The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Thermal and mechanical properties of chemical crosslinked polylactide (PLA)
Abstract
To improve the thermal stability and mechanical properties of PLA, crosslinking was introduced via chemical treatment of the melt by adding small amounts of crosslinking agent triallyl isocyanurate (TAIC) and dicumyl peroxide (DCP). A series of crosslinked PLA materials with different gel fraction and crosslink density were prepared. The crosslinked PLA samples were characterized by fourier transform infra-red spectrometry (FTIR). The thermal and mechanical properties of samples were also investigated by means of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), tensile testing and dynamic mechanical analysis (DMA). The results showed that the crosslinking of PLA started at a low content of either TAIC or DCP, resulting in a decrease of crystallinity and a significant improvement of the thermal degradation initiation and completion temperatures, which indicated better thermal stability than neat PLA. Crosslinking was also responsible for the improved tensile modulus and tensile strength.
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Cites
A Literature Review of Poly(Lactic Acid)
Garlotta, D. (2001) · Journal of Polymers and the Environment · doi:10.1023/a:1020200822435 · Cited by 3,707
Lewis acid catalyzed polymerization of L-lactide. Kinetics and mechanism of the bulk polymerization
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Thermal and Rheological Properties of Commercial-Grade Poly(Lactic Acid)s
Dorgan, J. R., Lehermeier, H., & Mang, M. (2000) · Journal of Polymers and the Environment · doi:10.1023/a:1010185910301 · Cited by 294
Properties of crosslinked polylactides (PLLA & PDLA) by radiation and its biodegradability
Quynh, T. M., Mitomo, H., Nagasawa, N., Wada, Y., Yoshii, F., & Tamada, M. (2007) · European Polymer Journal · doi:10.1016/j.eurpolymj.2007.03.007 · Cited by 140
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Cited by
Circular economy design considerations for research and process development in the chemical sciences
Clark, J. H., Farmer, T. J., Herrero-Davila, L., & Sherwood, J. (2016) · Green Chemistry · doi:10.1039/c6gc00501b · Cited by 344
Poly(Lactic Acid)-Based Biomaterials: Synthesis, Modification and Applications
Xiao, L., Wang, B., Yang, G., & Gauthier, M. (2012) · Biomedical Science, Engineering and Technology · doi:10.5772/23927 · Cited by 277
Zhao, X., Liu, J., Li, J., Liang, X., Zhou, W., & Peng, S. (2022) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2022.07.091 · Cited by 249
Chemical Modification and Foam Processing of Polylactide (PLA)
Standau, T., Zhao, C., Murillo Castellón, S., Bonten, C., & Altstädt, V. (2019) · Polymers · doi:10.3390/polym11020306 · Cited by 210
Li, Y., Yin, D., Liu, W., Zhou, H., Zhang, Y., & Wang, X. (2020) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2020.07.094 · Cited by 91
Metadata
- Authors
- Yang, S.-L., Wu, Z.-H., Yang, W., & Yang, M.-B.
- Venue
- Polymer Testing
- Publisher
- Elsevier BV
- Published
- 2008-12
- Volume
- 27
- Issue
- 8
- Pages
- 957-963
- ISSN
- 0142-9418 (ISSN-L)
- OpenAlex
- W2078035463
- Cited by
- 412
- References
- 6
- FWCI
- 3.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, S.-L., Wu, Z.-H., Yang, W., & Yang, M.-B. (2008). Thermal and mechanical properties of chemical crosslinked polylactide (PLA). Polymer Testing. https://doi.org/10.1016/j.polymertesting.2008.08.009
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.