Functionalization of poly(ε-caprolactone) by pendant hydroxyl, carboxylic acid and epoxide groups by atom transfer radical addition
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No protection is needed and no chain degradation is observed by SEC in ATRA.
“Again, no protection is needed and no chain degradation is observed by SEC [148].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [148]
3-buten-1-ol is quantitatively grafted onto chloro-PCL by CuBr/Me6TREN mediated ATRA in DMF at 65 °C for 4 h.
“Finally, 3-buten-1-ol is quantitatively grafted onto chloro-PCL by CuBr/Me 6 TREN meditated ATRA in DMF at 65 °C for 4 h [148].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [148]
α-chlorocyclohexanone is easily converted into parent lactone (αClεCL) by one-step oxidation with m-CPBA with high yield, the chlorine atom of the lactone being activated by proximity of the ester group.
“α-chlorocyclohexanone is easily converted into the parent lactone (αClεCL) by one-step oxidation with m-CPBA with high yield, the chlorine atom of the lactone being activated by the proximity of the ester group (Scheme 15) [148,149].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [148]
Cites
Detrembleur, C., Mazza, M., Lou, X., Halleux, O., Lecomte, P., Mecerreyes, D., Hedrick, J. L., & Jérôme, R. (2000) · Macromolecules · doi:10.1021/ma000488o · Cited by 73 · see citing works
Self-citationGautier, S., D'Aloia, V., Halleux, O., Mazza, M., Lecomte, P., & Jérôme, R. (2003) · Journal of Biomaterials Science, Polymer Edition · doi:10.1163/15685620360511146 · Cited by 49 · see citing works
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Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆
JEROME, C., & LECOMTE, P. (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2008.02.008 · Cited by 590 · see citing works
Self-citationRiva, R., Schmeits, S., Stoffelbach, F., Jérôme, C., Jérôme, R., & Lecomte, P. (2005) · Chemical Communications · doi:10.1039/b510282k · Cited by 208 · see citing works
Self-citationContribution of click chemistry to the synthesis of antimicrobial aliphatic copolyester
Riva, R., Lussis, P., Lenoir, S., Jérôme, C., Jérôme, R., & Lecomte, P. (2008) · Polymer · doi:10.1016/j.polymer.2008.03.008 · Cited by 57 · see citing works
Self-citationRiva, R., Rieger, J., Jérôme, R., & Lecomte, P. (2006) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.21674 · Cited by 48 · see citing works
Self-citationCationic salt-responsive bottle-brush polymers
Yao, K., Chen, Y., Zhang, J., Bunyard, C., & Tang, C. (2013) · Macromolecular Rapid Communications · doi:10.1002/marc.201300088 · Cited by 41 · see citing works
- Authors
- Riva, R., Lenoir, S., Jérôme, R., & Lecomte, P.
- Affiliations
- University of Liège (BE)
- Corresponding author
- Jérôme, R.
- ORCID
- Riva, R.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2005-09
- Volume
- 46
- Issue
- 19
- Pages
- 8511-8518
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2041887882
- Cited by
- 56
- References
- 2
- Citations by year
- 2025: 1 · 2024: 1 · 2023: 3 · 2022: 3 · 2020: 2 · 2019: 1 · 2017: 2 · 2016: 1 · 2015: 4 · 2014: 4 · 2013: 2 · 2012: 8
- FWCI
- 2.79
- Type
- journal article
- Language
- en
- Open access
- green
- orbi.uliege.be
- Licence
- Locations
- Polymer (publishedVersion)
- ORBi (University of Liège) (submittedVersion, other-oa)
- Funders
- Fonds De La Recherche Scientifique - FNRS
- Fonds pour la Formation à la Recherche dans l’Industrie et dans l’Agriculture
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › Polymer Surface Interaction Studies
- Keywords
- polycaprolactone, atom transfer radical addition, functionalization, pendant hydroxyl groups, carboxyl groups, epoxide groups, statistical copolymerization, Baeyer-Villiger oxidation, 2-chlorocyclohexanone, grafting yield
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