Effect of temperature on the sorption and desorption of perfluorooctane sulfonate on humic acid
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Sorption and desorption of perfluorooctane sulfonate (PFOS) on humic acid at different temperatures were studied. It was found that the sorption process could be modeled with power kinetic equation very well, suggesting that diffusion predominated the sorption of PFOS on the humic acid. The sorption capacity was doubled when the temperature increased from 5 to 35 degrees C, and thermodynamics parameters deltaG0 was calculated to be -7.11 to -5.04 kJ/mol, AHo was 14.2 kJ/mol, and deltaS0 was 69.5 J/(mol x K), indicating that the sorption was a spontaneous, endothermic, and entropy driven process. Desorption hysteresis occurred at all studied temperatures which suggested that humic acid may be an important sink of PFOS in the environment.
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The higher July φ values may be explained by enhanced adsorption capability due to the higher water temperature in July.
“This difference may be explained by the enhanced adsorption capability due to the higher water temperature in July (Jia et al., 2010).”
From Partitioning behavior of short-chain legacy and novel perfluorinated substances (PFAS) between dissolved and particulate phases in a river-estuary-coast continuum (2025) · cites this paper as Jia et al., 2010
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Conant, R. T., Ryan, M. G., Ågren, G. I., Birge, H. E., Davidson, E. A., Eliasson, P. E., Evans, S. E., Frey, S. D., Giardina, C. P., Hopkins, F. M., et al. (2011) · Global Change Biology · doi:10.1111/j.1365-2486.2011.02496.x · Cited by 1,635 · see citing works
Adsorption behavior and mechanism of perfluorinated compounds on various adsorbents—A review
Du, Z., Deng, S., Bei, Y., Huang, Q., Wang, B., Huang, J., & Yu, G. (2014) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2014.04.038 · Cited by 1,236 · see citing works
Shi, D., Pan, Y., Luo, Y., Dong, F., Zhang, J., Xin, X., Li, Y., Dai, J., & Tang, J. (2025) · Environmental Pollution · doi:10.1016/j.envpol.2025.126133 · Cited by 22 · see citing works
- Authors
- Jia, C., You, C., & Pan, G.
- Affiliations
- Chinese Academy of Sciences (CN)
- Corresponding author
- Pan, Gang
- ORCID
- Pan, Gang
- Venue
- Journal of Environmental Sciences
- Publisher
- Elsevier BV
- Published
- 2010-01
- Volume
- 22
- Issue
- 3
- Pages
- 355-361
- ISSN
- 1001-0742 (ISSN-L)
- OpenAlex
- W1970444648
- Cited by
- 63
- References
- 2
- Citations by year
- 2026: 5 · 2025: 6 · 2024: 6 · 2023: 2 · 2022: 8 · 2021: 6 · 2020: 5 · 2019: 3 · 2018: 6 · 2017: 1 · 2016: 3 · 2015: 2 · 2014: 4 · 2013: 2 · 2012: 1
- FWCI
- 1.62
- Type
- journal article
- Language
- en
- Open access
- green
- ir.rcees.ac.cn
- Licence
- cc-by-nc-nd
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- Locations
- Journal of Environmental Sciences (publishedVersion)
- PubMed (publishedVersion)
- Research Center for Eco-Environmental Sciences OpenIR (Chinese Academy of Sciences) (submittedVersion, cc-by-nc-nd)
- Nottingham Trent University's Institutional Repository (Nottingham Trent Repository) (submittedVersion)
- Funders
- National Natural Science Foundation of China
- Topics
- Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Toxic Organic Pollutants Impact
- Physical Sciences › Environmental Science › Environmental Chemistry › Environmental Chemistry and Analysis
- Keywords
- PFOS, humic acid, sorption, desorption, temperature effects, diffusion-controlled sorption, sorption thermodynamics, endothermic adsorption, desorption hysteresis
- MeSH terms
- Adsorption, Environmental Pollutants, Fluorocarbons, Humic Substances, Temperature, Alkanesulfonic Acids
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