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Cited by 264

The DOI matches its Crossref record; 66 of the 66 references it cites were found in a registry or an index.

1,4-Benzoquinone and 1,4-hydroquinone based determination of electron and superoxide radical formed in heterogeneous photocatalytic systems

Open access
Fónagy, Orsolya, Szabó-Bárdos, Erzsébet, Horváth, Ottó·2021·Journal of Photochemistry and Photobiology A: Chemistry

Abstract

In competition-based experiments, 1,4-benzoquinone (BQ) has been a frequently applied compound for determination of the role of O2− radicals. In those studies, only the influence of BQ (as a competitive O2− scavenger) on the degradation of a model compound (substrate) was investigated. Our goal was to develop a new, simple method monitoring a characteristic product of the reaction between the superoxide radical ion and BQ during heterogeneous photocatalysis. Interestingly, based on our results, if the concentration of BQ exceeds that of dissolved oxygen, it reacts with photogenerated electrons rather than with O2− radicals. During this process, it is quantitatively reduced to 1,4-hydroquinone (H2Q), the degradation of which was found to be dependent of the presence of O2− radicals. The photocatalytic transformation of both compounds (BQ, H2Q) was systematically investigated in anoxic and oxic atmosphere. Two new methods requiring only fluorescence measurements have been suggested: one for the determination of electrons with BQ (under anaerobic conditions) and another for the measurement of O2− radicals with H2Q.

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Metadata

Authors
Fónagy, O., Szabó-Bárdos, E., & Horváth, O.
Venue
Journal of Photochemistry and Photobiology A: Chemistry
Publisher
Elsevier BV
Published
2021-02
Volume
407
Pages
113057
ISSN
1010-6030 (ISSN-L)
OpenAlex
W3107761595
Cited by
264
References
66
FWCI
4.87
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: 1,4-Benzoquinone and 1,4-hydroquinone based determination of electron and superoxide radical formed in heterogeneous photocatalytic systems. https://app.cochat.ai/papers/10.1016/j.jphotochem.2020.113057
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Fónagy, O., Szabó-Bárdos, E., & Horváth, O. (2021). 1,4-Benzoquinone and 1,4-hydroquinone based determination of electron and superoxide radical formed in heterogeneous photocatalytic systems. Journal of Photochemistry and Photobiology A: Chemistry. https://doi.org/10.1016/j.jphotochem.2020.113057

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