An experimental study of calcite and limestone dissolution rates as a function of pH from −1 to 3 and temperature from 25 to 80°C
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The initial dissolution was pH-controlled.
“The notable pH variation showed that the initial dissolution was pH-controlled [20, 32].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [32]
Cites
Activity Coefficients in Electrolyte Solutions
Pitzer, K. S. (2018) · CRC Press eBooks · doi:10.1201/9781351069472 · Cited by 2,499 · see citing works
Plummer, L. N., & Busenberg, E. (1982) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(82)90056-4 · Cited by 1,886 · see citing works
Helgeson, H. C., Kirkham, D. H., & Flowers, G. C. (1981) · American Journal of Science · doi:10.2475/ajs.281.10.1249 · Cited by 1,781 · see citing works
Plummer, L. N., Wigley, T. M. L., & Parkhurst, D. L. (1978) · American Journal of Science · doi:10.2475/ajs.278.2.179 · Cited by 1,190 · see citing works
Wedborg, M., Turner, D. R., Anderson, L. G., & Dyrssen, D. W. (1999) · doi:10.1002/9783527613984.ch7 · Cited by 1,162 · see citing works
The role of magnesium in the crystal growth of calcite and aragonite from sea water
Berner, R. A. (1975) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(75)90102-7 · Cited by 807 · see citing works
Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals
Chou, L., Garrels, R. M., & Wollast, R. (1989) · Chemical Geology · doi:10.1016/0009-2541(89)90063-6 · Cited by 709 · see citing works
A surface complexation model of the carbonate mineral-aqueous solution interface
Cappellen, P. V., Charlet, L., Stumm, W., & Wersin, P. (1993) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(93)90135-j · Cited by 555 · see citing works
The thermodynamics of the carbonate system in seawater
Millero, F. J. (1979) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(79)90184-4 · Cited by 545 · see citing works
The Physical Chemistry of Seawater
Millero, F. J. (1974) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev.ea.02.050174.000533 · Cited by 408 · see citing works
Midgley, D. (1991) · Talanta · doi:10.1016/0039-9140(91)80158-v · Cited by 401 · see citing works
The geochemistry of some carbonate ground waters in central Pennsylvania
Langmuir, D. (1971) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(71)90019-6 · Cited by 393 · see citing works
Dissolution kinetics of calcium carbonate in sea water; IV, Theory of calcite dissolution
Berner, R. A., & Morse, J. W. (1974) · American Journal of Science · doi:10.2475/ajs.274.2.108 · Cited by 386 · see citing works
The dissolution kinetics of feldspars at 25°C and 1 atm CO2 partial pressure
Busenberg, E., & Clemency, C. V. (1976) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(76)90192-7 · Cited by 330 · see citing works
Acidization—II. The dissolution of calcite in hydrochloric acid
Lund, K., Fogler, H. S., McCune, C. C., et al. (1975) · Chemical Engineering Science · doi:10.1016/0009-2509(75)80047-9 · Cited by 311 · see citing works
Bühmann, D., & Dreybrodt, W. (1985) · Chemical Geology · doi:10.1016/0009-2541(85)90024-5 · Cited by 299 · see citing works
Critical Review of the Kinetics of Calcite Dissolution and Precipitation
Plummer, L. N., Parkhurst, D. L., & Wigley, T. M. L. (1979) · ACS symposium series · doi:10.1021/bk-1979-0093.ch025 · Cited by 296 · see citing works
Buhmann, D., & Dreybrodt, W. (1985) · Chemical Geology · doi:10.1016/0009-2541(85)90046-4 · Cited by 279 · see citing works
The Optimum Injection Rate for Matrix Acidizing of Carbonate Formations
Wang, Y., Hill, A. D., & Schechter, R. (1993) · SPE Annual Technical Conference and Exhibition · doi:10.2118/26578-ms · Cited by 275 · see citing works
Busenberg, E., & Plummer, L. N. (1982) · American Journal of Science · doi:10.2475/ajs.282.1.45 · Cited by 274 · see citing works
The dissolution of calcite in CO2-saturated solutions at 25°C and 1 atmosphere total pressure
Plummer, L. N., & Wigley, T. M. L. (1976) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(76)90176-9 · Cited by 263 · see citing works
The kinetics of calcium carbonate dissolution and precipitation
Morse, J. W. (1983) · Reviews in Mineralogy and Geochemistry · Cited by 261 · see citing works
The role of dislocations and surface morphology in calcite dissolution
MacInnis, I. N., & Brantley, S. L. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90049-o · Cited by 247 · see citing works
Carbonate Acidizing: Toward a Quantitative Model of the Wormholing Phenomenon
Daccord, G., Touboul, É., & Lenormand, R. (1989) · SPE Production Engineering · doi:10.2118/16887-pa · Cited by 245 · see citing works
Predicting mineral solubility from rate data; application to the dissolution of magnesian calcites
Plummer, L. N., & Mackenzie, F. T. (1974) · American Journal of Science · doi:10.2475/ajs.274.1.61 · Cited by 239 · see citing works
Sjöberg, E. L., & Rickard, D. T. (1984) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(84)90276-x · Cited by 230 · see citing works
Dissolution kinetics of strained calcite
Jacques Schott, A., Brantley, S. L., Crerar, D. A., Guy, C., Borcsik, M. P., & Willaime, C. (1989) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(89)90389-x · Cited by 224 · see citing works
Thorstenson, D. C., & Plummer, L. N. (1977) · American Journal of Science · doi:10.2475/ajs.277.9.1203 · Cited by 224 · see citing works
Ion Interaction Approach: Theory and Data Correlation
Pitzer, K. S. (2018) · CRC Press eBooks · doi:10.1201/9781351069472-3 · Cited by 221 · see citing works
A fundamental equation for calcite dissolution kinetics
Sjöberg, E. (1976) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(76)90009-0 · Cited by 208 · see citing works
731. Transport to the surface of a rotating disc
Gregory, D. P., & Riddiford, A. C. (1956) · Journal of the Chemical Society (Resumed) · doi:10.1039/jr9560003756 · Cited by 205 · see citing works
Dreybrodt, W., Lauckner, J., Liu, Z., Svensson, U., & Bühmann, D. (1996) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(96)00181-0 · Cited by 205 · see citing works
Liu, Z., & Dreybrod, W. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00143-9 · Cited by 204 · see citing works
Pleskov, Y. V., & Filinovskii, V. Y. (1976) · Springer eBooks · doi:10.1007/978-1-4615-8561-9 · Cited by 196 · see citing works
A Mechanistic Model of Wormhole Growth in Carbonate Matrix Acidizing and Acid Fracturing
Hung, K. M., Hill, A. D., & Sepehrnoori, K. (1989) · Journal of Petroleum Technology · doi:10.2118/16886-pa · Cited by 192 · see citing works
Multisite surface reaction versus transport control during the hydrolysis of a complex oxide
Guy, C., & Schott, J. (1989) · Chemical Geology · doi:10.1016/0009-2541(89)90057-0 · Cited by 189 · see citing works
Self-citationCalcite dissolution kinetics: Surface speciation and the origin of the variable pH dependence
Sjöberg, E., & Rickard, D. T. (1984) · Chemical Geology · doi:10.1016/0009-2541(84)90009-3 · Cited by 185 · see citing works
The Interaction of Phosphate with Calcite
Griffin, R. A., & Jurinak, J. J. (1973) · Soil Science Society of America Journal · doi:10.2136/sssaj1973.03615995003700060018x · Cited by 184 · see citing works
Mucci, A. O. (1986) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(86)90080-3 · Cited by 173 · see citing works
The thermodynamics of seawater at one atmosphere
Millero, F. J., & Leung, W. H. (1976) · American Journal of Science · doi:10.2475/ajs.276.9.1035 · Cited by 161 · see citing works
Mixed kinetic control of calcite dissolution rates
Rickard, D. T., & Sjoeberg, E. L. (1983) · American Journal of Science · doi:10.2475/ajs.283.8.815 · Cited by 154 · see citing works
Oelkers, É. H., & Helgeson, H. C. (1988) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(88)90057-9 · Cited by 149 · see citing works
Dissolution kinetics of calcium carbonate in sea water; I, A kinetic origin for the lysocline
Morse, J. W., & Berner, R. A. (1972) · American Journal of Science · doi:10.2475/ajs.272.9.840 · Cited by 143 · see citing works
Murphy, W. M., Oelkers, É. H., & Lichtner, P. C. (1989) · Chemical Geology · doi:10.1016/0009-2541(89)90069-7 · Cited by 118 · see citing works
Alkattan, M., Oelkers, É. H., Dandurand, J.-L., et al. (1997) · Chemical Geology · doi:10.1016/s0009-2541(96)00164-7 · Cited by 118 · see citing works
Self-citationNon-equilibrium water/rock interactions—I. Model for interface-controlled reactions
Dibble, W. E., & Tiller, W. A. (1981) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(81)90265-9 · Cited by 107 · see citing works
Kinetics and mechanism of calcite dissolution in aqueous solutions at low temperatures
Sjöberg, E. (1978) · Cited by 106 · see citing works
Fluid-Velocity and Reaction-Rate Effects During Carbonate Acidizing: Application of Network Model
Hoefner, M. L., & Fogler, H. S. (1989) · SPE Production Engineering · doi:10.2118/15573-pa · Cited by 99 · see citing works
Arakaki, T., & Mucci, A. O. (1995) · Aquatic Geochemistry · doi:10.1007/bf01025233 · Cited by 95 · see citing works
The influence of experimental design on the rate of calcite dissolution
Sjöberg, E., & Rickard, D. T. (1983) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(83)90051-0 · Cited by 94 · see citing works
Плесков, Ю. В., Filinovskii, V. Y., Wroblowa, H. S., et al. (1976) · Medical Entomology and Zoology · Cited by 89 · see citing works
Calcium carbonate retention in supersaturated seawater
Pytkowicz, R. M. (1973) · American Journal of Science · doi:10.2475/ajs.273.6.515 · Cited by 81 · see citing works
The Effect of Wormholing on the Fluid-Loss Coefficient in Acid Fracturing
Hill, A. D., Zhu, D., & Wang, Y. (1995) · SPE Production & Facilities · doi:10.2118/27403-pa · Cited by 80 · see citing works
Stability of calcite based on aqueous solubility measurements
Langmuir, D. (1968) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(68)90099-9 · Cited by 77 · see citing works
The dissolution of calcite in aqueous solution at pH < 4: kinetics and mechanism
Compton, R. G., & Unwin, P. R. (1990) · Philosophical Transactions of the Royal Society of London Series A Mathematical and Physical Sciences · doi:10.1098/rsta.1990.0001 · Cited by 69 · see citing works
Kinetics of the dissolution of calcite and its applications to karstification
Dreybrodt, W. (1980) · Chemical Geology · doi:10.1016/0009-2541(80)90089-3 · Cited by 64 · see citing works
The effect of added dissolved calcium on calcite dissolution kinetics in aqueous solutions at 25°C
Sjöberg, E., & Rickard, D. T. (1985) · Chemical Geology · doi:10.1016/0009-2541(85)90002-6 · Cited by 56 · see citing works
Equilibrium, kinetics, and the precipitation of magnesian calcite from seawater; discussion
Berner, R. A. (1978) · American Journal of Science · doi:10.2475/ajs.278.10.1475 · Cited by 52 · see citing works
The dissolution of calcite at pH > 7: kinetics and mechanism
Compton, R. G., & Pritchard, K. L. (1990) · Philosophical Transactions of the Royal Society of London Series A Mathematical and Physical Sciences · doi:10.1098/rsta.1990.0002 · Cited by 43 · see citing works
Kinetics of Calcite Dissolution as Affected by Carbon Dioxide Partial Pressure
Amrhein, C., Jurinak, J. J., & Moore, W. M. (1985) · Soil Science Society of America Journal · doi:10.2136/sssaj1985.03615995004900060012x · Cited by 43 · see citing works
An Overview of Current Acid Fracturing Technology with Recent Implications for Emulsified Acids
Li, Y., Sullivan, R. B., de Rozières, J., et al. (1993) · SPE Annual Technical Conference and Exhibition · doi:10.2118/26581-ms · Cited by 40 · see citing works
Chemistry of Calcium Carbonate in the Deep Oceans
Morse, J. W., & BERNER, R. C. (1979) · ACS symposium series · doi:10.1021/bk-1979-0093.ch024 · Cited by 40 · see citing works
Mixing corrosion in CaCO3/1bCO2/1bH2O systems and its role in the karstification of limestone areas
Dreybrodt, W. (1981) · Chemical Geology · doi:10.1016/0009-2541(81)90145-5 · Cited by 36 · see citing works
Carbonate cycle and the buffer mechanism of recent oceans
Pytkowicz, R. M. (1967) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(67)90098-1 · Cited by 36 · see citing works
Morse, J. W., de Kanel, J., & Harris, K. (1979) · American Journal of Science · doi:10.2475/ajs.279.5.488 · Cited by 35 · see citing works
Equilibria, nonequilibria, and natural waters
Pytkowicz, R. M. (1983) · Wiley eBooks · Cited by 34 · see citing works
On the Design of Fracture Acidizing Treatments
Gdanski, R., & Lee, W. S. (1989) · SPE Production Operations Symposium · doi:10.2118/18885-ms · Cited by 34 · see citing works
Alkattan, M., Oelkers, É. H., Dandurand, J.-L., et al. (1997) · Chemical Geology · doi:10.1016/s0009-2541(97)00097-1 · Cited by 27 · see citing works
Self-citationDomelen, M. S. V. (1992) · International Meeting on Petroleum Engineering · doi:10.2118/22393-ms · Cited by 21 · see citing works
Equilibrium Acid Fracturing: A New Fracture Acidizing Technique for Carbonate Formations
Tinker, S. J. (1991) · SPE Production Engineering · doi:10.2118/18883-pa · Cited by 10 · see citing works
Alkattan, M. (1996) · Cited by 4 · see citing works
Self-citationEquilibrium Acid Fracturing: A New Fracture Acidizing Technique for Carbonate Formations
Tinker, S. J. (1989) · SPE Production Operations Symposium · doi:10.2118/18883-ms · Cited by 4 · see citing works
A new american compilation of physics data
Bates, L. F. (1973) · Contemporary Physics · doi:10.1080/00107517308210768 · Cited by 2 · see citing works
Mixed cinetic control of calcite dissolution
Sjöberg, E. (1983) · Sciences Géologiques, bulletins et mémoires · Cited by 1 · see citing works
Sibley, D. F., Dedoes, R. E., & Bartlett, T. R. (1987) · Geology · doi:10.1130/0091-7613(1987)15
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Dissolution kinetics of calcite, dolomite and magnesite at 25 °C and 0 to 50 atm pCO2
Pokrovsky, O. S., Golubev, S. V., & Schott, J. (2005) · Chemical Geology · doi:10.1016/j.chemgeo.2004.12.012 · Cited by 423 · see citing works
Self-citationPokrovsky, O. S., & Schott, J. (1999) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00013-7 · Cited by 153 · see citing works
Spatio-temporal assembly of functional mineral scaffolds within microbial biofilms
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Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C
Zhu, Y., Nong, P., Mo, N., Zhu, Z., Deng, H., Tang, S., Yang, H., Zhang, L., & Wang, X. (2021) · Geochemical Transactions · doi:10.1186/s12932-021-00075-1 · Cited by 11 · see citing works
“The notable pH variation showed that the initial dissolution was pH-controlled [20, 32].”
Background
- Authors
- Alkattan, M., Oelkers, E. H., Dandurand, J.-L., & Schott, J.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Alkattan, Marwan
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 1998-10
- Volume
- 151
- Issue
- 1-4
- Pages
- 199-214
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2068349868
- Cited by
- 235
- References
- 76
- Citations by year
- 2026: 5 · 2025: 12 · 2024: 11 · 2023: 7 · 2022: 11 · 2021: 14 · 2020: 14 · 2019: 12 · 2018: 8 · 2017: 8 · 2016: 9 · 2015: 13 · 2014: 10 · 2013: 13 · 2012: 13
- FWCI
- 1.75
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- UCL Discovery (University College London) (submittedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Physical Sciences › Earth and Planetary Sciences › Earth-Surface Processes › Karst Systems and Hydrogeology
- Keywords
- calcite dissolution, limestone dissolution, dissolution rate, pH dependence, temperature dependence, apparent rate constant, activation energy, rotating disk, hydrochloric acid solutions
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