the experimental approach will benefit the design of new catalysts to reduce the cost of hydrogen production.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Electrochemical Methods: Fundamentals and Applications
Bard, A. J., & Faulkner, L. R. (1980) · Cited by 22,435
Electrochemical Methods: Fundamentals and Applications
de Rooij, D. M. R. (2003) · Anti-Corrosion Methods and Materials · doi:10.1108/acmm.2003.12850eae.001 · Cited by 13,009
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Trotochaud, L., Young, S. L., Ranney, J. K., & Boettcher, S. W. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502379c · Cited by 3,588
An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen
Louie, M. W., & Bell, A. T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405351s · Cited by 2,803
Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting
Friebel, D., Louie, M. W., Bajdich, M., Sanwald, K. E., Cai, Y., Wise, A. M., Cheng, M.-J., Sokaras, D., Weng, T.-C., Alonso-Mori, R., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511559d · Cited by 2,732
Direct And Mediated Anodic Oxidation of Organic Pollutants
Panizza, M., & Cerisola, G. (2009) · Chemical Reviews · doi:10.1021/cr9001319 · Cited by 2,346
Surface science studies of model fuel cell electrocatalysts
Markovic, N. (2002) · Surface Science Reports · doi:10.1016/s0167-5729(01)00022-x · Cited by 2,143
Cited by
Rong, C., Shen, X., Wang, Y., Thomsen, L., Zhao, T., Li, Y., Lu, X., Amal, R., & Zhao, C. (2022) · Advanced Materials · doi:10.1002/adma.202110103 · Cited by 503
Lanthanide-regulating Ru-O covalency optimizes acidic oxygen evolution electrocatalysis
Li, L., Zhang, G., Zhou, C., Lv, F., Tan, Y., Han, Y., Luo, H., Wang, D., Liu, Y., Shang, C., et al. (2024) · Nature Communications · doi:10.1038/s41467-024-49281-2 · Cited by 368
Multicomponent transition metal oxides and (oxy)hydroxides for oxygen evolution
Han, J., & Guan, J. (2023) · Nano Research · doi:10.1007/s12274-022-4874-7 · Cited by 145
Metadata
- Authors
- Tao, H. B., Xu, Y., Huang, X., Chen, J., Pei, L., Zhang, J., Chen, J. G., & Liu, B.
- Venue
- Joule
- Publisher
- Elsevier BV
- Published
- 2019-06
- Volume
- 3
- Issue
- 6
- Pages
- 1498-1509
- ISSN
- 2542-4351 (ISSN-L)
- OpenAlex
- W2938998034
- Cited by
- 587
- References
- 48
- FWCI
- 7.99
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: A General Method to Probe Oxygen Evolution Intermediates at Operating Conditions. https://app.cochat.ai/papers/10.1016/j.joule.2019.03.012
- The paper
- Tao, H. B., Xu, Y., Huang, X., Chen, J., Pei, L., Zhang, J., Chen, J. G., & Liu, B. (2019). A General Method to Probe Oxygen Evolution Intermediates at Operating Conditions. Joule. https://doi.org/10.1016/j.joule.2019.03.012
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
