Non-crystallizing solvent mixtures and lithium electrolytes for low temperatures
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Kasprzyk et al. prepared a non-crystallizing solvent by mixing EC with PEG250; the mixture exhibited a super low glass transition temperature from -93 to -95 °C and an ionic conductivity of 0.014 mS cm-1 at -60 °C.
“Recently, Kasprzyk et al. [73] prepared a new type of non-crystallizing solvent by mixing EC with poly(ethylene glycol) dimethyl ether (PEG250).Because of the special interactions between planar EC and PEG250 chain, this mixture exhibited a super low glass transition temperature in the range from -93 to -95 °C, and an ionic conductivity of 0.014 mS cm -1 at -60 °C.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [73]
Cites
Electrolytes for Low‐Temperature Lithium Batteries Based on Ternary Mixtures of Aliphatic Carbonates
Smart, M. C., Ratnakumar, B. V., & Surampudi, S. (1999) · Journal of The Electrochemical Society · doi:10.1149/1.1391633 · Cited by 339 · see citing works
Smart, M. C., Ratnakumar, B. V., & Surampudi, S. (2002) · Journal of The Electrochemical Society · doi:10.1149/1.1453407 · Cited by 234 · see citing works
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Jiang, K., Liao, G., Jiaqiang, E., Zhang, F., Chen, J., & Leng, E. (2020) · Journal of Energy Storage · doi:10.1016/j.est.2020.101816 · Cited by 178 · see citing works
Lithium-ion batteries for low-temperature applications: Limiting factors and solutions
Belgibayeva, A., Rakhmetova, A., Rakhatkyzy, M., Kairova, M., Mukushev, I., Issatayev, N., Kalimuldina, G., Nurpeissova, A., Sun, Y.-K., & Bakenov, Z. (2023) · Journal of Power Sources · doi:10.1016/j.jpowsour.2022.232550 · Cited by 141 · see citing works
Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries
Tan, S., Shadike, Z., Cai, X., Lin, R., Kludze, A., Borodin, O., Lucht, B. L., Wang, C., Hu, E., Xu, K., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00199-1 · Cited by 118 · see citing works
“Recently, Kasprzyk et al. [73] prepared a new type of non-crystallizing solvent by mixing EC with poly(ethylene glycol) dimethyl ether (PEG250).”
Extending the low temperature operational limit of Li-ion battery to −80 °C
Xu, J., Wang, X., Yuan, N., Ding, J.-N., Qin, S., Razal, J., Wang, X., Ge, S., & Gogotsi, Y. (2019) · Energy Storage Materials · doi:10.1016/j.ensm.2019.04.033 · Cited by 113 · see citing works
Su, X., Xu, Y., Wu, Y.-C., Li, H.-J., Yang, J., Liao, Y., Qu, R., & Zhang, Z.-C. (2023) · Energy Storage Materials · doi:10.1016/j.ensm.2023.01.044 · Cited by 100 · see citing works
The experimental evaluation of lithium ion batteries after flash cryogenic freezing
Grandjean, T. R. B., Groenewald, J., & Marco, J. (2019) · Journal of Energy Storage · doi:10.1016/j.est.2018.11.027 · Cited by 67 · see citing works
“Despite new mixtures exhibiting a glass transition that takes place at temperatures below − 70 °C, most stateof-the-art electrolytes crystallise at temperatures below − 40 °C [58].”
BackgroundLin, W., Zhu, M., Fan, Y., Wang, H., Tao, G., Ding, M., Liu, N., Yang, H., Wu, J., Fang, J., et al. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.164163 · Cited by 64 · see citing works
Cycle life of lithium ion batteries after flash cryogenic freezing
Grandjean, T. R. B., Groenewald, J., McGordon, A., & Marco, J. (2019) · Journal of Energy Storage · doi:10.1016/j.est.2019.100804 · Cited by 35 · see citing works
A Dual Ionic Liquid-Based Low-Temperature Electrolyte System.
Xu, Y.-F., Lin, W. J., Gliege, M. E., Gunckel, R., Zhao, Z.-F., Yu, H.-Y., & Dai, L. L. (2018) · Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.8b08815 · Cited by 13 · see citing works
Królikowski, M., Kasprzyk-Niedzicka, M., Królikowska, M., & Gąsiorowska, B. (2022) · Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2022.106747 · Cited by 5
Sulfone additive enhanced ultrahigh energy density Li/CFx primary batteries
Zhang, H., Zou, J.-L., Shen, Z., Liu, Z.-M., Hu, L., Yue, H.-J., Chen, H.-X., Wu, Y., Huang, S., Li, Z., et al. (2025) · Journal of Power Sources · doi:10.1016/j.jpowsour.2024.236098 · Cited by 3
Kasprzyk, M., Zalewska, A., & Wieczorek, W. (2020) · doi:10.1021/acs.jpcc.9b10655 · Cited by 3
Self-citationThe Chemistry of Lithium Alkyl Carbonates in the Graphite SEI of Lithium-Ion Batteries
Holthuijsen, M., & Hall, D. S. (2026) · ACS Applied Energy Materials · doi:10.1021/acsaem.6c00933 · Cited by 2
Liu, X.-Y., Liu, S.-M., Zhang, J.-L., Ding, W.-Y., & Dong, C. (2026) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2026.191711
Li, Z.-L., Wu, L., Hwang, B., & Jiang, J. (2025) · Electrochimica Acta · doi:10.1016/j.electacta.2025.146802
Kasprzyk, M., Tymejczyk, M., Zalewska, A., Broszkiewicz, M., & Pyzik, M. (2025) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2025.127949
Self-citation
- Authors
- Kasprzyk, M., Zalewska, A., Niedzicki, L., Bitner, A., Marcinek, M., & Wieczorek, W.
- Affiliations
- Warsaw University of Technology (PL)
- Corresponding author
- Kasprzyk, Marta
- Venue
- Solid State Ionics
- Publisher
- Elsevier BV
- Published
- 2017-10
- Volume
- 308
- Pages
- 22-26
- ISSN
- 0167-2738 (ISSN-L)
- OpenAlex
- W2617100621
- Cited by
- 19
- References
- 0
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 2 · 2023: 2 · 2022: 4 · 2020: 3 · 2019: 2 · 2018: 2
- FWCI
- 0.80
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Solid State Ionics (publishedVersion)
- Funders
- National Science Centre (DEC-ODW1/2013/09/N/ST5/00875)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- low-temperature lithium-ion batteries, mixed solvents, ethylene carbonate, poly(ethylene glycol) dimethyl ether, glass transition, LiPF6, ionic conductivity, electrochemical stability window
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