Well-defined sterically hindered zinc aryloxides: Excellent catalysts for ring-opening polymerization of ɛ-caprolactone and l-lactide
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Complexes 85 and 86 revealed high catalytic activity in L-LA polymerization at 30 °C compared with complexes 83 and 84 at 83 °C, and the mononuclear Ti complex 87 exhibited low catalytic activity for L-LA polymerization at 30 °C (94 h, conversion = 76 %).
“Complexes 85 and 86 revealed high catalytic activity in L-LA polymerization at 30 °C compared with complexes 83 and 84 at 83 °C, and the mononuclear Ti complex 87 exhibited low catalytic activity for L-LA polymerization at 30 °C (94 h, conversion = 76 %).”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [98]
Ti-Mg complex 86 exhibited greater controllability than did Ti-Zn complex 85.
“In addition, Ti-Mg complex 86 exhibited greater controllability than did Ti-Zn complex 85.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [98]
The synthesis of hetero-dinuclear Zn-Ti and Mg-Ti complexes involved diphenol (EDBP) reacting with ZnEt2 and MgnBu2 to form complexes 83 and 84, then reacting with Ti(OiPr)4 to form complexes 85 and 86.
“For example, the synthesis of hetero-dinuclear Zn-Ti and Mg-Ti complexes [98] was that diphenol (EDBP) reacted with ZnEt 2 and Mg n Bu 2 , respectively, to form complexes 83 and 84, and then reacted with Ti(O i Pr) 4 to form complexes 85 and 86.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [98]
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New emerging trends in synthetic biodegradable polymers—Polylactide: A critique
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Self-citation
- Authors
- Huang, B.-H., Lin, C.-N., Hsueh, M.-L., Athar, T., & Lin, C.-C.
- Affiliations
- National Chung Hsing University (TW)
- Corresponding author
- Lin, Chu-Chieh
- ORCID
- Lin, Chu-Chieh
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2006-09
- Volume
- 47
- Issue
- 19
- Pages
- 6622-6629
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2064538002
- Cited by
- 61
- References
- 5
- Citations by year
- 2024: 1 · 2022: 1 · 2019: 4 · 2018: 1 · 2017: 1 · 2016: 4 · 2015: 8 · 2014: 3 · 2013: 4 · 2012: 12
- FWCI
- 2.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- ring-opening polymerization, ε-caprolactone, L-lactide, controlled polymerization, polydispersity index
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