Cited by 63Per- and polyfluoroalkyl substances researchToxic Organic Pollutants ImpactEnvironmental Chemistry and Analysis

Effect of temperature on the sorption and desorption of perfluorooctane sulfonate on humic acid

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Jia, Chengxia, You, Chun, Pan, Gang·2010·Journal of Environmental Sciences

Abstract

Sorption and desorption of perfluorooctane sulfonate (PFOS) on humic acid at different temperatures were studied. It was found that the sorption process could be modeled with power kinetic equation very well, suggesting that diffusion predominated the sorption of PFOS on the humic acid. The sorption capacity was doubled when the temperature increased from 5 to 35 degrees C, and thermodynamics parameters deltaG0 was calculated to be -7.11 to -5.04 kJ/mol, AHo was 14.2 kJ/mol, and deltaS0 was 69.5 J/(mol x K), indicating that the sorption was a spontaneous, endothermic, and entropy driven process. Desorption hysteresis occurred at all studied temperatures which suggested that humic acid may be an important sink of PFOS in the environment.

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Crossref · 10.1016/s1001-0742(09)60115-7

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Authors
Jia, C., You, C., & Pan, G.
Affiliations
Chinese Academy of Sciences (CN)
Corresponding author
Pan, Gang
Venue
Journal of Environmental Sciences
Publisher
Elsevier BV
Published
2010-01
Volume
22
Issue
3
Pages
355-361
ISSN
1001-0742 (ISSN-L)
OpenAlex
W1970444648
Cited by
63
References
2
Citations by year
2026: 5 · 2025: 6 · 2024: 6 · 2023: 2 · 2022: 8 · 2021: 6 · 2020: 5 · 2019: 3 · 2018: 6 · 2017: 1 · 2016: 3 · 2015: 2 · 2014: 4 · 2013: 2 · 2012: 1
FWCI
1.62
Type
journal article
Language
en
Open access
Locations
  • Journal of Environmental Sciences (publishedVersion)
  • PubMed (publishedVersion)
  • Research Center for Eco-Environmental Sciences OpenIR (Chinese Academy of Sciences) (submittedVersion, cc-by-nc-nd)
  • Nottingham Trent University's Institutional Repository (Nottingham Trent Repository) (submittedVersion)
Funders
National Natural Science Foundation of China
Topics
  • Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
  • Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Toxic Organic Pollutants Impact
  • Physical Sciences › Environmental Science › Environmental Chemistry › Environmental Chemistry and Analysis
Keywords
PFOS, humic acid, sorption, desorption, temperature effects, diffusion-controlled sorption, sorption thermodynamics, endothermic adsorption, desorption hysteresis
MeSH terms
Adsorption, Environmental Pollutants, Fluorocarbons, Humic Substances, Temperature, Alkanesulfonic Acids

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