The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Mutual effects of cadmium and phosphate on their adsorption and desorption by goethite
Abstract
Adsorption of cadmium (Cd) and phosphate by oxides or soils has been extensively studied, but the adsorption/desorption kinetics and mutual effects of these two species in co-existing systems has received little attention. In this study, a batch equilibration method was used to investigate the effect of phosphate and its application time on Cd adsorption and desorption on goethite. The influence of Cd and its application time on phosphate sorption and desorption kinetics was also determined. For Cd adsorption, phosphate was introduced into the system by two sequences: pre-treating goethite at 40 (degrees)C for 1 week, and applying with Cd simultaneously. Similarly, for phosphate sorption, Cd was applied by pre-treating goethite at 40 (degrees)C for 1 week or simultaneous addition with phosphate. Results demonstrated that phosphate added to goethite enhanced Cd adsorption, and facilitated Cd release as compared to untreated goethite. Cadmium had slightly higher adsorption, but a significantly faster desorption rate from the goethite simultaneously treated with phosphate and Cd, as compared to phosphate-pretreated goethite. Cadmium and its application time had little impact on phosphate sorption by goethite. However, phosphate desorption kinetics was affected by Cd application time. When the sorption time was short (15 min), phosphate desorption was faster from the goethite that was simultaneously treated with phosphate and Cd, as compared to Cd pretreated or untreated goethite. In contrast, a longer sorption time (4 weeks) resulted in a higher desorption rate of phosphate from Cd pretreated goethite than simultaneously phosphate-Cd treated goethite. This study provided useful information on adsorption/desorption kinetics in complicated Cd-phosphate-goethite systems.
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“Of course, the sorption of phosphate and other ligands with a strong affinity for the surfaces of variable charge minerals (e.g., LMMOLs) also increases the surface negative charges and decreases the electrostatic potential near the solid surfaces [42].”
From Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments (2016) · cites this paper as [42]
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Cites
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Residence Time Effects on Arsenate Adsorption/Desorption Mechanisms on Goethite
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Kinetics of Cadmium and Cobalt Desorption from Iron and Manganese Oxides
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Interaction between Calcium and Phosphate Adsorption on Goethite
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Effects of crystallinity of goethite: II. Rates of sorption and desorption of phosphate
STRAUSS, R., Brümmer, G. W., & Barrow, N. J. (1997) · European Journal of Soil Science · doi:10.1111/j.1365-2389.1997.tb00189.x · Cited by 224
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- Kruse, 1988, Automatische apparatur zur volumetrischen gasadsorptionsmessung, GIT Fachzeitschrift fur das labor, 32, 1096
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Trophic state assessment of global inland waters using a MODIS-derived Forel-Ule index
Wang, S., Li, J., Zhang, B., Spyrakos, E., Tyler, A. N., Shen, Q., Zhang, F., Kuster, T., Lehmann, M. K., Wu, Y., et al. (2018) · Remote Sensing of Environment · doi:10.1016/j.rse.2018.08.026 · Cited by 407
Innovative methods in soil phosphorus research: A review
Kruse, J., Abraham, M., Amelung, W., Baum, C., Bol, R., Kühn, O., Lewandowski, H., Niederberger, J., Oelmann, Y., Rüger, C. P., et al. (2015) · Journal of Plant Nutrition and Soil Science · doi:10.1002/jpln.201400327 · Cited by 412
Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments
Caporale, A. G., & Violante, A. (2016) · Current Pollution Reports · doi:10.1007/s40726-015-0024-y · Cited by 369
Mechanisms of competitive adsorption of Pb, Cu, and Cd on peat
Qin, F., Wen, B., Shan, X.-Q., Xie, Y., Liu, T., Zhang, S., & Khan, S. U. (2006) · Environmental Pollution · doi:10.1016/j.envpol.2005.12.036 · Cited by 259
An overview of the role of goethite surfaces in the environment
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Metadata
- Authors
- Wang, K., & Xing, B.
- Affiliations
- University of Massachusetts Amherst (US)
- Corresponding author
- Xing, Baoshan
- Venue
- Environmental Pollution
- Publisher
- Elsevier BV
- Published
- 2004-01
- Volume
- 127
- Issue
- 1
- Pages
- 13-20
- ISSN
- 0269-7491 (ISSN-L)
- OpenAlex
- W2094448107
- Cited by
- 95
- References
- 28
- Citations by year
- 2026: 4 · 2025: 1 · 2024: 8 · 2023: 7 · 2022: 5 · 2021: 1 · 2020: 6 · 2019: 3 · 2018: 4 · 2017: 7 · 2016: 6 · 2015: 3 · 2014: 3 · 2013: 4 · 2012: 2
- FWCI
- 3.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Pollution (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Waste Management and Disposal › Phosphorus and nutrient management
- Keywords
- cadmium, phosphate, goethite, adsorption kinetics, desorption kinetics, metal release, iron oxide minerals, phosphate pretreatment, heavy metal contamination
- MeSH terms
- Adsorption, Cadmium, Minerals, Phosphates, Soil Pollutants, Hazardous Substances, Iron Compounds
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