Analysis of particles size distributions in Mg(OH)2 precipitation from highly concentrated MgCl2 solutions
Open accessAbstract
Magnesium is a raw material of great importance, which attracted increasing interest in the last years. A promising route is to recover magnesium in the form of Magnesium Hydroxide via precipitation from highly concentrated Mg2+ resources, e.g. industrial or natural brines and bitterns. Several production methods and characterization procedures have been presented in the literature reporting a broad variety of Mg(OH)2 particle sizes. In the present work, a detailed experimental investigation is aiming to shed light on the characteristics of produced Mg(OH)2 particles and their dependence upon the reacting conditions. To this purpose, two T-shaped mixers were employed to tune and control the degree of homogenization of reactants. Particles were analysed by laser static light scattering with and without an anti-agglomerant treatment based on ultrasounds and addition of a dispersant. Zeta potential measurements were also carried out to further assess Mg(OH)2 suspension stability.
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For the concentration-effect tests, Battaglia et al. provided an estimated mixing time of about 2 ms at the chosen flow rate.
“For these operative conditions, Battaglia et al.17 provided an estimated mixing time of about 2 ms.”
From Computational Modeling of Magnesium Hydroxide Precipitation and Kinetics Parameters Identification (2023) · cites this paper as [17]
The effect of flow rates on variance profiles is confirmed quantitatively by empirically estimated mixing times from previous work.
“Furthermore, the effect of flow rates on variance profiles is confirmed quantitatively by empirically estimated mixing times from our previous work17 and reported in Table 1.”
From Computational Modeling of Magnesium Hydroxide Precipitation and Kinetics Parameters Identification (2023) · cites this paper as [17]
Magnesium hydroxide volume-based PSDs show a bimodal distribution of nano-sized and micron-sized aggregates.
“As reported in Figure 5 in Battaglia et al.,17 magnesium hydroxide volume-based PSDs, measured with static light scattering, clearly show a bimodal distribution of nano-sized and micron-sized aggregates.”
From Computational Modeling of Magnesium Hydroxide Precipitation and Kinetics Parameters Identification (2023) · cites this paper as [17]
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- Authors
- Battaglia, G., Romano, S., Raponi, A., Marchisio, D., Ciofalo, M., Tamburini, A., Cipollina, A., & Micale, G.
- Affiliations
- University of Palermo (IT)
- Politecnico di Torino (IT)
- Corresponding author
- Cipollina, A.
- Venue
- Powder Technology
- Publisher
- Elsevier BV
- Published
- 2022-01
- Volume
- 398
- Pages
- 117106
- ISSN
- 0032-5910 (ISSN-L)
- OpenAlex
- W4205147986
- Cited by
- 49
- References
- 50
- Citations by year
- 2026: 12 · 2025: 12 · 2024: 13 · 2023: 7 · 2022: 5
- FWCI
- 2.60
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Powder Technology (publishedVersion, cc-by-nc-nd)
- PORTO@Iris (submittedVersion, cc-by-nc-nd)
- Nova Science Publishers (Nova Science Publishers, Inc.) (submittedVersion, other-oa)
- Funders
- Horizon 2020 (869467)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Magnesium Oxide Properties and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
- Physical Sciences › Materials Science › Materials Chemistry › Layered Double Hydroxides Synthesis and Applications
- Keywords
- magnesium hydroxide, particle size distribution, magnesium recovery, ultrasound, dispersants, suspension stability, zeta potential
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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