The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
A smart safe rechargeable zinc ion battery based on sol-gel transition electrolytes
Abstract
Thermal runaway has been a long-standing safety issue impeding the development of high-energy-density batteries. Physical safety designs such as employing circuit-breakers and fuses to batteries are limited by small operating voltage windows and no resumption of original working condition when it is cooled down. Here we report a smart thermoresponsive polymer electrolyte that can be incorporated inside batteries to prevent thermal runaway via a fast and reversible sol-gel transition, and successfully combine this smart electrolyte with a rechargeable Zn/α-MnO2 battery system. At high temperature, battery operation is inhibited as a result of the increased internal resistance caused by the gelation of liquid electrolyte. After cooling down, the electrolyte is spontaneously reversed to sol state and the electrochemical performance of the battery is restored. More importantly, sol-gel transition enables the smart battery to experience different charge-discharge rates under various temperature levels, providing a smart and active strategy to achieve dynamic and reversible self-protection.
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Huang, Y., Ip, W. S., Lau, Y. Y., Sun, J., Zeng, J., Yeung, N. S. S., Ng, W. S., Li, H., Pei, Z., Xue, Q., et al. (2017) · ACS Nano · doi:10.1021/acsnano.7b03322 · Cited by 352
Self-citationChen, S., Mo, F., Yang, Y., Stadler, F. J., Chen, S., Yang, H., & Ge, Z. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06304j · Cited by 126
Self-citation
Cited by
Flexible Zn‐Ion Batteries: Recent Progresses and Challenges
Yu, P., Zeng, Y., Zhang, H., Yu, M., Tong, Y., & Lu, X. (2019) · Small · doi:10.1002/smll.201804760 · Cited by 566
Wu, K., Huang, J., Yi, J., Liu, X., Liu, Y., Wang, Y., Zhang, J., & Xia, Y. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903977 · Cited by 522
Zinc-ion batteries for stationary energy storage
Gourley, S. W. D., Brown, R., Adams, B. D., & Higgins, D. (2023) · Joule · doi:10.1016/j.joule.2023.06.007 · Cited by 482
Recent Advances in Vanadium‐Based Aqueous Rechargeable Zinc‐Ion Batteries
Liu, S., Kang, L., Kim, J. M., Chun, Y. T., Zhang, J., & Jun, S. C. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000477 · Cited by 481
Principals and strategies for constructing a highly reversible zinc metal anode in aqueous batteries
Han, C., Li, W., Liu, H. K., Dou, S., & Wang, J. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104880 · Cited by 363
Metadata
- Authors
- Mo, F., Li, H., Pei, Z., Liang, G., Ma, L., Yang, Q., Wang, D., Huang, Y., & Zhi, C.
- Venue
- Science Bulletin
- Publisher
- Elsevier BV
- Published
- 2018-08
- Volume
- 63
- Issue
- 16
- Pages
- 1077-1086
- ISSN
- 2095-9273 (ISSN-L)
- OpenAlex
- W2833952088
- Cited by
- 182
- References
- 2
- FWCI
- 7.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mo, F., Li, H., Pei, Z., Liang, G., Ma, L., Yang, Q., Wang, D., Huang, Y., & Zhi, C. (2018). A smart safe rechargeable zinc ion battery based on sol-gel transition electrolytes. Science Bulletin. https://doi.org/10.1016/j.scib.2018.06.019
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