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Adsorption of textile dyes on raw and decanted Moroccan clays: Kinetics, equilibrium and thermodynamics

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Elmoubarki, R., Mahjoubi, F.Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., El Albani, A., Barka, N.·2015·Water Resources and Industry

Abstract

Inexpensive and easily available Moroccan natural clays were investigated for the removal availability of textile dyes from aqueous solution. For this purpose, the adsorption of methylene blue (MB) as reference molecule, malachite green (MG) representative of cationic dyes and methyl orange (MO) representative of anionic dyes, was studied in batch mode under various parameters. The clays were characterized by means of XRD, cationic exchange capacity and BET surface area analysis. The experimental results show that, the adsorption was pH dependent with a high adsorption capacity of MB and MG in basic range and high adsorption of MO in acidic range. The pseudo-second-order kinetic model provided the best fit to the experimental data for the adsorption of MB and MG by the clays. However, the adsorption of MO was more suitable to be controlled by an intra-particle diffusion mechanism. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Dubinin–Radushkevich isotherm models. The adsorption process was found to be exothermic in nature in the case of MB and MO. However, the adsorption of MG was endothermic.

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Metadata

Authors
Elmoubarki, R., Mahjoubi, F. Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., El Albani, A., & Barka, N.
Venue
Water Resources and Industry
Publisher
Elsevier BV
Published
2015-03
Volume
9
Pages
16-29
ISSN
2212-3717 (ISSN-L)
OpenAlex
W2031715809
Cited by
324
References
26
FWCI
15.36
Type
journal article
Language
en
Open access
gold

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The paper
Elmoubarki, R., Mahjoubi, F. Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., El Albani, A., & Barka, N. (2015). Adsorption of textile dyes on raw and decanted Moroccan clays: Kinetics, equilibrium and thermodynamics. Water Resources and Industry. https://doi.org/10.1016/j.wri.2014.11.001

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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