The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water
Open accessAbstract
Covalent triazine-based frameworks (CTFs) are a subclass of conjugated microporous polymers (CMPs) that can be used as organic photocatalysts for photocatalytic hydrogen evolution from water. Seven materials with varied spacer units from phenylene to quarterphenylene were synthesized, either by trifluoromethanesulfonic acid (TfOH) catalysis from nitriles or by Suzuki-Miyaura polycondensation. The photocatalytic performance under visible light of all materials was systematically studied in the presence of a hole-scavenger, showing that both synthesis routes produce CTFs with similar hydrogen evolution rates (HER), but different optical properties. The highest hydrogen evolution rate in the cyclotrimerized series was found for CTF-2 with an apparent quantum yield of 1.6% at 420 nm in a mixture of water and triethanolamine with a platinum co-catalyst. Based on (TD-)DFT calculations, the highest performance was expected for CTF-1 and this discrepancy is explained by a trade-off between increased light absorption and decreased thermodynamic driving force.
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Cites
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Cited by
Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water
Wang, X., Chen, L., Chong, S. Y., Little, M. A., Wu, Y., Zhu, W.-H., Clowes, R., Yan, Y., Zwijnenburg, M. A., Sprick, R. S., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0141-5 · Cited by 1,320
Self-citationCovalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Conjugated polymers for visible-light-driven photocatalysis
Dai, C., & Liu, B. (2020) · Energy & Environmental Science · doi:10.1039/c9ee01935a · Cited by 687
Bai, Y., Wilbraham, L., Slater, B. J., Zwijnenburg, M. A., Sprick, R. S., & Cooper, A. I. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b03591 · Cited by 409
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Metadata
- Authors
- Meier, C. B., Sprick, R. S., Monti, A., Guiglion, P., Lee, J.-S. M., Zwijnenburg, M. A., & Cooper, A. I.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2017-09
- Volume
- 126
- Pages
- 283-290
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2604620129
- Cited by
- 169
- References
- 3
- FWCI
- 8.92
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Meier, C. B., Sprick, R. S., Monti, A., Guiglion, P., Lee, J.-S. M., Zwijnenburg, M. A., & Cooper, A. I. (2017). Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water. Polymer. https://doi.org/10.1016/j.polymer.2017.04.017
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