The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis
Open accessAbstract
Abstract Deep eutectic solvents (DESs) based on the cation choline have been proposed to date for a variety of applications due to their remarkable physicochemical properties. The thermal stability is one of the first properties of DESs that needs to be known since it limits the maximum operating temperature for which these solvents are useful in many applications. In this work, the thermal stability of eight different choline chloride-based DESs formed using levulinic acid, malonic acid, glycerol, ethylene glycol, phenylacetic acid, phenylpropionic acid, urea, and glucose as hydrogen bond donors (HBDs) has been studied using isothermal and dynamic thermogravimetric analysis/Fourier transform infrared-attenuated total reflectance spectroscopy (TGA/FTIR-ATR) techniques. Isothermal and dynamic FTIR-ATR were carried out to confirm the formation and to show the structural changes with temperature of the DESs, respectively. The onset decomposition temperatures of the DESs were obtained from dynamic TGA. However, the maximum operating temperatures determined by isothermal TGA in long-term scenarios have demonstrated to be significantly lower than the onset decomposition temperatures for every DES studied. The thermal stability and the boiling point of HBDs have a crucial impact on the maximum operating temperature of DESs.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
Florindo, C., Oliveira, F. S., Rebelo, L. P. N., Fernandes, A. M., & Marrucho, I. M. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500439w · Cited by 977
Low melting mixtures in organic synthesis–an alternative to ionic liquids?
Ruß, C., & König, B. (2012) · Green Chemistry · doi:10.1039/c2gc36005e · Cited by 654
Properties and thermal behavior of natural deep eutectic solvents
Craveiro, R., Aroso, I., Flammia, V., Carvalho, T., Viciosa, M. T., Dionísio, M., Barreiros, S., Reis, R. L., Duarte, A. R. C., & Paiva, A. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.01.038 · Cited by 449
Ionic liquids and deep eutectic mixtures: Sustainable solvents for extraction processes
Pena‐Pereira, F., & Namieśnik, J. (2014) · ChemSusChem · doi:10.1002/cssc.201301192 · Cited by 432
Experimental and Computational Studies of Choline Chloride-Based Deep Eutectic Solvents
Perkins, S. L., Painter, P., & Colina, C. M. (2014) · Journal of Chemical & Engineering Data · doi:10.1021/je500520h · Cited by 374
Thermal and physical properties of (Choline chloride + urea +l-arginine) deep eutectic solvents
Chemat, F., Anjum, H., Shariff, A. M., Kumar, P., & Murugesan, T. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.02.062 · Cited by 274
Cited by
Deep eutectic solvents: A review of fundamentals and applications
Hansen, B. B., Spittle, S., Chen, B., Poe, D., Zhang, Y., Klein, J. M., Horton, A., Adhikari, L., Zelovich, T., Doherty, B. W., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00385 · Cited by 3,422
Everything You Wanted to Know about Deep Eutectic Solvents but Were Afraid to Be Told
Abranches, D. O., & Coutinho, J. A. P. (2023) · Annual Review of Chemical and Biomolecular Engineering · doi:10.1146/annurev-chembioeng-101121-085323 · Cited by 384
Aslan Türker, D., & Doğan, M. (2021) · LWT · doi:10.1016/j.lwt.2020.110775 · Cited by 68
Mat Hussin, S. A., Varanusupakul, P., Shahabuddin, S., Yih Hui, B., & Mohamad, S. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.113015 · Cited by 60
Rastbood, S., Hadjmohammadi, M. R., & Majidi, S. M. (2020) · Analytical Methods · doi:10.1039/d0ay00095g · Cited by 40
Metadata
- Authors
- Delgado-Mellado, N., Larriba, M., Navarro, P., Rigual, V., Ayuso, M., García, J., & Rodríguez, F.
- Venue
- Journal of Molecular Liquids
- Publisher
- Elsevier BV
- Published
- 2018-06
- Volume
- 260
- Pages
- 37-43
- ISSN
- 0167-7322 (ISSN-L)
- OpenAlex
- W2791533407
- Cited by
- 561
- References
- 30
- FWCI
- 7.01
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis. https://app.cochat.ai/papers/10.1016/j.molliq.2018.03.076
- The paper
- Delgado-Mellado, N., Larriba, M., Navarro, P., Rigual, V., Ayuso, M., García, J., & Rodríguez, F. (2018). Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis. Journal of Molecular Liquids. https://doi.org/10.1016/j.molliq.2018.03.076
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
