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Water as an efficient medium for the synthesis of cyclic carbonate
Open accessAbstract
Herein, we report a novel method for the synthesis of cyclic carbonate in water. By tuning the amount of water, cycloaddition Of CO(2) to epoxide in aqueous medium leads to cyclic carbonates with moderate to excellent yields and high selectivities. In addition, the presence of water could remarkably improve the activity of ionic liquids by which the turnover frequency of the reaction is about 4-5 times higher in the presence than in the absence of water. The relationship between the higher catalytic reactivity and water was proposed. (c) 2008 Elsevier Ltd. All rights reserved.
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Citations
Cited by
Sustainable conversion of carbon dioxide: the advent of organocatalysis
Fiorani, G., Guo, W., & Kleij, A. W. (2015) · Green Chemistry · doi:10.1039/c4gc01959h · Cited by 658
Alves, M., Grignard, B., Mereau, R., Jerome, C., Tassaing, T., & Detrembleur, C. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy00438a · Cited by 531
Recent advances in the synthesis of cyclic carbonates via CO2 cycloaddition to epoxides
Rehman, A., Saleem, F., Javed, F., Ikhlaq, A., Ahmad, S. W., & Harvey, A. (2021) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2021.105113 · Cited by 281
Metadata
- Authors
- Sun, J., Ren, J., Zhang, S., & Cheng, W.
- Venue
- Tetrahedron Letters
- Publisher
- Elsevier BV
- Published
- 2009-01
- Volume
- 50
- Issue
- 4
- Pages
- 423-426
- ISSN
- 0040-4039 (ISSN-L)
- OpenAlex
- W1997077472
- Cited by
- 273
- References
- 0
- FWCI
- 10.55
- Type
- journal article
- Language
- en
- Open access
- green
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- Sun, J., Ren, J., Zhang, S., & Cheng, W. (2009). Water as an efficient medium for the synthesis of cyclic carbonate. Tetrahedron Letters. https://doi.org/10.1016/j.tetlet.2008.11.034
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