Reactivity of HO2/O− 2 radicals in aqueous solution
Abstract
Kinetic data for the superoxide radical (HO2⇄O−2 +H+, pK=4.8) in aqueous solution have been critically assessed. Rate constants for reactions of O−2 and HO2 with more than 300 organic and inorganic ions, molecules and other transient species have been tabulated.
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Superoxide absorbs light in the ultraviolet range with a maximum at 245 nm and an extinction coefficient of 2350 M−1 cm−1, whereas hydroperoxyl absorbs at 225 nm with an extinction coefficient of 1400 M−1 cm−1.
“Superoxide absorbs light in the ultraviolet range with a maximum at 245 nm and an extinction coefficient of 2350 M−1 cm−1, whereas hydroperoxyl absorbs at 225 nm with an extinction coefficient of 1400 M−1 cm−1 [20].”
From Superoxide Anion Chemistry—Its Role at the Core of the Innate Immunity (2023) · cites this paper as [20]
Superoxide oxidises few biological compounds.
“Superoxide oxidises few biological compounds [20], and this is due to the following reasons:-Its anionic charge which limits its reactivity to compounds with electron-rich centres [63].-Its facility for spontaneous dismutation [64].”
From Superoxide Anion Chemistry—Its Role at the Core of the Innate Immunity (2023) · cites this paper as [20]
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- Authors
- Bielski, B. H. J., Cabelli, D. E., Arudi, R. L., & Ross, A. B.
- Affiliations
- Brookhaven National Laboratory (US)
- University of Notre Dame (US)
- Venue
- Journal of Physical and Chemical Reference Data
- Publisher
- AIP Publishing
- Published
- 1985-10-01
- Volume
- 14
- Issue
- 4
- Pages
- 1041-1100
- ISSN
- 0047-2689 (ISSN-L)
- 1529-7845
- OpenAlex
- W2051802937
- Cited by
- 2,169
- References
- 0
- Citations by year
- 2026: 93 · 2025: 90 · 2024: 83 · 2023: 109 · 2022: 109 · 2021: 118 · 2020: 100 · 2019: 77 · 2018: 80 · 2017: 77 · 2016: 94 · 2015: 75 · 2014: 78 · 2013: 73 · 2012: 57
- FWCI
- 29.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Physical and Chemical Reference Data (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Chemistry › Organic Chemistry › Free Radicals and Antioxidants
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
- Keywords
- superoxide, hydroperoxyl radical, reaction kinetics, rate constants, aqueous solutions, radical reactivity, hydrogen peroxide, critical appraisal, transient species
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Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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