Cited by 35Organic Electronics and PhotovoltaicsPhotodynamic Therapy Research StudiesOrganic Light-Emitting Diodes Research

Improving efficiencies by modulating the central metal ion in porphyrin-oligothiophene-mediated P3HT/PCBM organic solar cells

Lyons, Dani M., Kesters, Jurgen, Maes, Wouter, Bielawski, Christopher W., Sessler, Jonathan L.·2013·Synthetic Metals

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Crossref · 10.1016/j.synthmet.2013.06.013

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  • Cu-based porphyrins (I14 and I19) showed the best results, while their free-base counterparts (I11 and I16) gave the lowest performance.

    “Cu-based porphyrins ( I14 and I19 ) showed the best results, while their free-base counterparts ( I11 and I16 ) gave the lowest performance.”
  • Weight ratios of 1-10% were tried, and noticeable changes were observed in the efficiency and output parameters.

    “Weight ratios of 1 -10% were tried, and noticeable changes were observed in the e ffi ciency and output parameters.”
  • This indicates the importance of the central metal.

    “This indicates the importance of the central metal.”
  • On a general basis, the effectiveness of these sensitizers was increased in the following order of 2H < Co < Zn < Ni < Cu.

    “On a general basis, the e ff ectiveness of these sensitizers was increased in the following order of 2H &lt; Co &lt; Zn &lt; Ni &lt; Cu.”

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Authors
Lyons, D. M., Kesters, J., Maes, W., Bielawski, C. W., & Sessler, J. L.
Affiliations
  • The University of Texas at Austin (US)
  • Hasselt University (BE)
  • Seoul National University (KR)
  • Yonsei University (KR)
Corresponding author
Sessler, Jonathan L.
Venue
Synthetic Metals
Publisher
Elsevier BV
Published
2013-08
Volume
178
Pages
56-61
ISSN
0379-6779 (ISSN-L)
OpenAlex
W1967336119
Cited by
35
References
0
Citations by year
2025: 1 · 2024: 3 · 2023: 2 · 2022: 3 · 2021: 2 · 2020: 4 · 2019: 4 · 2018: 2 · 2017: 2 · 2016: 3 · 2015: 6 · 2014: 3
FWCI
2.40
Type
journal article
Language
en
Open access
closed
Locations
  • Synthetic Metals (publishedVersion)
  • Document Server@UHasselt (UHasselt) (submittedVersion)
  • Scholarworks@UNIST (Ulsan National Institute of Science and Technology) (submittedVersion)
Funders
  • National Science Foundation (CHE-1057904)
  • Welch Foundation (F-0046, F-1018, R31-10013, R32-10217)
  • National Research Foundation of Korea
  • Ministry of Education, Science and Technology
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
  • Health Sciences › Medicine › Pulmonary and Respiratory Medicine › Photodynamic Therapy Research Studies
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
Keywords
organic solar cells, P3HT:PCBM, bulk heterojunction, metalloporphyrins, central metal ion, copper(II) porphyrin, terthiophene, power conversion efficiency, free-base porphyrin

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