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Diffusional lithium trapping as a failure mechanism of aluminum foil anodes in lithium-ion batteries
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Pure aluminum anode capacity fading is caused by loss of lithium due to diffusion into the bulk or formation of stable AlLi phases.
“The causes of this have been extensively studied and include: (i) structural damage from excessive volume changes during the charge–discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”
From Solid-State Diffusion Bonding of Aluminum to Copper for Bimetallic Anode Fabrication (2024) · cites this paper as [9]
The mechanism section (pp. 7, 10) attributes rapid capacity loss in aluminum foil anodes to lithium trapped in residual β-LiAl beneath a poorly diffusive α-Al surface layer. This supports lithium becoming inaccessible through diffusion-related trapping, but not the specific explanation that lithium diffuses into the bulk or that intrinsically stable AlLi phases cause the loss. (LLM, conf=0.84)
Experimental — accuracy not yet measuredPure aluminum anode capacity fading is caused by structural damage from excessive volume changes during charge-discharge, leading to crack nucleation and pulverization and loss of electrical contact.
“The causes of this have been extensively studied and include: (i) structural damage from excessive volume changes during the charge–discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”
From Solid-State Diffusion Bonding of Aluminum to Copper for Bimetallic Anode Fabrication (2024) · cites this paper as [9]
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Cited by
Sorted by citations
Solid-State Diffusion Bonding of Aluminum to Copper for Bimetallic Anode Fabrication
de Prado, J., Børresen, B. T., Utrilla, V., & Ureña, A. (2024) · Materials · doi:10.3390/ma17215333 · Cited by 6
“…structural damage from excessive volume changes during the charge– discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”
Background
Metadata
- Authors
- Crowley, P. J., Scanlan, K. P., & Manthiram, A.
- Affiliations
- Texas Materials Institute (US)
- Corresponding author
- Manthiram, Arumugam
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2022-10
- Volume
- 546
- Pages
- 231973
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W4293182795
- Cited by
- 62
- References
- 0
- Citations by year
- 2026: 12 · 2025: 19 · 2024: 20 · 2023: 10 · 2022: 1
- FWCI
- 3.42
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- www.elsevier.com/legal/tdmrep-license (tdm)
- www.elsevier.com/open-access/userlicense/1.0/ (am, 326 d)
- doi.org/10.15223/policy-017 (stm-asf)
- doi.org/10.15223/policy-037 (stm-asf)
- doi.org/10.15223/policy-012 (stm-asf)
- doi.org/10.15223/policy-029 (stm-asf)
- doi.org/10.15223/policy-004 (stm-asf)
- Locations
- Journal of Power Sources (acceptedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Texas Digital Library (University of Texas)
- Funders
- University of Texas at Austin
- Division of Materials Sciences and Engineering
- U.S. Department of Energy (DE-SC0005397)
- Basic Energy Sciences
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, grain boundaries, lithium ion diffusion, capacity fade, alloy design, lithium-silicon alloy, aluminum-lithium alloys, delithiation, cycle life, first cycle efficiency
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