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Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water

Open access
Meier, Christian B., Sprick, Reiner Sebastian, Monti, Adriano, Guiglion, Pierre, Lee, Jet-Sing M., Zwijnenburg, Martijn A., Cooper, Andrew I.·2017·Polymer

Abstract

Covalent triazine-based frameworks (CTFs) are a subclass of conjugated microporous polymers (CMPs) that can be used as organic photocatalysts for photocatalytic hydrogen evolution from water. Seven materials with varied spacer units from phenylene to quarterphenylene were synthesized, either by trifluoromethanesulfonic acid (TfOH) catalysis from nitriles or by Suzuki-Miyaura polycondensation. The photocatalytic performance under visible light of all materials was systematically studied in the presence of a hole-scavenger, showing that both synthesis routes produce CTFs with similar hydrogen evolution rates (HER), but different optical properties. The highest hydrogen evolution rate in the cyclotrimerized series was found for CTF-2 with an apparent quantum yield of 1.6% at 420 nm in a mixture of water and triethanolamine with a platinum co-catalyst. Based on (TD-)DFT calculations, the highest performance was expected for CTF-1 and this discrepancy is explained by a trade-off between increased light absorption and decreased thermodynamic driving force.

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Metadata

Authors
Meier, C. B., Sprick, R. S., Monti, A., Guiglion, P., Lee, J.-S. M., Zwijnenburg, M. A., & Cooper, A. I.
Venue
Polymer
Publisher
Elsevier BV
Published
2017-09
Volume
126
Pages
283-290
ISSN
0032-3861 (ISSN-L)
OpenAlex
W2604620129
Cited by
169
References
3
FWCI
8.92
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water. https://app.cochat.ai/papers/10.1016/j.polymer.2017.04.017
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Meier, C. B., Sprick, R. S., Monti, A., Guiglion, P., Lee, J.-S. M., Zwijnenburg, M. A., & Cooper, A. I. (2017). Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water. Polymer. https://doi.org/10.1016/j.polymer.2017.04.017

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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