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Microporous polymer electrolyte based on PVDF/PEO star polymer blends for lithium ion batteries
Open accessAbstract
Abstract A novel microporous polymer electrolyte (MPE) based on poly (vinylidene fluoride) (PVDF)/poly (ethylene oxide) (PEO) star polymer was prepared by a phase inversion technique. The effects of PEO chain length of star polymer and temperature on ionic conductivity of MPE were investigated. The results showed that the ionic conductivity increased generally with the chain length of star polymer arms without any abrupt change. Effects of star polymer mass fraction on electrolyte uptake and leakage were also discussed. The distribution of holes and connectivity was improved with star polymer mass fraction increased, thus resulted in a high ionic conductivity (3.03×10−3 S cm−1) exhibited at room temperature. Moreover, the electrochemical stability window was observed above 5.0 V (vs. Li/Li+). All these results showed that this MPE could be served as a good candidate for lithium ion batteries.
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Cites
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
A review on the key issues for lithium-ion battery management in electric vehicles
Lu, L., Han, X., Li, J., Hua, J., & Ouyang, M. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.10.060 · Cited by 4,837
Cited by
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
Xue, Z., He, D., & Xie, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta03471j · Cited by 2,302
Self-citationNie, K., Hong, Y., Qiu, J., Li, Q., Yu, X., Li, H., & Chen, L. (2018) · Frontiers in Chemistry · doi:10.3389/fchem.2018.00616 · Cited by 278
Baskoro, F., Wong, H. Q., & Yen, H.-J. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.9b00295 · Cited by 258
Metadata
- Authors
- Deng, F., Wang, X., He, D., Hu, J., Gong, C., Ye, Y. S., Xie, X., & Xue, Z.
- Venue
- Journal of Membrane Science
- Publisher
- Elsevier BV
- Published
- 2015-10
- Volume
- 491
- Pages
- 82-89
- ISSN
- 0376-7388 (ISSN-L)
- OpenAlex
- W317906208
- Cited by
- 197
- References
- 2
- FWCI
- 9.30
- Type
- journal article
- Language
- en
- Open access
- green
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- Deng, F., Wang, X., He, D., Hu, J., Gong, C., Ye, Y. S., Xie, X., & Xue, Z. (2015). Microporous polymer electrolyte based on PVDF/PEO star polymer blends for lithium ion batteries. Journal of Membrane Science. https://doi.org/10.1016/j.memsci.2015.05.021
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
