Morphology and mechanical properties of poly (methylmethacrylate)-b-poly (alkylacrylate)-b-poly (methylmethacrylate)

Tong, J.D; Leclère, Ph; Doneux, C; Brédas, J.L; Lazzaroni, R; Jérôme, R

doi:10.1016/s0032-3861(00)00759-x

Cited by 49Block Copolymer Self-AssemblyPolymer crystallization and propertiesAdvanced Polymer Synthesis and Characterization

Morphology and mechanical properties of poly (methylmethacrylate)-b-poly (alkylacrylate)-b-poly (methylmethacrylate)

Open access

Tong, J.D, Leclère, Ph, Doneux, C, Brédas, J.L, Lazzaroni, R, Jérôme, R·2001·Polymer

DOI 10.1016/s0032-3861(00)00759-x

Open this paper in CoChat — free account Open PDF

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Integrity signals

Registry

Crossref · 10.1016/s0032-3861(00)00759-x

Cites

44 of 44 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

The tensile strength of the all acrylic-based high temperature TPEs was lower compared to similar products prepared via living anionic polymerization.
“These TPEs exhibited superior stress-strain behavior compared to that of conventional all acrylic-based TPEs consisting of PMMA and PBA made by controlled radical processes [94], while the tensile strength was lower compared to that of similar products prepared via living anionic polymerization [95].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [95]

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Viscoelastic Properties of Polymers
Ferry, J. D., & Myers, H. S. (1961) · Journal of The Electrochemical Society · doi:10.1149/1.2428174 · Cited by 13,509 · see citing works
Encyclopedia of polymer science and engineering
Mark, H., & Kroschwitz, J. I. (1985) · Wiley eBooks · Cited by 5,877 · see citing works
Encyclopedia of polymer science and engineering
Bawn, C. S. H. (1987) · Polymer · doi:10.1016/0032-3861(87)90274-6 · Cited by 4,223 · see citing works
Theory of Microphase Separation in Block Copolymers
Ludwik Leibler, B. (1980) · Macromolecules · doi:10.1021/ma60078a047 · Cited by 3,929 · see citing works
Block Copolymer Thermodynamics: Theory and Experiment
Bates, F. S., & Fredrickson, G. H. (1990) · Annual Review of Physical Chemistry · doi:10.1146/annurev.pc.41.100190.002521 · Cited by 3,889 · see citing works
Properties of Polymers
Krevelen, D. W. V. (1990) · Cited by 3,264 · see citing works
Theory of Filler Reinforcement
Guth, E. (1945) · Journal of Applied Physics · doi:10.1063/1.1707495 · Cited by 1,244 · see citing works
Phase imaging and stiffness in tapping-mode atomic force microscopy
Magonov, S., Elings, V. B., & Whangbo, M. (1997) · Surface Science · doi:10.1016/s0039-6028(96)01591-9 · Cited by 1,021 · see citing works
Energy dissipation in tapping-mode atomic force microscopy
Cleveland, J. P., Anczykowski, B., Schmid, A. E., & Elings, V. B. (1998) · Applied Physics Letters · doi:10.1063/1.121434 · Cited by 881 · see citing works
Block Copolymer Theory. 4. Narrow Interphase Approximation
Helfand, E., & Wasserman, Z. R. (1976) · Macromolecules · doi:10.1021/ma60054a001 · Cited by 613 · see citing works
Periodic area-minimizing surfaces in block copolymers
Thomas, E. L., Anderson, D. M., Henkee, C. S., & Hoffman, D. (1988) · Nature · doi:10.1038/334598a0 · Cited by 463 · see citing works
Liquid Crystalline Order in Polymers
(1978) · Elsevier eBooks · doi:10.1016/b978-0-121-08650-3.x5001-0 · Cited by 437 · see citing works
Thermoplastic Elastomers
Holden, G. (1987) · Springer eBooks · doi:10.1007/978-1-4615-7823-9_16 · Cited by 436 · see citing works
Rheological Properties of Anionic Polystyrenes. I. Dynamic Viscoelasticity of Narrow-Distribution Polystyrenes
Onogi, S., Masuda, T., & Kitagawa, K. (1970) · Macromolecules · doi:10.1021/ma60014a001 · Cited by 431 · see citing works
Domain-Boundary Structure of Styrene-Isoprene Block Copolymer Films Cast from Solution. 4. Molecular-Weight Dependence of Lamellar Microdomains
Hashimoto, T., Shibayama, M., & Kawai, H. (1980) · Macromolecules · doi:10.1021/ma60077a040 · Cited by 419 · see citing works
Rheology of ordered and disordered symmetric poly(ethylenepropylene)-poly(ethylethylene) diblock copolymers
Rosedale, J. H., & Bates, F. S. (1990) · Macromolecules · doi:10.1021/ma00210a032 · Cited by 390 · see citing works
Domain-Boundary Structure of Styrene-Isoprene Block Copolymer Films Cast from Solutions. 5. Molecular-Weight Dependence of Spherical Microdomains
Hashimoto, T., Fujimura, M., & Kawai, H. (1980) · Macromolecules · doi:10.1021/ma60078a055 · Cited by 294 · see citing works
Surface analysis with STM and AFM : experimental and theoretical aspects of image analysis
Magonov, S., & Whangbo, M. (1996) · Cited by 218 · see citing works
Departures of the elastic behaviour of rubbers in simple extension from the kinetic theory
Gumbrell, S. M., Mullins, L., & Rivlin, R. S. (1953) · Transactions of the Faraday Society · doi:10.1039/tf9534901495 · Cited by 208 · see citing works
Rheological technique for determining the order–disorder transition of block copolymers
Han, C. D., & Kim, J. (1987) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.1987.090250815 · Cited by 198 · see citing works
Effect of Volume Fraction on the Order-Disorder Transition in Low Molecular Weight Polystyrene-block-Polyisoprene Copolymers. 1. Order-Disorder Transition Temperature Determined by Rheological Measurements
Han, C. D., Baek, D. M., Kim, J. K., Ogawa, T., Sakamoto, N., & Hashimoto, T. (1995) · Macromolecules · doi:10.1021/ma00118a038 · Cited by 182 · see citing works
On the Factors Affecting the Contrast of Height and Phase Images in Tapping Mode Atomic Force Microscopy
Brandsch, R., Bar, G., & Whangbo, M. (1997) · Langmuir · doi:10.1021/la970822i · Cited by 162 · see citing works
Synthesis and properties of block polymers. I. Poly-α-methylstyrene-polyisoprene-poly-α-methylstyrene
Fetters, L. J., & Morton, M. (1969) · Macromolecules · doi:10.1021/ma60011a002 · Cited by 161 · see citing works
Living Polymerizations and Copolymerizations of Alkyl Acrylates by the Unique Catalysis of Rare Earth Metal Complexes
Ihara, E., Morimoto, M., & Yasuda, H. (1995) · Macromolecules · doi:10.1021/ma00127a040 · Cited by 160 · see citing works
Domain-Boundary Structure of Styrene-Isoprene Block Copolymer Films Cast from Toluene Solutions
Hashimoto, T., Nagatoshi, K., Todo, A., Hasegawa, H., & Kawai, H. (1974) · Macromolecules · doi:10.1021/ma60039a019 · Cited by 136 · see citing works
Microdomain Morphology Analysis of Block Copolymers by Atomic Force Microscopy with Phase Detection Imaging
Leclère, P. E. L. G., Lazzaroni, R., Brédas, J., et al. (1996) · Langmuir · doi:10.1021/la9600964 · Cited by 126 · see citing works
Self-citation
Structure and properties of tapered block polymers. 4. "Domain-boundary mixing" and "mixing-in-domain" effects on microdomain morphology and linear dynamic mechanical response
Hashimoto, T., Tsukahara, Y., Tachi, K., et al. (1983) · Macromolecules · doi:10.1021/ma00238a031 · Cited by 120 · see citing works
Domain-Boundary Structure of Styrene-Isoprene Block Copolymer Films Cast from Solutions. 2. Quantitative Estimation of the Interfacial Thickness of Lamellar Microphase Systems
Hashimoto, T., Todo, A., Itoi, H., & Kawai, H. (1977) · Macromolecules · doi:10.1021/ma60056a030 · Cited by 113 · see citing works
Preparation and study of block copolymers with ordered structures
Gallot, B. (2007) · Springer eBooks · doi:10.1007/3-540-08886-5_3 · Cited by 113 · see citing works
Dynamic viscoelastic behavior of ABA block polymers and the nature of the domain boundary
Kraus, G., & Rollmann, K. W. (1976) · Journal of Polymer Science Polymer Physics Edition · doi:10.1002/pol.1976.180140615 · Cited by 103 · see citing works
Synthesis, Morphology, and Mechanical Properties of Poly(methyl methacrylate)- b- poly( n -butyl acrylate)- b -poly(methyl methacrylate) Triblocks. Ligated Anionic Polymerization vs Atom Transfer Radical Polymerization
Tong, J. D., Moineau, G., Leclère, P. E. L. G., et al. (1999) · Macromolecules · doi:10.1021/ma990886v · Cited by 96 · see citing works
Self-citation
Synthesis of poly(methyl methacrylate)-b-poly(n-butyl acrylate)-b-poly(methyl methacrylate) triblocks and their potential as thermoplastic elastomers
Tong, J. D., & Jérôme, R. (2000) · Polymer · doi:10.1016/s0032-3861(99)00412-7 · Cited by 71 · see citing works
Self-citation
Structure/chain-flexibility relationships of polymers
Xu, Z., Hadjichristidis, N., Fetters, L. J., et al. (1995) · Advances in polymer science · doi:10.1007/3-540-58704-7_1 · Cited by 65 · see citing works
Effect of Viscoelastic Properties of Polymers on the Phase Shift in Tapping Mode Atomic Force Microscopy
Bar, G., Brandsch, R., & Whangbo, M. (1998) · Langmuir · doi:10.1021/la980969p · Cited by 59 · see citing works
Syndiotactic Poly(methyl methacrylate) (sPMMA)−Polybutadiene (PBD)−sPMMA Triblock Copolymers: Synthesis, Morphology, and Mechanical Properties
Yu, J. M., Dúbois, P., Teyssié, P., et al. (1996) · Macromolecules · doi:10.1021/ma9603950 · Cited by 56 · see citing works
ABA Block Copolymers of Dienes and Cyclic Sulfides
Morton, M., & Mikesell, S. L. (1973) · Journal of Macromolecular Science Part A - Chemistry · doi:10.1080/10601327308060508 · Cited by 45 · see citing works
Direct Observation of Microdomain Morphology in “All-Acrylic” Thermoplastic Elastomers Synthesized via Living Radical Polymerization
Leclère, P. E. L. G., Moineau, G., Minet, M., et al. (1999) · Langmuir · doi:10.1021/la981273z · Cited by 44 · see citing works
Self-citation
Domain‐boundary structure of styrene‐isoprene block copolymer films cast from solutions. III. Preliminary results on spherical microdomains
Todo, A., Hiroyukiuno, Miyoshi, K., et al. (1977) · Polymer Engineering and Science · doi:10.1002/pen.760170816 · Cited by 36 · see citing works
Difunctional Initiator Based on 1,3-Diisopropenylbenzene. 2. Kinetics and Mechanism of the sec-Butyllithium/1,3-Diisopropenylbenzene Reaction
Yu, Y. S., Dúbois, P., Jérôme, R., et al. (1996) · Macromolecules · doi:10.1021/ma951076w · Cited by 31 · see citing works
Self-citation
Morphological characterization of well defined methacrylic based di- and triblock ionomers
Venkateshwaran, L. N., York, G., Deporter, C. D., et al. (1992) · Polymer · doi:10.1016/0032-3861(92)90517-z · Cited by 30 · see citing works
Miscibility of some methacrylate and acrylate homopolymer blends
Cowie, J. M. G., Ferguson, R., Fernández, M. D., et al. (1992) · Macromolecules · doi:10.1021/ma00038a023 · Cited by 29 · see citing works
Rheological behaviour of block copolymers in the disordered state: effects of molecular weight and block length ratio
Han, C., Baek, D. M., Kim, J., & Chu, S. G. (1992) · Polymer · doi:10.1016/0032-3861(92)90986-7 · Cited by 21 · see citing works
Viscoelastic properties of a styrene‐isoprene‐styrene triblock copolymer and its blends with polyisoprene homopolymer and styrene‐isoprene diblock copolymer
Berglund, C. A., & McKay, K. W. (1993) · Polymer Engineering and Science · doi:10.1002/pen.760331807 · Cited by 19 · see citing works
N.m.r. investigation of interphases and microphase composition in (methylmethacrylate)-b-(n-butylacrylate) block copolymers
Soltani, R., Laupretre, F., MONNERIE, L., et al. (1998) · Polymer · doi:10.1016/s0032-3861(97)10273-7 · Cited by 8 · see citing works

Flagged first, then by citations

Research works printed but not linked: 43

Fetters LJ, Morton M. Macromolecules 1969;2(5):453.
Yu Y, Dubois Ph, Jérôme R, Teyssié Ph. Macromolecules 1996; 29:1753 (see also p. 2738).
Yu JM, Dubois Ph, Teyssié Ph, Jérôme R. Macromolecules 1996; 29:6090.
Cowie JMG, Ferguson R, Fernandez MD, Fernandez MJ, McEwen IJ. Macromolecules 1992; 25:3170.
Jérôme R, Fayt R, Teyssié Ph. In: Legge NR, Holden G, Schroeder HE, editors. Thermoplastic elastomers, vol. 2. Munich: Hanser, 1996 (p. 521).
Venkateshwaran LN, York GA, Deporter CD, McGrath JE, Wilkes GL. Polymers 1992; 33:2277.
Ihara E, Morimoto M, Yasuda H. Macromolecules 1995; 28:7886.
Tong JD, Moineau G, Leclère Ph, Brédas JL, Lazzeromi R, Jérôme R. Macromolecules 2000;33:470.
Soltani R, Laupretre F, Monnerie L, Teyssié Ph. Polymer 1998;39:3297.
Tong JD, Jérôme R. Polymer 2000; 41:2499.
Gallot BRM. Adv Polym Sci 1978; 29:85.
Hashimoto T, Nagatoshi K, Todo A, Hasegawa H, Kawai H. Macromolecules 1974;7:364.
Hashimoto T, Todo A, Itoi H, Kawai H. Macromolecules 1977; 10:377.
Todo A, Kiuno H, Miyoshi K, Hashimoto T, Kawai H. Polym Engng Sci 1977;17:587.
Hashimoto T, Shibayama M, Kawai H. Macromolecules 1980; 13:1237.
Hashimoto T, Fujimura M, Kawai H. Macromolecules 1980;13: 1660.
Thomas EL, Anderson DM, Henkee CS, Hoffman D. Nature 1988;334:598.
Rasmont A, Leclère Ph, Doneux C, Lambin G, Tong JD, Jérôme R, Brédas JL, Lazzaroni R. Colloids Surf B: Biointerfaces 2001; 13:381.
Leclère Ph, Moineau G, Minet M, Dubois Ph, Jérôme R, Brédas JL, Lazzaroni R. Langmuir 1999;15:3915.
Leclère Ph, Lazzaroni R, Brédas JL, Yu JM, Dubois Ph, Jérôme R. Langmuir 1996; 12:4317.
Brandsch R, Bar G, Whangbo MH. Langmuir 1997; 13:6349.
Bar G, Brandsch R, Whangbo MH. Langmuir 1997; 14:7343.
Cleveland JP, Anczykowski B, Schmidt AE, Elings VB. Appl Phys Lett 1998; 72:2613.
Magonov SN, Elings V, Whangbo WH. Surf Sci Lett 1997; 375: L385.
Bates FS, Fredrickson GH. Annu Rev Phys Chem 1990; 41:525.
Hashimoto T, Tsukahara Y, Tachi K, Kawai H. Macromolecules 1983; 16:648.
Kraus G, Rollmann KW. J Polym Sci, Polym Phys Ed 1976; 14: 1133.
Berglund CA, Mckay KW. Polym Enngg Sci 1993; 33:1195.
Holden G, Legge NR. In: Holden G, Legge NR, Quirk R, Schroeder HE, editors. Thermoplastic elastomers, vol. 2. Munich: Hanser, 1996 (p. 47).
Quirk PR, Morton M. In: Holden G, Legge NR, Quirk R, Schroeder HE, editors. Thermoplastic elastomers, vol. 2. Munich: Hanser, 1996 (P-71).
Gumbrell SM, Mullins L, Rivlin RS. Trans Faraday Soc 1953;49:1495.
Guth E. J Appl Phys 1945; 16:20.
Graessley WW. Adv Polym Sci 1974; 16:58.
Xu Z, Hadjichristidis N, Fetters LJ, Mays JW. Adv Polym Sci 1995; 120:1.
Onogi S, Masuda T, Kitagawa K. Macromolecules 1970; 3:109.
Han CD, Baek DM, Kim JK, Chu SG. Polymer 1992;33:294.
Helfand E, Wasserman ZR. Macromolecules 1976; 9:879.
Leibler L. Macromolecules 1980; 13:1062.
Bates FS, Fredrickson GH. In: Holden G, Legge NR, Quirk R, Schroeder HE, editors. Thermoplastic elastomers, vol. 2. Munich: Hanser, 1996 (p. 335).
Hashimoto T. In: Holden G, Legge NR, Quirk R, Schroeder HE, editors. Thermoplastic elastomers, vol. 2. Munich: Hanser, 1996 (P- 429).
Han CD, Baek DM, Kim JK, Ogawa T, Sakamoto N, Hashimoto T. Macromolecules 1995;28:5043.
Rosesale JH, Bates FS. Macromolecules 1990; 23:2329.
Han CD, Kim J. J Polym Sci, Part B 1987; 25:1741.

Sorted by citations

Block Copolymers: Synthesis, Self-Assembly, and Applications
Feng, H., Lu, X., Wang, W., Kang, N.-G., & Mays, J. (2017) · Polymers · doi:10.3390/polym9100494 · Cited by 467 · see citing works
“These TPEs exhibited superior stress-strain behavior compared to that of conventional all acrylic-based TPEs consisting of PMMA and PBA made by controlled radical processes [94], while the tensile strength was lower compared to that of similar products prepared via living anionic polymerization [95].”
Background
Polystyrene-block-poly(n-butyl acrylate)-block-polystyrene Triblock Copolymer Thermoplastic Elastomer Synthesized via RAFT Emulsion Polymerization
Luo, Y., Wang, X., Zhu, Y., Li, B.-G., & Zhu, S. (2010) · Macromolecules · doi:10.1021/ma101348k · Cited by 138 · see citing works
Physical Properties of PBMA‐b‐PBA‐b‐PBMA Triblock Copolymers Synthesized by Atom Transfer Radical Polymerization
Martín‐Gomis, L., Fernández‐García, M., de la Fuente, J. L., Madruga, E. L., & Cerrada, M. L. (2003) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200300001 · Cited by 12 · see citing works

Compression after Impact and Charpy Impact Characterizations of Glass Fiber/Epoxy/MWCNT Composites
Demircan, Ö., Kadıoğlu, K., Çolak, P., et al. (2020) · Fibers and Polymers · doi:10.1007/s12221-020-9921-9 · Cited by 19 · see citing works
Structure and properties of HNBR composites reinforced by silicate nano-short fiber and short aramid fiber
Ming, T. (2010) · China Rubber Industry · Cited by 1 · see citing works
Cryogenic Compression Properties and Failure Mechanism of Lightweight 3D MWK Carbon Fabric Reinforced Epoxy Composites
Li, D., Duan, H.-W., & Jiang, L. (2019) · Fibers and Polymers · doi:10.1007/s12221-019-8639-z · Cited by 10 · see citing works
Graphite fiber composites interlayered with single-walled carbon nanotubes
Kim, H., & Hahn, H. T. (2011) · Journal of Composite Materials · doi:10.1177/0021998311402726 · Cited by 60 · see citing works
Effect on Compression Molding Parameters in Mechanical Properties of MWCNT/Glass Fiber/Epoxy Composites
Venugopal, J., Dhanasakkaravarthi, B., Surakasi, R., et al. (2022) · Advances in Polymer Technology · doi:10.1155/2022/9295407 · Cited by 34 · see citing works

Authors: Tong, J. D., Leclère, P., Doneux, C., Brédas, J. L., Lazzaroni, R., & Jérôme, R.
Affiliations: University of Liège (BE)
University of Mons (BE)
ORCID: Brédas, J.L
Lazzaroni, R
Venue: Polymer
Publisher: Elsevier BV
Published: 2001-04
Volume: 42
Issue: 8
Pages: 3503-3514
ISSN: 0032-3861 (ISSN-L)
DOI: 10.1016/s0032-3861(00)00759-x
OpenAlex: W2038080437
Cited by: 49
References: 44
Citations by year: 2026: 2 · 2024: 1 · 2022: 1 · 2021: 1 · 2020: 1 · 2019: 4 · 2018: 2 · 2017: 4 · 2016: 3 · 2015: 4 · 2013: 3 · 2012: 3
FWCI: 1.08
Type: journal article
Language: en
Open access: green
orbi.uliege.be
Licence: other-oa
www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Polymer (publishedVersion)
Open Repository and Bibliography (University of Liège) (submittedVersion, other-oa)
ORBi UMONS (submittedVersion)
Funders: Fonds De La Recherche Scientifique - FNRS
Topics: Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords: poly(methyl methacrylate), poly(alkyl acrylates), block copolymers, triblock copolymers, morphology (materials science), mechanical properties, polymer blends

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Morphology and mechanical properties of poly (methylmethacrylate)-b-poly (alkylacrylate)-b-poly (methylmethacrylate)

Integrity signals

Claims the paper makes

Claims other papers make about this one

Self-check

Cites

Cited by

Related

Record

About these checks