The DOI matches its Crossref record; 58 of the 58 references it cites were found in a registry or an index.
Accelerated Discovery of Organic Polymer Photocatalysts for Hydrogen Evolution from Water through the Integration of Experiment and Theory
Open accessAbstract
Abstract Conjugated polymers are an emerging class of photocatalysts for hydrogen production where the large breadth of potential synthetic diversity presents both an opportunity and a challenge. Here, we integrate robotic experimentation with high-throughput computation to navigate the available structure–property space. A total of 6354 co-polymers was considered computationally, followed by the synthesis and photocatalytic characterization of a sub-library of more than 170 co-polymers. This led to the discovery of new polymers with sacrificial hydrogen evolution rates (HERs) of more than 6 mmol g–1 h–1. The variation in HER across the library does not correlate strongly with any single physical property, but a machine-learning model involving four separate properties can successfully describe up to 68% of the variation in the HER data between the different polymers. The four variables used in the model were the predicted electron affinity, the predicted ionization potential, the optical gap, and the dispersibility of the polymer particles in solution, as measured by optical transmittance.
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XGBoost: A Scalable Tree Boosting System
Chen, T., & Guestrin, C. (2016) · Proceedings of the 22nd ACM SIGKDD International Conference on Knowledge Discovery and Data Mining · doi:10.1145/2939672.2939785 · Cited by 54,569
A metal-free polymeric photocatalyst for hydrogen production from water under visible light
Wang, X., Maeda, K., Thomas, A., Takanabe, K., Xin, G., Carlsson, J. M., Domen, K., & Antonietti, M. (2009) · Nature Materials · doi:10.1038/nmat2317 · Cited by 12,532
Heterogeneous photocatalyst materials for water splitting
Kudo, A., & Miseki, Y. (2009) · Chem. Soc. Rev. · doi:10.1039/b800489g · Cited by 10,585
Grimme, S., Bannwarth, C., & Shushkov, P. (2017) · Journal of Chemical Theory and Computation · doi:10.1021/acs.jctc.7b00118 · Cited by 2,022
Wang, X., Maeda, K., Chen, X., Takanabe, K., Domen, K., Hou, Y., Fu, X., & Antonietti, M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809307s · Cited by 1,809
Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water
Wang, X., Chen, L., Chong, S. Y., Little, M. A., Wu, Y., Zhu, W.-H., Clowes, R., Yan, Y., Zwijnenburg, M. A., Sprick, R. S., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0141-5 · Cited by 1,320
Self-citationA tunable azine covalent organic framework platform for visible light-induced hydrogen generation
Vyas, V. S., Haase, F., Stegbauer, L., Savasci, G., Podjaski, F., Ochsenfeld, C., & Lotsch, B. V. (2015) · Nature Communications · doi:10.1038/ncomms9508 · Cited by 1,263
A hydrazone-based covalent organic framework for photocatalytic hydrogen production
Stegbauer, L., Schwinghammer, K., & Lotsch, B. V. (2014) · Chem. Sci. · doi:10.1039/c4sc00016a · Cited by 1,145
Overall water splitting by Pt/g-C3N4photocatalysts without using sacrificial agents
Zhang, G., Lan, Z.-A., Lin, L., Lin, S., & Wang, X. (2016) · Chemical Science · doi:10.1039/c5sc04572j · Cited by 967
Kang, Y., Yang, Y., Yin, L., Kang, X., Liu, G., & Cheng, H. (2015) · Advanced Materials · doi:10.1002/adma.201501939 · Cited by 924
Cited by
Burger, B., Maffettone, P. M., Gusev, V. V., Aitchison, C. M., Bai, Y., Wang, X., Li, X., Alston, B. M., Li, B., Clowes, R., et al. (2020) · Nature · doi:10.1038/s41586-020-2442-2 · Cited by 1,516
Self-citationQian, Y., Han, Y., Zhang, X., Yang, G., Zhang, G., & Jiang, H.-L. (2023) · Nature Communications · doi:10.1038/s41467-023-38884-w · Cited by 448
Liu, L., Gao, M.-Y., Yang, H., Wang, X., Li, X., & Cooper, A. I. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c09979 · Cited by 394
Self-citationSide-chain tuning in conjugated polymer photocatalysts for improved hydrogen production from water
Woods, D. J., Hillman, S. A. J., Pearce, D., Wilbraham, L., Flagg, L. Q., Duffy, W., McCulloch, I., Durrant, J. R., Guilbert, A. A. Y., Zwijnenburg, M. A., et al. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01213k · Cited by 146
Self-citationEdström, K., Dominko, R., Fichtner, M., & Perraud, S. (2020) · doi:10.33063/diva2-1452023 · Cited by 46
Metadata
- Authors
- Bai, Y., Wilbraham, L., Slater, B. J., Zwijnenburg, M. A., Sprick, R. S., & Cooper, A. I.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-10
- Volume
- 141
- Issue
- 22
- Pages
- 9063-9071
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2944219262
- Cited by
- 409
- References
- 58
- FWCI
- 11.03
- Type
- journal article
- Language
- en
- Open access
- hybrid
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