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Studies on syntheses and physical characterization of biodegradable aliphatic poly(butylene succinate-co-ɛ-caprolactone)s
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“Metal salts such as titanium alkoxides, tin alkoxides, zinc or magnesium carboxylates are commonly used catalysts for the step-growth synthesis of polyesters and polycarbonates.[224][225][226][227]228,229”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [224]
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Catalysis as an Enabling Science for Sustainable Polymers
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“Thus, the objectives of this study were to (1) produce biodegradable antimicrobial PCL-based film incorporated with GSE using a twin-screw extruder; (2) determine structural, colorimetric, thermal, and mechanical properties of the films; (3) investigate in vitro and in vivo (real food system, cheddar cheese packaging)…”
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“Some particular features of PCL include flexibility, low Tg (−61 °C), and low melting point (65 °C), comparatively high price, and a fairly long biodegradability cycle [14,15].”
BackgroundWu, D., Yuan, L., Laredo, E., Zhang, M., & Zhou, W. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie2022288 · Cited by 159
Soil burial and enzymatic degradation in solution of aliphatic co-polyesters
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Biodegradable polyester-polybutylene succinate (PBS): a review
Rajgond, V., Mohite, A. S., More, N., & More, A. P. (2023) · Polymer Bulletin · doi:10.1007/s00289-023-04998-w · Cited by 127
“The fracture strains of the copolyesters were in the range of 817%–1173% [42].”
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“Other works opted for chitin to create new materials with the desired properties (Orhan and Buyukgungor 2000; Degli-Innocenti et al. 2001; Abou-Zeid et al. 2001; Cao et al. 2002; Ishiaku et al. 2002) and to reduce environmental pollution (El Hadji 2008).”
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The synthesis of copolymers, blends and composites based on poly(butylene succinate)
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“This limitation may be overcome by blending of PCL with costeffective biodegradable natural biopolymers, such as starch, cellulose, and chitin, to create new materials with desired properties [4–15].”
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“In a previous study about thermal properties of coP(BSxCLy), Tm and Tc of the copolyesters shifted toward a lower temperature with an increase in the CL/BS molar ratio, however, no double crystallization or melting peaks where reported, as the composition range explored was limited [5].”
InfluentialSafari, M., de Ilarduya, A. M., Múgica, A., Zubitur, M., Muñoz‐Guerra, S., & Müller, A. J. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b01742 · Cited by 50
PBS Makes its Entrance into the Family of Biobased Plastics
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“All in all, PBFCL demonstrates excellent thermal stability, which is comparable or even better than those of aliphatic polyesters [26, 27].”
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Synthesis, Characterization and Biodegradation Study of Low Molecular Weight Polyesters
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“Cao et al. [39] studied the tensile behavior of PBS-ran -PCL copolymers with average M n around 55,000 g/mol and found that the maximum elongation at break occurred for the 18% PBS composition, which is fairly close to the results obtained in this work.”
ResultSynthesis of Poly(butylene succinate) and Poly(ethylene succinate) Including Diglycollate Moiety
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Enzymatic Synthesis and Chemical Recycling of Novel Polyester-Type Thermoplastic Elastomers
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“One effective way to resolve this problem is to form PBS-based thermoplastic elastomers by the introduction of soft segments into the polymer chain [15–18].”
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Abdolmohammadi, S., Yunus, W. M. Z. W., Rahman, M. Z. A., & Ibrahim, N. A. (2011) · Journal of Reinforced Plastics and Composites · doi:10.1177/0731684411410338 · Cited by 28
“Flexibility, low Tg ( 61 C), melting point of the (65 C), comparatively high price, and fairly long biodegradability cycle are noted as particular features of PCL.(8,9) Based on its biodegradable characters, PCL is broadly applied in environmental (e.”
BackgroundSahoo, P. K., & Rana, P. K. (2006) · Journal of Materials Science · doi:10.1007/s10853-006-0504-y · Cited by 26
A New Synthesis of Nickel 12-Hydroxy Oleate Formulation to Improve Polyolefins Degradation
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“, oligomers, dimers, and monomers, that are smaller enough to pass the semi-permeable outer bacterial membranes, [13] and then to be utilized as carbon and energy sources.”
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A new arylesterase from Pseudomonas pseudoalcaligenes can hydrolyze ionic phthalic polyesters
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Microstructure Analysis and Model Discrimination of Enzyme-Catalyzed Copolyesters
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Makgwane, P. R., Muniyasamy, S., Hlekelele, L., Swanepoel, A., Sypu, V. S., Mdlalose, L., Naidoo, S., Cele, Z. E. D., Maity, A., Balogun, M. O., et al. (2025) · JOURNAL OF RENEWABLE MATERIALS · doi:10.32604/jrm.2025.027523 · Cited by 21
“In the other study, the biodegradable aliphatic poly(butylene succinate-co - ε -carprolactone) (PBSCs) copolymers were synthesized via polycondensation using TTP catalyst, diphenylphosphinic acid (DPPA) and stannous octoate (Sn(Oct) 2 ) as effective co-catalysts [113].”
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Effects of molecular architecture on the rheological and physical properties of polycaprolactone
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“…to gain sufficient control over the degradation rate: such measures have included blending PCL with polystyrene and polylactic acid, copolymerization, and grafting with butylene succinate and polypyrrole (Biresaw and Carriere, 2002; Cao et al., 2002; Chen et al., 2003; Mecerreyes et al., 2002).”
MethodBiodegradable Polymers and their Applications: A Review
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Degradation performances of CL-modified PBSCL copolyesters in different environments
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Copolymerization of Poly(butylene succinate) with 3-Alkoxy-1,2-propanediols
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Synthesis and biodegradation studies of 1,3-propanediol based aliphatic poly(ester carbonate)s
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Metadata
- Authors
- Cao, A.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2002-02
- Volume
- 43
- Issue
- 3
- Pages
- 671-679
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2021643094
- Cited by
- 108
- References
- 24
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 1 · 2023: 5 · 2022: 5 · 2021: 4 · 2020: 1 · 2019: 3 · 2018: 3 · 2017: 13 · 2016: 3 · 2015: 1 · 2014: 4 · 2013: 6 · 2012: 15
- FWCI
- 2.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- biodegradable copolyesters, aliphatic polyesters, polycondensation, diphenylphosphinic acid, stannous octoate, random copolymerization, thermal properties, crystal structure, mechanical properties, fracture elongation, biodegradation, compost soil, chain flexibility
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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