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Studies on syntheses and physical properties of biodegradable aliphatic poly(butylene succinate-co-ethylene succinate)s and poly(butylene succinate-co-diethylene glycol succinate)s
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“For example, Ti(O i Pr)4 can mediate the polycondensation of several bio-derived diesters (succinate, adipate, sebacate) with 1,4-butanediol under high temperature (up to 240 °C) and in vacuo to generate aliphatic polyesters with Mn > 20 kDa.225,230,231”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [231]
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“To tailor design the physical properties of PBS, random copolymerization with different types of comonomer units has been examined, including adipic acid [44, 47, 57], terephthalic acid [66–70], methyl succinic acid [41, 71–73], 2,2-dimetyl succinic acid [74], benzyl succinic acid [75], ethylene glycol [43, 75–77] and…”
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“This result indicates that the degradation of RHF is faster than that of PBS matrix polymer because the cellulosic materials are easily attacked by microorganisms [18].”
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“In order to decrease the toxicity, we used a lower toxicity of titanium tetraisopropoxide.(23) The chemical structure was confirmed by (1)H-nuclear magnetic resonance (NMR) and Fourier transform infrared (FT-IR) spectroscopy, and the physical properties were determined by gel permeation chromatography (GPC) and differ…”
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“PBS의 용융점에 대해서는 Jin et al.(2000) 115.9℃ , Kim et al.(2001) 115.8℃ , Cao et al.(2002) 114.4℃, Qiu et al.(2003) 118℃, Nikolic et al.(2003) 115℃, Lim et al.(2005) 120℃, Chrissafis et al.(2005) 112.”
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“Similar results have been reported for the other series of aliphatic copolyesters [23, 34, 45, 49].”
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“biodegradability cycle are known as particular characteristics of PCL [5].”
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“Table 1 Synthetic conditionsa and chain structure parameters of the flexible copolyesters Run Copolyester Feed ratio Copolyester composition Rf Mn*10 -3 g Mw*10 -3 g Ðh 1 PBSeAS334 0.3:0.3:0.4b 0.311:0.291:0.398d 0.98 39.4 74.6 1.89 2 PBAzAS334 0.3:0.3:0.4b 0.317:0.301:0.382d 1.02 42.1 82.5 1.96 3 PBSeAT334 0.3:0.3:0.…”
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“그리고 열처리 온도가 75。C에서 파단 강 도와 신장률이 70。C보다 큰 폭으로 감소하는 것 은 Jang et al. (2010)이 일정 온도 이상으로 열처 리 하면 강도가 급격히 감소한다고 보고한 결과 와 일치하며, Cao et al. (2002)이 PBS의 연화점이 95。C라고 보고한 것에 근접하고 하고 있기 때문 이라 사료된다.”
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“…to polyethylene and polypropylene, the commercial PBS is usually a copolymer with other diacids, diols or even a copolymer of α , ω -hydroxy acids such as adipic acid, ethylene glycol, and ε -caprolactone (Fujimaki 1998; He et al. 2000; Cao et al. 2002; Oishi et al. 2006; Mazzocchetti et al. 2009).”
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“3 C.(26) And Td of poly (butylene succinate-co-E-caprolactone)s (PBS–PCL) copolymer is reduced by 60.”
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Thermal and thermooxidative degradation
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Synthesis and Characterization of Binders for Propellants
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“그리고 열처리 온도가 75。C에서 파단강도와 신 장률이 온도 70。C 보다 큰 폭으로 감소하는 것은 Jang et al (2010)이 일정 온도 이상으로 열처리 하면 강도가 급 격히 감소한다고 보고한 결과와 일치하며, Cao et al (2002)이 PBS의 연화점이 95。C라고 보고한 온도에 근 접하고 하고 있기 때문이라 사료된다.”
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PROPERTIES OF POLY(p‐DIOXANONE‐URETHANE) COPOLYMERS WITH CONTROLLABLE STRUCTURES
Zhou, Y., Zhang, J., Qiu, Z., Zeng, Q., Chang, J., Yang, K., & Wang, Y. (2009) · Soft Materials · doi:10.1080/15394450903344736 · Cited by 4
Metadata
- Authors
- Cao, A., Okamura, T., Nakayama, K., Inoue, Y., & Masuda, T.
- Affiliations
- Tokyo University of Science (JP)
- National Institute of Advanced Industrial Science and Technology (JP)
- Tokyo Institute of Technology (JP)
- Corresponding author
- Masuda, Takashi
- Venue
- Polymer Degradation and Stability
- Publisher
- Elsevier BV
- Published
- 2002-01
- Volume
- 78
- Issue
- 1
- Pages
- 107-117
- ISSN
- 0141-3910 (ISSN-L)
- OpenAlex
- W1972519202
- Cited by
- 113
- References
- 25
- Citations by year
- 2026: 4 · 2025: 1 · 2024: 4 · 2023: 1 · 2022: 3 · 2021: 3 · 2020: 3 · 2019: 6 · 2018: 2 · 2017: 6 · 2016: 5 · 2015: 9 · 2014: 8 · 2013: 7 · 2012: 9
- FWCI
- 1.29
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer Degradation and Stability (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- biodegradable aliphatic polyesters, copolyesters, direct polycondensation, diphenylphosphinic acid, comonomer composition, sequence distribution, thermal stability, crystallization behavior, mechanical properties, ether groups
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