Sonolytic degradation of bisphenol S: Effect of dissolved oxygen and peroxydisulfate, oxidation products and acute toxicity
Abstract
In this paper, the kinetics of bisphenol S (BPS) degradation in the presence of peroxydisulfate (PDS) or dissolved oxygen (DO) in ultrasound (US) system were investigated. For PDS (US/PDS), increased PDS concentration result in faster BPS degradation, but the enhancement was not remarkable with multiplying PDS dosages. Therefore, heterogeneous PDS activation model based on a Langmuir-type adsorption mechanism was proposed to explain the trait of BPS abatement. The equilibrium constant of PDS (K PDS) was calculated to be 2.91 × 10-4/μM, which was much lower than that of BPS, suggesting that PDS was hard to adsorb on the gas-liquid interface of the cavitation bubble following by activation. Besides, the formation of •OH and SO 4•- in US/PDS system was reinvestigated. The result showed that SO 4•- rather than •OH was the predominant radical, which was quite different from previous study. Dissolved oxygen largely improve the degradation of BPS in US system and •OH rather than O 2•- was proved to be the main reactive oxygen species (ROS). The improvement of •OH generation possibly caused by the reaction of DO with •H so that it cannot recombine with •OH. The transformation of the BPS in US system mainly included BPS radical polymerization, hydroxylation and hydrolysis. Frustratingly, the acute toxicity assay of Vibrio fischeri suggests that the degradation products of BPS are more toxic. These results will improve the understanding on the activation mechanisms of PDS and the role of dissolved oxygen play in US. Further investigations may need to explore other treatment ways of BPS and evaluate the acute toxicity of degradation products.
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Similar results, i.e., an enhancement in degradation at lower pollutant concentrations, were reported for bisphenol S, DEET, 4-cumylphenol, etc.
“Similar results, i.e., an enhancement in the degradation at lower pollutant concentrations, was reported for bisphenol S, N,N-Diethyl-meta-toluamide (DEET), 4-cumylphenol, etc. [104-106].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [105]
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- Authors
- Lu, X., Zhao, J., Wang, Q., Wang, D., Xu, H., Ma, J., Qiu, W., & Hu, T.
- Affiliations
- Harbin Institute of Technology (CN)
- Southwest Jiaotong University (CN)
- Corresponding author
- Wang, Qun
- Ma, Jun
- Venue
- Water Research
- Publisher
- Elsevier BV
- Published
- 2019-11
- Volume
- 165
- Pages
- 114969
- ISSN
- 0043-1354 (ISSN-L)
- OpenAlex
- W2969104980
- Cited by
- 85
- References
- 66
- Citations by year
- 2026: 3 · 2025: 7 · 2024: 9 · 2023: 8 · 2022: 18 · 2021: 24 · 2020: 16
- FWCI
- 5.25
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Water Research (publishedVersion)
- PubMed (publishedVersion)
- Funders
- State Key Laboratory of Urban Water Resource and Environment
- Key Technologies Research and Development Program
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Materials Science › Materials Chemistry › Ultrasound and Cavitation Phenomena
- Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
- Keywords
- bisphenol S, sonochemical degradation, persulfate activation, dissolved oxygen, Langmuir adsorption, cavitation bubbles, sulfate radicals, hydroxyl radicals, reactive oxygen species, degradation kinetics, degradation products, acute toxicity, Vibrio fischeri, radical polymerization, hydroxylation, hydrolysis
- MeSH terms
- Bisphenol S Compounds, Oxidation-Reduction, Oxygen, Phenols, Sulfones, Water Pollutants, Chemical
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