Multifunctional initiation of lactide polymerization by stannous octoate/pentaerythritol
Abstract
Abstract L‐Lactide was polymerized with stannous 2‐ethylhexanoate (stannous octoate) in the presence of pentaerythritol to investigate multifunctional initiation. The prepared oligomers contain starshaped 4‐arm molecules when the mole ratio of [lactide]/[pentaerythritol] is above 32. The molecular weight of oligomers coincides with the [lactide]/[pentaerythritol] ratio, indicating that pentaerythritol in conjugation with stannous octoate is an initiator for the “living” polymerization of L‐lactide.
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Stannous octoate is accepted by FDA as a food additive.
“We have also come across references which state that stannous octoate is accepted by FDA as a food additive (Gilding and Reed, 1979, text reference;Kim et al., 1992)”
From Biodegradable synthetic polymers for tissue engineering (2003) · cites this paper as Kim et al., 1992
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Linear and Branched Lactide Polymers for Targeted Drug Delivery Systems
Gomzyak, V. I., Sedush, N. G., Puchkov, A. A., Polyakov, D. K., & Чвалун, С. Н. (2021) · Polymer Science Series B · doi:10.1134/s1560090421030064 · Cited by 31 · see citing works
Quiescent and shear-induced crystallization of linear and branched polylactides
Najafi, N., Heuzey, M. C., Carreau, P. J., & Therriault, D. (2015) · Rheologica Acta · doi:10.1007/s00397-015-0874-7 · Cited by 31 · see citing works
- Authors
- Kim, S. H., Han, Y., Kim, Y. H., & Hong, S. I.
- Affiliations
- Korea Institute of Science and Technology (KR)
- Seoul National University (KR)
- Corresponding author
- Kim, Young Ha
- Venue
- Die Makromolekulare Chemie
- Publisher
- Wiley
- Published
- 1992-07
- Volume
- 193
- Issue
- 7
- Pages
- 1623-1631
- ISSN
- 0025-116X (ISSN-L)
- OpenAlex
- W1562769333
- Cited by
- 196
- References
- 19
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 2 · 2022: 7 · 2021: 2 · 2020: 2 · 2019: 2 · 2018: 5 · 2017: 11 · 2016: 6 · 2015: 7 · 2014: 9 · 2013: 6 · 2012: 15
- FWCI
- 4.38
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Die Makromolekulare Chemie (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- L-lactide, stannous octoate, pentaerythritol, star-shaped oligomers, living polymerization, ring-opening polymerization, poly(L-lactic acid)
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