Characterization and enzymatic degradation of microbial copolyester P(3HB-co-3HV)s produced by metabolic reaction model-based system
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Depending on the provenance of the PHB depolymerase, either monomer and dimer of 3-hydroxybutyric acid or oligomers can be obtained.
“Depending on the provenance of the PHB depolymerase, either monomer and dimer of 3-hydroxybutyric acid 497 or oligomers can be obtained.[498][499][500]”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [499]
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“The defined fractions were characterized based on their sequence distributions determined through 1H and 13C NMR analyses according to a previous report [27].”
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“Polymer dissolved in chloroform was precipitated with twofold chilled hexane and was evaporated using a rotary evaporator at 55 C.([19]) The collected polymer was dried at room temperature for 24 h.”
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“The main degradation process with a constant surface area is surface erosion [55].”
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“As expected, the result showed that P(3HBco-7 mol% 3HV) was a block copolymer, which corresponded with two studies whereby, similar block copolymers were synthesized using Paracoccus denitrificans ATTC 17741 (Chanprateep et al., 2006) and Cupriavidus sp. USMAA2-4 (Shantini, 2015).”
ResultNanthachai, S., Kim, B. S., Honda, K., & Napathorn, S. C. (2025) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2025.111420 · Cited by 7 · see citing works
Phothong, N., Bhamarasuta, S., Morikane, S., Tomita, H., Honda, K., & Napathorn, S. C. (2025) · Advanced Industrial and Engineering Polymer Research · doi:10.1016/j.aiepr.2025.05.002 · Cited by 6 · see citing works
Biocompatibility of Nanomaterials Reinforced Polymer-Based Nanocomposites
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Biocompatibility of Nanomaterials Reinforced Polymer-Based Nanocomposites
Fouad, F. A., Youssef, D. G., Refay, F. A., & Heakal, F. E. (2022) · Springer eBooks · doi:10.1007/978-3-030-83783-9_17-1 · Cited by 1 · see citing works
Gil-Castell, O. (2018) · doi:10.4995/thesis/10251/107950 · Cited by 1 · see citing works
Phothong, N., Naumtanong, P., Honda, K., & Napathorn, S. C. (2026) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2026.112144
- Authors
- Chanprateep, S., Shimizu, H., & Shioya, S.
- Affiliations
- The University of Osaka (JP)
- ORCID
- Shimizu, Hiroshi
- Venue
- Polymer Degradation and Stability
- Publisher
- Elsevier BV
- Published
- 2006-12
- Volume
- 91
- Issue
- 12
- Pages
- 2941-2950
- ISSN
- 0141-3910 (ISSN-L)
- OpenAlex
- W1968470325
- Cited by
- 24
- References
- 21
- Citations by year
- 2026: 2 · 2025: 2 · 2023: 3 · 2022: 2 · 2019: 3 · 2018: 1 · 2017: 3 · 2014: 1 · 2013: 1 · 2012: 1
- FWCI
- 0.18
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer Degradation and Stability (publishedVersion)
- Funders
- Chulalongkorn University
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Environmental Science › Pollution › Microbial bioremediation and biosurfactants
- Keywords
- poly(3-hydroxybutyrate-co-3-hydroxyvalerate), Paracoccus denitrificans, enzymatic degradation, copolymer sequence distribution, block copolymers, feeding optimization, hydrolytic degradation, surface erosion, biodegradable films
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