Combination of ring-opening polymerization and “click” chemistry towards functionalization of aliphatic polyesters
Open accessAbstract
Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 degrees C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.
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ω-alkyne-PEO with poly(αN3εCL-co-LA), provided that OH end-groups of copolylactide chains are previously esterified with acetyl chloride, gives PLA-g-PEO graft amphiphilic copolymers.
“ω-alkyne-PEO with poly(αN 3 εCL-co-LA), provided that the OH end-groups of the copolylactide chains are previously esterified with acetyl chloride gives PLA-g-PEO graft amphiphilic copolymers (Scheme 17) [154],”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [154]
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- Authors
- Riva, R., Schmeits, S., Stoffelbach, F., Jérôme, C., Jérôme, R., & Lecomte, P.
- Affiliations
- University of Liège (BE)
- Corresponding author
- Jérôme, Robert
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Issue
- 42
- Pages
- 5334
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2083415276
- Cited by
- 208
- References
- 7
- Citations by year
- 2025: 2 · 2024: 8 · 2023: 3 · 2022: 4 · 2021: 4 · 2020: 2 · 2019: 6 · 2018: 7 · 2017: 8 · 2016: 4 · 2015: 10 · 2014: 10 · 2013: 17 · 2012: 17
- FWCI
- 9.36
- Type
- journal article
- Language
- en
- Open access
- green
- orbi.uliege.be
- Licence
- other-oa
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- Open Repository and Bibliography (University of Liège) (submittedVersion, other-oa)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Click Chemistry and Applications
- Keywords
- aliphatic polyesters, ring-opening polymerization, click chemistry, azide functionalization, tertiary amines, ammonium salts, polylactic acid, graft copolymerization
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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