Removal of chromate anions and immobilization using surfactant-modified zeolites
Abstract
In this research surface modified zeolites, Linde Type A and clinoptilolite, were used for the chromate ions uptake from aqueous solutions as well as its encapsulation through a vitrification process. The surface chemistry of zeolites was modified using a cationic surfactant hexadecyltrimethylammonium (HDTMA) to promote the capability of anions uptake. The results of characterization by X-ray diffraction showed unique crystalline phases for each zeolite which remain unchanged after the incorporation of the surfactant. Evidence from Fourier-transform infrared spectroscopy studies revealed the effective bond of the HDTMA on the clinoptilolite surface. Results suggested that the presence of CH2− groups after the modification play a key role for the anion attraction. Kinetic studies revealed that surfactant-modified clinoptilolite was able to adsorb 9.83 mg/g of chromate and better fitted pseudo-second order model (R2 = 0.957). The equilibrium was better represented by Freundlich model (R2 = 0.993). Finally, the proposed vitrification process the spent zeolitic adsorbent was successful, avoiding leaching of chromate ions after two months at different pH values.
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The pseudo-second order kinetic model has been the best fit for the adsorption of heavy metals with natural zeolites.
“Among these kinetic models, the pseudo-second order kinetic model has been the best fit for the adsorption of heavy metals with natural zeolites.”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Dimas Rivera et al., 2021
A large part of heavy metals such as As, Cd, Cr, Pb, Hg, and Ni are adsorbed with natural zeolites by chemisorption via intraparticle diffusion and inner-pore.
“This result indicates that a large part of heavy metals such as As (Bilici Baskan and Pala, 2011), Cd (Merrikhpour and Jalali, 2013), Cr (Dimas Rivera et al., 2021;Lv et al., 2014a;Taamneh and Al Dwairi, 2013), Pb (Fei et al., 2010;Ratios, 2019), Hg (Shirzadi andNezamzadeh-Ejhieh, 2017), andNi (Al-Abbad andAl Dwairi, 2021;Rajic et al., 2010) are adsorbed with natural zeolites by chemisorption via”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Dimas Rivera et al., 2021
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“This result indicates that a large part of heavy metals such as As (Bilici Baskan and Pala, 2011), Cd (Merrikhpour and Jalali, 2013), Cr (Dimas Rivera et al., 2021; Lv et al., 2014a; Taamneh and Al Dwairi, 2013), Pb (Fei et al., 2010; Ratios, 2019), Hg (Shirzadi and Nezamzadeh-Ejhieh, 2017), and Ni…”
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Self-citation
- Authors
- Dimas Rivera, G. L., Martínez Hernández, A., Pérez Cabello, A. F., Rivas Barragán, E. L., Liñán Montes, A., Flores Escamilla, G. A., Sandoval Rangel, L., Suarez Vazquez, S. I., & De Haro Del Río, D. A.
- Venue
- Journal of Water Process Engineering
- Publisher
- Elsevier BV
- Published
- 2021-02
- Volume
- 39
- Pages
- 101717
- ISSN
- 2214-7144 (ISSN-L)
- OpenAlex
- W3092059779
- Semantic Scholar
- 96d481c07a683a91c9098e5d9d44421bed0cb4cc
- Cited by
- 34
- References
- 94
- Citations by year
- 2026: 1 · 2025: 11 · 2024: 7 · 2023: 4 · 2022: 7 · 2021: 4
- FWCI
- 1.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Water Process Engineering (publishedVersion)
- Funders
- Fondation Chiropratique du Québec
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- chromate removal, hexavalent chromium, surfactant-modified zeolite, clinoptilolite, zeolite A, hexadecyltrimethylammonium, anion adsorption, adsorption kinetics, adsorption isotherms, water treatment, heavy metal immobilization
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