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Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors
Open accessAbstract
Bubbles are known to influence energy and mass transfer in gas-evolving electrodes. However, we lack a detailed understanding on the intricate dependencies between bubble evolution processes and electrochemical phenomena. This review discusses our current knowledge on the effects of bubbles on electrochemical systems with the aim to identify opportunities and motivate future research in this area. We first provide a base background on the physics of bubble evolution as it relates to electrochemical processes. Then we outline how bubbles affect energy efficiency of electrode processes, detailing the bubble-induced impacts on activation, ohmic, and concentration overpotentials. Lastly, we describe different strategies to mitigate losses and how to exploit bubbles to enhance electrochemical reactions.
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Cites
Bruggeman, D. A. G. (1935) · Annalen der Physik · doi:10.1002/andp.19354160705 · Cited by 8,645
Recent progress in alkaline water electrolysis for hydrogen production and applications
Zeng, K., & Zhang, D. (2010) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2009.11.002 · Cited by 3,611
Compilation of Henry's law constants (version 4.0) for water as solvent
Sander, R. (2015) · Atmospheric Chemistry and Physics · doi:10.5194/acp-15-4399-2015 · Cited by 2,873
Redox flow batteries: a review
Weber, A. Z., Mench, M. M., Meyers, J. P., Ross, P. N., Gostick, J. T., & Liu, Q. (2011) · Journal of Applied Electrochemistry · doi:10.1007/s10800-011-0348-2 · Cited by 2,008
On the Stability of Gas Bubbles in Liquid-Gas Solutions
Epstein, P. S., & Plesset, M. S. (1950) · The Journal of Chemical Physics · doi:10.1063/1.1747520 · Cited by 1,634
Cambié, D., Bottecchia, C., Straathof, N. J. W., Hessel, V., & Noël, T. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00707 · Cited by 1,502
On the dynamics of phase growth
Scriven, L. E. (1959) · Chemical Engineering Science · doi:10.1016/0009-2509(59)80019-1 · Cited by 994
Surface nanobubbles and nanodroplets
Lohse, D., & Zhang, X. (2015) · Reviews of Modern Physics · doi:10.1103/revmodphys.87.981 · Cited by 858
Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation
Rakowski Dubois, M., & Dubois, D. L. (2009) · Accounts of Chemical Research · doi:10.1021/ar900110c · Cited by 823
Selectivity between Oxygen and Chlorine Evolution in the Chlor-Alkali and Chlorate Processes
Karlsson, R. K. B., & Cornell, A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00389 · Cited by 714
Research works printed but not linked: 53
- Blanco, 2019, Organic electrosynthesis for Sustainable Chemical Manufacturing, J. Trends Chem., 1, 8, 10.1016/j.trechm.2019.01.001 · doi:10.1016/j.trechm.2019.01.001
- Ellis, 1983, Electrocatalytic oxidation of chloride to chlorine based on polypyridine complexes of ruthenium, J. Am. Chem. Soc., 105, 4842, 10.1021/ja00352a057 · doi:10.1021/ja00352a057
- Burgmann, 2012, Investigation of the effect of CO2 bubbles and slugs on the performance of a DMFC by means of laser-optical flow measurements, Energy Procedia, 28, 88, 10.1016/j.egypro.2012.08.043 · doi:10.1016/j.egypro.2012.08.043
- Thorne, 2015, Bubble evolution and anode surface properties in aluminium electrolysis, J. Electrochem. Soc., 162, E104, 10.1149/2.0321508jes · doi:10.1149/2.0321508jes
- Kiros, 2008, Low energy consumption in chlor-alkali cells using oxygen reduction electrodes, Int. J. Electrochem. Sci., 3, 444, 10.1016/S1452-3981(23)15464-2 · doi:10.1016/s1452-3981(23)15464-2
- Cooksey, 2008, Resistance due to gas bubbles in aluminum reduction cells, JOM, 60, 51, 10.1007/s11837-008-0019-x · doi:10.1007/s11837-008-0019-x
- Haupin, 1971, A scanning reference electrode for voltage contours in aluminum smelting cells, JOM, 23, 46, 10.1007/BF03355737 · doi:10.1007/bf03355737
- Wang, 2015, Effect of gas bubble on cell voltage oscillations based on equivalent circuit simulation in aluminum electrolysis cell, Trans. Nonferrous Met. Soc. China, 25, 335, 10.1016/S1003-6326(15)63609-3 · doi:10.1016/s1003-6326(15)63609-3
- Granados Mendoza, 2017, Intensification of the chlor-alkali process by using a spinning disc membrane electrolyzer, Chem. Eng. Res. Des., 128, 120, 10.1016/j.cherd.2017.10.001 · doi:10.1016/j.cherd.2017.10.001
- Cheng, 2002, Chlorine evolution in a centrifugal field, J. Appl. Electrochem., 32, 831, 10.1023/A:1020170627227 · doi:10.1023/a:1020170627227
- Patel, 2019, Investigating effect of different gas diffusion layers on water droplet characteristics for proton exchange membrane (PEM) fuel cells, Int. J. Hydrogen Energy, 44, 18340, 10.1016/j.ijhydene.2019.05.111 · doi:10.1016/j.ijhydene.2019.05.111
- Vogt, 1987, Superposition of microconvective and macroconvective mass transfer at gas-evolving electrodes - a theoretical attempt, Electrochim. Acta, 32, 633, 10.1016/0013-4686(87)87054-8 · doi:10.1016/0013-4686(87)87054-8
- Dees, 1987, Mass transfer at gas evolving surfaces, J. Electrochem. Soc., 134, 1702, 10.1149/1.2100740 · doi:10.1149/1.2100740
- Volanschi, 1997, Microcavity electrodes used as single-nucleation site electrodes for the electrolysis of water, Sens. Mater., 9, 223
- Kolasinski, 2014, Bubbles: a review of their relationship to the formation of thin films and porous materials, Mesopor. Biomater., 1, 49
- Enríquez, 2013, Growing bubbles in a slightly supersaturated liquid solution, Rev. Sci. Instrum., 84, 065111, 10.1063/1.4810852 · doi:10.1063/1.4810852
- Ryan, 1993, Bubble formation in water at smooth hydrophobic surfaces, J. Colloid Interface Sci., 157, 312, 10.1006/jcis.1993.1191 · doi:10.1006/jcis.1993.1191
- Atchley, 1989, The crevice model of bubble nucleation, J. Acoust. Soc. Am., 86, 1065, 10.1121/1.398098 · doi:10.1121/1.398098
- Wilt, 1986, Nucleation rates and bubble stability in water-carbondioxide solutions, J. Colloid Interface Sci., 112, 530, 10.1016/0021-9797(86)90122-0 · doi:10.1016/0021-9797(86)90122-0
- Lubetkin, 1988, The nucleation of bubbles in supersaturated solutions, J. Colloid Interface Sci., 126, 610, 10.1016/0021-9797(88)90161-0 · doi:10.1016/0021-9797(88)90161-0
- Ward, 1970, On the thermodynamics of nucleation in weak gas-liquid solutions, J. Basic Eng., 92, 695, 10.1115/1.3425107 · doi:10.1115/1.3425107
- Bowers, 1996, Unstable supersaturation solutions of gases in liquids and nucleation theory, Faraday Trans., 92, 2843, 10.1039/ft9969202843 · doi:10.1039/ft9969202843
- de Chalendar, 2018, Pore-scale modelling of Ostwald ripening, J. Fluid Mech., 835, 363, 10.1017/jfm.2017.720 · doi:10.1017/jfm.2017.720
- Brandon, 1985, Interfacial electrical properties of electrogenerated bubbles, Electrophoresis, 15, 485
- Chen, 2015, One-heater flow-through polymerase chain reaction device by heat pipes cooling, Biomicrofluidics, 9, 014107, 10.1063/1.4906505 · doi:10.1063/1.4906505
- Hammadi, 2013, Field nano-localization of gas bubble production from water electrolysis, Appl. Phys. Lett., 103, 223106, 10.1063/1.4836095 · doi:10.1063/1.4836095
- Tong, 1990, Contact angle effects on boiling incipience of highly-wetting liquids, Int. J. Heat Mass Transf., 33, 91, 10.1016/0017-9310(90)90144-J · doi:10.1016/0017-9310(90)90144-j
- Borkent, 2009, Nucleation threshold and deactivation mechanisms of nanoscopic cavitation nuclei, Phys. Fluids, 21, 102003, 10.1063/1.3249602 · doi:10.1063/1.3249602
- Fritz, 1935, Berechnung Des maximal volume von dampfblasen, Phys. Z., 36, 379
- Duhar, 2006, Dynamics of bubble growth and detachment in a viscous shear flow, Phys. Fluids, 18, 077101, 10.1063/1.2213638 · doi:10.1063/1.2213638
- van Stralen, 1979, Hemisphere, Boiling Phenom., 1
- Vogt, 2004, The limits of the analogy between boiling and gas evolution at electrodes, Int. J. Heat Mass. Translator, 47, 787, 10.1016/j.ijheatmasstransfer.2003.07.023 · doi:10.1016/j.ijheatmasstransfer.2003.07.023
- Hanafizadeh, 2015, The effect of gas properties on bubble formation, growth, and detachment, Part. Sci. Technol., 33, 645, 10.1080/02726351.2015.1017033 · doi:10.1080/02726351.2015.1017033
- Di Bari, 2013, Experimental study of gas injected bubble growth from submerged orifices, Exp. Therm. Fluid Sci., 44, 124, 10.1016/j.expthermflusci.2012.06.005 · doi:10.1016/j.expthermflusci.2012.06.005
- Jain, 2017, Molecular Dynamics simulations of the surface tension of oxygen-supersaturated water, AIP Adv., 7, 045001, 10.1063/1.4979662 · doi:10.1063/1.4979662
- Nahra, 2003, Prediction of bubble diameter at detachment from a wall orifice in liquid cross-flow under reduced and normal gravity conditions, Chem. Eng. Sci., 58, 55, 10.1016/S0009-2509(02)00516-X · doi:10.1016/s0009-2509(02)00516-x
- Zijlstra, 2015, Enhancing acoustic cavitation using artificial crevice bubbles, Ultrasonics, 56, 512, 10.1016/j.ultras.2014.10.002 · doi:10.1016/j.ultras.2014.10.002
- Sigrist, 1980, On the conductivity and void fraction of gas dispersions in electrolyte solutions, J. Appl. Electrochem., 10, 223, 10.1007/BF00726089 · doi:10.1007/bf00726089
- Newman, 2013, Scaling with Ohm's law; Wired vs. wireless Photoelectrochemical Cells, J. Electrochem. Soc., 160, F309, 10.1149/2.020304jes · doi:10.1149/2.020304jes
- Esposito, 2017, Deconvoluting the influences of 3D structure on the performance of photoelectrodes for solar-driven water splitting, Sustain. Energy Fuels, 1, 154, 10.1039/C6SE00073H · doi:10.1039/c6se00073h
- Njoka, 2019, Effects of photo-generated gas bubbles on the performance of tandem photoelectrochemical reactors for hydrogen production, Int. J. Hydrogen Energy, 44, 10286, 10.1016/j.ijhydene.2019.02.194 · doi:10.1016/j.ijhydene.2019.02.194
- Kellogg, 1950, Anode effect in aqueous electrolysis, J. Electrochem. Soc., 97, 133, 10.1149/1.2777980 · doi:10.1149/1.2777980
- Gabrielli, 1991, Real-time measurement of electrolyte resistance fluctuations, J. Electrochem. Soc., 138, L82, 10.1149/1.2085517 · doi:10.1149/1.2085517
- Paust, 2009, Capillary-driven pumping for passive degassing and fuel supply in direct methanol fuel cells, Microfluid. Nanofluid., 7, 531, 10.1007/s10404-009-0414-9 · doi:10.1007/s10404-009-0414-9
- Metz, 2010, Capillary driven movement of gas bubbles in tapered structures, Microfluid. Nanofluid., 9, 341, 10.1007/s10404-009-0551-1 · doi:10.1007/s10404-009-0551-1
- Sun, 2011, A self-pumping and self-breathing micro direct methanol fuel cell with polymer bipolar plates, J. Power Sources, 196, 7533, 10.1016/j.jpowsour.2011.03.037 · doi:10.1016/j.jpowsour.2011.03.037
- Kang, 2010, A hemispherical microfluidic channel for the trapping and passive dissipation of microbubbles, J. Micromech. Microeng., 20, 045009, 10.1088/0960-1317/20/4/045009 · doi:10.1088/0960-1317/20/4/045009
- Paust, 2009, Self-regulating passive fuel supply for small direct methanol fuel cells operating in all orientations, J. Power Sources, 192, 442, 10.1016/j.jpowsour.2009.03.030 · doi:10.1016/j.jpowsour.2009.03.030
- Zhu, 2011, An on-demand microfluidic hydrogen generator with self-regulated gas generation and self-circulated reactant exchange with a rechargeable reservoir, Microfluid. Nanofluid., 11, 569, 10.1007/s10404-011-0822-5 · doi:10.1007/s10404-011-0822-5
- Nefedov, 1998, Electrolysis of water at high electric field intensities: the fountain effects, Russ. J. Electrochem., 34, 852
- Diao, 2009, Electrochemical noise analysis of the effects of a magnetic field on cathodic hydrogen evolution, Electrochem. Commun., 11, 740, 10.1016/j.elecom.2009.01.020 · doi:10.1016/j.elecom.2009.01.020
- Li, 2009, Water electrolysis in the presence of an ultrasonic field, Electrochim. Acta, 54, 3877, 10.1016/j.electacta.2009.01.087 · DOI · Paper page
- Bolaños-Jiménez, 2017, Streaming flow by oscillating bubbles: quantitative diagnostics via particle tracking velocimetry, J. Fluid Mech., 820, 529, 10.1017/jfm.2017.229 · doi:10.1017/jfm.2017.229
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Metadata
- Authors
- Angulo, A., van der Linde, P., Gardeniers, H., Modestino, M., & Fernández Rivas, D.
- Venue
- Joule
- Publisher
- Elsevier BV
- Published
- 2020-03
- Volume
- 4
- Issue
- 3
- Pages
- 555-579
- ISSN
- 2542-4351 (ISSN-L)
- OpenAlex
- W3004289541
- Cited by
- 958
- References
- 116
- FWCI
- 15.27
- Type
- journal article
- Language
- en
- Open access
- hybrid
- Licence
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- www.elsevier.com/legal/tdmrep-license (tdm)
- www.elsevier.com/open-access/userlicense/1.0/ (vor, 382 d)
- Funders
- Ministerio de Educación, Cultura y Deporte
- Ministerie van Economische Zaken (U1.2)
- Ministerie van Onderwijs, Cultuur en Wetenschap
- Nederlandse Organisatie voor Wetenschappelijk Onderzoek
- Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (CRSII5_173860)
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