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Copper hexacyanoferrate with a well-defined open framework as a positive electrode for aqueous zinc ion batteries

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Jia, Zhijun, Wang, Baoguo, Wang, Yi·2015·Materials Chemistry and Physics

Abstract

The feasibility of the electrochemical zinc ion insertion/extraction reaction in CuHCF nano-cube in aqueous solution is investigated. It is demonstrated for the first time that the divalent zinc ions can be reversibly inserted/extracted into/from CuHCF nano-cube in aqueous solution due to the small radius steric effect of zinc ions. The zinc ion insertion and extraction is controlled by the solid phase diffusion into/from the CuHCF electrode. Divalent cation (de)intercalation discovered in this work expands perspectives on intercalation electrochemistry Of divalent cations, and it will possibly lead to development of novel divalent cation intercalation compounds for aqueous rechargeable batteries. (C) 2014 Elsevier B.V. All rights reserved.

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Metadata

Authors
Jia, Z., Wang, B., & Wang, Y.
Venue
Materials Chemistry and Physics
Publisher
Elsevier BV
Published
2015-01
Volume
149-150
Pages
601-606
ISSN
0254-0584 (ISSN-L)
OpenAlex
W2090792976
Cited by
275
References
0
FWCI
3.71
Type
journal article
Language
en
Open access
green

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Jia, Z., Wang, B., & Wang, Y. (2015). Copper hexacyanoferrate with a well-defined open framework as a positive electrode for aqueous zinc ion batteries. Materials Chemistry and Physics. https://doi.org/10.1016/j.matchemphys.2014.11.014

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