Cited by 385Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsHydrogen Storage and Materials

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CoP nanosheet assembly grown on carbon cloth: A highly efficient electrocatalyst for hydrogen generation

Yang, Xiulin, Lu, Ang-Yu, Zhu, Yihan, Hedhili, Mohamed Nejib, Min, Shixiong, Huang, Kuo-Wei, Han, Yu, Li, Lain-Jong·2015·Nano Energy

DOI 10.1016/j.nanoen.2015.05.026

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Abstract

There exists a strong demand to replace expensive noble metal catalysts with cheap metal sulfides or phosphides for hydrogen evolution reaction (HER). Recently metal phosphides such as NixP, FeP and CoP have been considered as promising candidates to replace Pt cathodes. Here we report that the nanocrystalline CoP nanosheet assembly on carbon cloth can be formed by a two-step process: electrochemical deposition of Co species followed by gas phase phosphidation. The CoP catalyst in this report exhibits a Tafel slope of 30.1 mV/dec in 0.5 M H2SO4 and 42.6 mV/dec in 1 M KOH. The high HER performance of our CoP catalysts is attributed to the rugae-like morphology which results in a high double-layer capacitance and high density of active sites, estimated as 7.77×1017 sites/cm2.

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Authors: Yang, X., Lu, A.-Y., Zhu, Y., Hedhili, M. N., Min, S., Huang, K.-W., Han, Y., & Li, L.-J.
Affiliations: King Abdullah University of Science and Technology (SA)
Corresponding author: Li, Lain-Jong
ORCID: Yang, Xiulin
Lu, Ang-Yu
Zhu, Yihan
Hedhili, Mohamed Nejib
Min, Shixiong
Huang, Kuo-Wei
Han, Yu
Li, Lain-Jong
Venue: Nano Energy
Publisher: Elsevier BV
Published: 2015-07
Volume: 15
Pages: 634-641
ISSN: 2211-2855 (ISSN-L)
DOI: 10.1016/j.nanoen.2015.05.026
OpenAlex: W1703055330
Cited by: 385
References: 65
Citations by year: 2026: 10 · 2025: 12 · 2024: 22 · 2023: 24 · 2022: 43 · 2021: 43 · 2020: 50 · 2019: 59 · 2018: 48 · 2017: 48 · 2016: 23 · 2015: 3
FWCI: 12.04
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/legal/tdmrep-license (tdm)
Locations: Nano Energy (publishedVersion)
King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion)
Funders: King Abdullah University of Science and Technology
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
Keywords: cobalt phosphide, carbon cloth, hydrogen evolution reaction, electrocatalysts, metal phosphides, noble metal-free catalysts, electrodeposition, double-layer capacitance, Tafel slope, acidic and alkaline electrolytes

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CoP nanosheet assembly grown on carbon cloth: A highly efficient electrocatalyst for hydrogen generation

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