Synthesis and crystallization behavior of poly( l -lactide)- block -poly(ϵ-caprolactone) copolymer

Block Copolymer Thermodynamics: Theory And Experiment

Bates, F. S., & Fredrickson, G. H. (1990) · Annual Review of Physical Chemistry · doi:10.1146/annurev.pc.41.100190.002521 · Cited by 3,994

Investigation of the structure of solution grown crystals of lactide copolymers by means of chemical reactions

Fischer, E. W., Sterzel, H. J., & Wegner, G. (1973) · Kolloid-Zeitschrift und Zeitschrift für Polymere · doi:10.1007/bf01498927 · Cited by 1,704

Polymer Data Handbook

Mark, J. E. (2009) · Cited by 1,654

The physics of block copolymers

(1999) · Choice Reviews Online · doi:10.5860/choice.37-1566 · Cited by 1,548

Thermodynamics of fusion of poly-β-propiolactone and poly-ϵ-caprolactone. comparative analysis of the melting of aliphatic polylactone and polyester chains

Crescenzi, V., Manzini, G., Calzolari, G., & Borri, C. (1972) · European Polymer Journal · doi:10.1016/0014-3057(72)90109-7 · Cited by 751

Structural and optical properties of poly lactic acids

Kobayashi, J., Asahi, T., Ichiki, M., Oikawa, A., Suzuki, H., Watanabe, T., Fukada, E., & Shikinami, Y. (1995) · Journal of Applied Physics · doi:10.1063/1.358712 · Cited by 317

Surgical applications of biodegradable polymers in human tissues

Vainionpää, S., Rokkanen, P., & Törmälä, P. (1989) · Progress in Polymer Science · doi:10.1016/0079-6700(89)90013-0 · Cited by 289

Determination of the order-disorder transition temperature of block copolymers

Han, C. D., Kim, J., & Kim, J. K. (1989) · Macromolecules · doi:10.1021/ma00191a071 · Cited by 276

Crystallization of block copolymers. 1. Small-angle x-ray scattering study of a .epsilon.-caprolactone-butadiene diblock copolymer

Nojima, S., Kato, K., Yamamoto, S., & Ashida, T. (1992) · Macromolecules · doi:10.1021/ma00034a027 · Cited by 248

Structure Development in Semicrystalline Diblock Copolymers Crystallizing from the Ordered Melt

Ryan, A. J., Hamley, I. W., Bras, W., & Bates, F. S. (1995) · Macromolecules · doi:10.1021/ma00115a016 · Cited by 233

A comparative study of poly( l ‐lactide)‐ block ‐poly( ϵ ‐caprolactone) six‐armed star diblock copolymers and polylactide/poly( ϵ ‐caprolactone) blends

Konwar, D. B., Jacob, J., & Satapathy, B. K. (2016) · Polymer International · doi:10.1002/pi.5168 · Cited by 17

Constitution and in vivo test of micro-porous tubular scaffold for esophageal tissue engineering

Hou, L., Jin, J., Lv, J., Ling, C., Zhu, Y., & Liu, X. (2015) · Journal of Biomaterials Applications · doi:10.1177/0885328215596285 · Cited by 16

Fully bio‐based poly(ɛ‐capolactone)/poly(lactide) alternating multiblock supramolecular polymers: Synthesis, crystallization behavior, and properties

Shi, X., Jing, Z., Zhang, G., Xu, Y., & Yao, Y. (2017) · Journal of Applied Polymer Science · doi:10.1002/app.45575 · Cited by 16

The effect of PCL/PEG ABA block lengths on the crystallization of homo/block- based polyurethane/CNW nanocomposites

Nourany, M., Ghelichkhani, S., Sarkhosh, H., Zakizadeh, M., & Behrouz, T. (2021) · Journal of Polymer Research · doi:10.1007/s10965-020-02376-y · Cited by 16

Shape memory property of poly(l-lactide-co-ɛ-caprolactone) copolymers

Lu, X., Cai, W., Gao, Z., & Zhao, L. (2006) · Materials Science and Engineering A · doi:10.1016/j.msea.2006.04.120 · Cited by 16

Morphology and Biodegradability of Poly(ε-caprolactone)/Poly(vinyl alcohol) Block Copolymers

Zhou, J. H., Nishimura, Y., Takasu, A., Inai, Y., & Hirabayashi, T. (2004) · Polymer Journal · doi:10.1295/polymj.36.695 · Cited by 15

P(CL-b-LLA) diblock copolymers grafting onto cellulosic nanocrystals

Mano, V., Chimenti, S., Ruggeri, G., Pereira, F. V., & de Paula, E. L. (2017) · Polymer Bulletin · doi:10.1007/s00289-017-1919-0 · Cited by 13

Polarized optical microscopy study on the superstructures of oxyethylene/oxybutylene block copolymers

Xu, J., Liang, G., & Fan, Z. (2004) · Polymer · doi:10.1016/j.polymer.2004.07.071 · Cited by 13

High-performance poly(lactide) composites by construction of network-like shish-kebab crystals

Shen, T., Xu, Y., Ma, P., Wang, L., Dong, W., & Chen, M. (2016) · RSC Advances · doi:10.1039/c6ra11815a · Cited by 13

Crystallization and Morphology of Triple Crystalline Polyethylene-b-poly(ethylene oxide)-b-poly(ε-caprolactone) PE-b-PEO-b-PCL Triblock Terpolymers

Matxinandiarena, E., Múgica, A., Zubitur, M., Ladelta, V., Zapsas, G., Cavallo, D., Hadjichristidis, N., & Müller, A. J. (2021) · Polymers · doi:10.3390/polym13183133 · Cited by 12

Effect of block asymmetry on the crystallization of double crystalline diblock copolymers

Kundu, C., & Dasmahapatra, A. K. (2014) · The Journal of Chemical Physics · doi:10.1063/1.4889997 · Cited by 12

Crystallization of poly(hexamethylene carbonate)-co-poly(hexamethylene urethane) segmental block copolymers: From single to double crystalline phases

Zhang, C., Pérez‐Camargo, R. A., Zheng, L., Zhao, Y., Liu, G., Wang, L., & Wang, D. (2021) · Polymer · doi:10.1016/j.polymer.2021.123675 · Cited by 12

The influences of polyethylene glycol molecular weight on thermal stability, nonisothermal crystallization behavior, and morphology of poly(trimethylene terephthalate)/poly(ethylene oxide terephthalate) copolymers

Chen, Z.-M., Liu, Y., Yao, C.-G., & Yang, G. (2012) · Polymer Testing · doi:10.1016/j.polymertesting.2012.03.008 · Cited by 9

Modification of PLA

Ren, J. (2010) · Springer eBooks · doi:10.1007/978-3-642-17596-1_4 · Cited by 11

Conetworks composed of 4-armed star-shaped l-lactide oligomer and 4-armed star-shaped ɛ-caprolactone oligomer

Shibita, A., Shimasaki, T., Teramoto, N., & Shibata, M. (2015) · Polymer · doi:10.1016/j.polymer.2015.07.052 · Cited by 11

The Effect of d,l ‐Lactidyl/ϵ‐Caproyl Weight Ratio and Chemical Microstructure on Surface Properties of Biodegradable Poly ( d,l ‐Lactide)‐co‐Poly (ϵ‐Caprolactone) Random Copolymers

Hao, J., Keller, T. F., Cai, K., Klemm, E., Bossert, J., & Jandt, K. D. (2008) · Advanced Engineering Materials · doi:10.1002/adem.200800112 · Cited by 11

Microstructure, thermal and rheological properties of poly(L‐lactide‐co‐ε‐caprolactone) tapered block copolymer for potential use in biomedical applications

Saeheng, C., Fuongfuchat, A., Sriyai, M., Daranarong, D., Namhongsa, M., Molloy, R., Meepowpan, P., & Punyodom, W. (2022) · Journal of Applied Polymer Science · doi:10.1002/app.53091 · Cited by 10

A novel paclitaxel eluting bioresorbable vascular stent with a super flexible stent structure and round cross section struts fabricated using 3D printing technology with a rotating platform

Liu, W., Li, Q., Song, G., Lin, Z., Gong, X., Feng, H., Zhao, H. Q., Zhou, Y., Wang, Y., Fan, Z., et al. (2025) · Regenerative Biomaterials · doi:10.1093/rb/rbaf073 · Cited by 9

A dual role of D-Sorbitol in crystallizing and processing poly (lactic acid)

Liu, H., Hu, J. S., Zhang, Y., Zhao, J. Q., Wang, X., & Song, J. (2023) · Journal of Polymer Research · doi:10.1007/s10965-023-03480-5 · Cited by 9

Copolyesters of ε-caprolactone and l -lactide catalyzed by a tetrabutylammonium phthalimide- N -oxyl organocatalyst

Feng, Z., Wu, L., Dong, H., Liu, B., & Cheng, R. (2021) · RSC Advances · doi:10.1039/d1ra02417e · Cited by 9

Synthesis of mid-chain functional macrophotoinitiators of poly(D,L-lactide) homopolymer and tetrablock poly(D,L-lactide)-poly(ε-caprolactone) copolymer by ring-opening polymerization

Değirmenci, M., Urun, T., Durgun, M., & Barım, E. (2015) · Designed Monomers & Polymers · doi:10.1080/15685551.2015.1070499 · Cited by 9

Crystallization behavior and morphology of double crystalline poly(trimethylene terephthalate)/poly(ethylene oxide terephthalate) copolymers

Chen, Z., Liu, Y., Yao, C., & Yang, G. (2012) · Polymer International · doi:10.1002/pi.4284 · Cited by 8

Photo-Cross-Linked Poly(trimethylene carbonate)/Poly(ε-caprolactone) Triblock Copolymers with Controlled Architectures: From Phase-Separated Structures to Shape-Memory Materials

Toshikj, N., Robin, J., Ramonda, M., Catrouillet, S., & Blanquer, S. (2021) · ACS Applied Polymer Materials · doi:10.1021/acsapm.1c00721 · Cited by 8

Disclosing the crystallization behavior and morphology of poly(ϵ‐caprolactone) within poly(ϵ‐caprolactone)/poly( l ‐lactide) blends

Han, W., Liao, X., He, B., Yang, Q. Y., & Li, G. (2018) · Polymer International · doi:10.1002/pi.5548 · Cited by 8

Crystallization assisted microphase separation in all-conjugated phenylene-thiophene diblock copolymers

Yang, H., Zhang, R., Wang, L., Zhang, J., Yu, X., Geng, Y., & Han, Y. (2016) · Polymer · doi:10.1016/j.polymer.2016.05.037 · Cited by 7

Synthesis of ε-caprolactone-b-l-lactide block copolymers by mean sequential polymerization, using diphenylzinc as initiator

Contreras, J., Pestana, J., López‐Carrasquero, F., & Torres, C. F. (2014) · Polymer Bulletin · doi:10.1007/s00289-014-1147-9 · Cited by 7

Synthesis and properties of poly(L-lactide)-polyether-poly(L-lactide) triblock copolymers

Kim, H. Y., & Kim, S. C. (2011) · Macromolecular Research · doi:10.1007/s13233-011-0514-8 · Cited by 6

Confined crystallization morphology of poly(ϵ‐caprolactone) block within poly(ϵ‐caprolactone)–poly( l ‐lactide) copolymers

Han, W., Li, S., Liao, X., He, B., Yang, Q. Y., & Li, G. (2019) · Polymer International · doi:10.1002/pi.5911 · Cited by 6

A versatile strategy for the synthesis and mechanical property manipulation of networked biodegradable polymeric materials composed of well-defined alternating hard and soft domains

Tsuji, H., Tamura, K.-I., & Arakawa, Y. (2019) · RSC Advances · doi:10.1039/c9ra00255c · Cited by 5

Effect of halloysite nanotube loading on structure, mechanical and thermal properties of poly (l-lactic acid) / poly-(butylene succinate) blend

Liu, H. Y., Chen, L., Li, W., & Wang, K.-L. (2019) · IOP Conference Series Materials Science and Engineering · doi:10.1088/1757-899x/634/1/012012 · Cited by 5

Morphology and nonisothermal crystallization of a polyacetal/poly(ε‐caprolactone) reactive blend prepared via a chain‐transfer reaction

Kawaguchi, K., Nakao, H., Masuda, E., & Tajima, Y. (2007) · Journal of Applied Polymer Science · doi:10.1002/app.27144 · Cited by 5

Synthesis and characterization of poly( L ‐lactide‐co‐ϵ‐caprolactone)‐b‐poly( L ‐lactide) biodegradable diblock copolyesters: Effect of the block lengths on their thermal properties

Niamsa, N., & Baimark, Y. (2007) · Journal of Applied Polymer Science · doi:10.1002/app.26993 · Cited by 5

Multifilament yarns of polyoxymethylene/poly(lactic acid) blends produced by a melt-spinning method

Pivsa‐Art, W., & Pivsa‐Art, S. (2019) · Textile Research Journal · doi:10.1177/0040517519865043 · Cited by 5

Investigations on Preparation and Characterization of Certain Copolyesters

Jayachandran, K., Cingaram, R., Jaisankar, V., Sagadevan, S., & Jayaraman, V. (2016) · Materials Research · doi:10.1590/1980-5373-mr-2015-0573 · Cited by 4

Crystallization behavior, rheology, mechanical properties, and enzymatic degradation of poly(L-lactide)/poly(D-lactide)/glycidyl methacrylate grafted poly(ethylene octane) blends

Yan, X., Zhao, Y., Hao, Y., Pan, H., Zhang, H., Wang, Z., & Dong, L. (2017) · Fibers and Polymers · doi:10.1007/s12221-017-1175-9 · Cited by 4

Synthesis and Properties of Biodegradable Copolyester with Phenyl Side Groups

Ge, T., Zhao, D.-L., Liu, X., Yu, Y., He, X., Qi, Y., Liu, W., & Sun, Q. (2025) · Macromolecular Chemistry and Physics · doi:10.1002/macp.202400442 · Cited by 3

Tetracrystalline Tetrablock Quarterpolymers: Four Different Crystallites under the Same Roof

Ladelta, V., Zapsas, G., Abou‐Hamad, E., Gnanou, Y., & Hadjichristidis, N. (2019) · Angewandte Chemie · doi:10.1002/ange.201908688 · Cited by 3

Direct melting polycondensation and characterization of poly(ɛ-caprolactone-co-lactic acid)

Zhao, Y., Zhou, L., & Wang, Z. (2007) · Frontiers of Chemistry in China · doi:10.1007/s11458-007-0036-2 · Cited by 3

Crystallization of double crystalline diblock copolymer from microphase separated melt

Kundu, C., Joshi, N. S., & Dasmahapatra, A. K. (2019) · Polymer Crystallization · doi:10.1002/pcr2.10089 · Cited by 3

Synthesis and characterization of poly(L‐lactide)‐block‐poly(ε‐caprolactone)‐grafted titanium dioxide nanoparticles via ring‐opening in situ grafting polymerization

Ebrahimi, H. P., Sharif, F., & A., A. R. S. (2021) · Polymer Composites · doi:10.1002/pc.26087 · Cited by 2

Copolymerization of L-lactide and ε-caprolactone in supercritical fluid

Prabowo, B., Choi, D. H., & Kim, S. H. (2009) · Macromolecular Research · doi:10.1007/bf03218911 · Cited by 2

Mechanical Properties and In Vitro Degradation Study of Modified‐Polylactic Acid Block Copolymers/Polyetheretherketone Biocomposites

Shi, M., Zhu, G., Lin, N., & Ma, J. (2024) · Journal of Applied Polymer Science · doi:10.1002/app.56523 · Cited by 1

Synthesis and characterization of poly (butylene adipate-co-phenylsuccinate-co-terephthalate) (PBAPT) with good mechanical properties and excellent water vapor barrier

He, X., Sun, Q., Yue, Q., Liu, X., Yu, Y., Hao, T., & Ge, T. (2026) · Journal of Polymer Research · doi:10.1007/s10965-026-04759-z · Cited by 1

Crystallization Behaviors and Regime Kinetics Analysis of Poly(L-lactide)-poly(butylene adipate)-poly(L-lactide) Based Multiblock Thermoplastic Polyurethanes

Zhong, Q. (2018) · Polymer Science Series A · doi:10.1134/s0965545x18030197 · Cited by 1

Random Copolymerization of ε-Caprolactone and L-Lactide by Ring Opening Polymerization Using a Co/N-Doped Carbon Framework as Catalyst

Naz, F., Ciprian, M., Luo, Z., Yan, S., Iqbal, S. Z., Zhu, M., Chaemchuen, S., & Verpoort, F. (2021) · Chemistry Africa · doi:10.1007/s42250-021-00288-y · Cited by 1

Aliphatic polyesters with novel molecular architectures via ring-opening polymerization: synthesis, properties, and applications

Deokar, M. D., Kulkarni, A., Garnaik, B., Lele, A. K., & Sivaram, S. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-821998-0.00010-7

Fabrication of biodegradable composite – an implication of plasticizer

Kaiser, M. R., Anuar, H., & Maleque, M. A. (2010)

Melt Structure and its Transformation by Sequential Crystallization of the Two Blocks within Poly( L ‐lactide)‐ block ‐Poly( ε ‐caprolactone) Double Crystalline Diblock Copolymers

Hamley, I. W., Parras, P., Castelletto, V., Castillo, R. V., Müller, A. J., Pollet, E., Dubois, P., & Martin, C. M. (2006) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200600085 · Cited by 108

Crystallization in Poly(l-lactide)-b-poly(ε-caprolactone) Double Crystalline Diblock Copolymers: A Study Using X-ray Scattering, Differential Scanning Calorimetry, and Polarized Optical Microscopy

Hamley, I. W., Castelletto, V., Castillo, R. V., Müller, A. J., Martin, C. M., Pollet, E., & Dubois, P. (2005) · Macromolecules · doi:10.1021/ma0481499 · Cited by 160

Crystallization of double crystalline block copolymer/crystalline homopolymer blends: 2. crystallization behavior

Gondo, S., Osawa, S., Marubayashi, H., & Nojima, S. (2015) · Polymer Journal · doi:10.1038/pj.2015.33 · Cited by 11

Crystallization behavior of diblock copolymers based on PCL and PLLA biopolymers

Navarro-Baena, I., Marcos-Fernández, Á. A., Kenny, J. M., & Peponi, L. (2014) · Journal of Applied Crystallography · doi:10.1107/s1600576714022468 · Cited by 20

Confined Crystallization and Morphology of Melt Segregated PLLA- b -PE and PLDA- b -PE Diblock Copolymers

Castillo, R. V., Müller, A. J., Lin, M.-C., Chen, H., Jeng, U., & Hillmyer, M. A. (2008) · Macromolecules · doi:10.1021/ma800859y · Cited by 111