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Multivariate statistical study of heavy metal enrichment in sediments of the Pearl River Estuary

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Liu, W.X, Li, X.D, Shen, Z.G, Wang, D.C, Wai, O.W.H, Li, Y.S·2003·Environmental Pollution

Abstract

The concentrations and chemical partitioning of heavy metals in the sediment cores of the Pearl River Estuary were studied. Based on Pearson correlation coefficients and principal component analysis results, Al was selected as the concentration normalizer for Pb, while Fe was used as the normalizing element for Co, Cu, Ni and Zn. In each profile, sections with metal concentrations exceeding the upper 95% prediction interval of the linear regression model were regarded as metal enrichment layers. The heavy metal accumulation mainly occurred at sites in the western shallow water areas and east channel, which reflected the hydraulic conditions and influence from riparian anthropogenic activities. Heavy metals in the enrichment sections were evaluated by a sequential extraction method for possible chemical forms in sediments. Since the residual, Fe/Mn oxides and organic/sulfide fractions were dominant geochemical phases in the enriched sections, the bioavailability of heavy metals in sediments was generally low. The 206Pb/207Pb ratios in the metal-enriched sediment sections also revealed the influence of anthropogenic sources. The spatial distribution of cumulative heavy metals in the sediments suggested that the Zn and Cu mainly originated from point sources, while the Pb probably came from non-point sources in the estuary.

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Metadata

Authors
Liu, W. X., Li, X. D., Shen, Z. G., Wang, D. C., Wai, O. W. H., & Li, Y. S.
Venue
Environmental Pollution
Publisher
Elsevier BV
Published
2003-03
Volume
121
Issue
3
Pages
377-388
ISSN
0269-7491 (ISSN-L)
OpenAlex
W2008234654
Cited by
431
References
14
FWCI
7.29
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Multivariate statistical study of heavy metal enrichment in sediments of the Pearl River Estuary. https://app.cochat.ai/papers/10.1016/s0269-7491(02)00234-8
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Liu, W. X., Li, X. D., Shen, Z. G., Wang, D. C., Wai, O. W. H., & Li, Y. S. (2003). Multivariate statistical study of heavy metal enrichment in sediments of the Pearl River Estuary. Environmental Pollution. https://doi.org/10.1016/s0269-7491(02)00234-8

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