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The Oxygen Evolution Reaction on Passive Oxide Covered Transition Metal Electrodes in Alkaline Solution Part II - Cobalt
Open accessAbstract
Details are outlined of an electrochemical investigation of the oxygen evolution reaction (OER) at passive oxide covered polycrystalline Co electrodes in aqueous alkaline solution. Kinetic studies on electrodes subjected to different pre-treatment routines, yielded different values of the Tafel slope and the reaction order with respect to OH- activity. Only one mechanistic pathway could account for all observed values of these kinetic parameters. This pathway is similar, although not identical, to that proposed, in the first paper of this series, for the reaction at oxide covered Ni anodes. Using cyclic voltammetry it was shown that the mechanism for the initial passivation of Co electrodes varies with OH- concentration. This in turn can have an effect on the experimental value of the OER Tafel slope, a phenomenon which can be rationalized in terms of a dual energy barrier model.
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Cited by
Anantharaj, S., Ede, S. R., Karthick, K., Sam Sankar, S., Sangeetha, K., Karthik, P. E., & Kundu, S. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03457a · Cited by 1,632
Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
Fabbri, E., Habereder, A., Waltar, K., Kötz, R., & Schmidt, T. J. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00669k · Cited by 1,303
Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst
Song, F., & Hu, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5096733 · Cited by 1,163
Electrocatalytic Oxygen Evolution at Surface-Oxidized Multiwall Carbon Nanotubes
Lu, X., Yim, W.-L., Suryanto, B. H. R., & Zhao, C. (2015) · Journal of the American Chemical Society · doi:10.1021/ja509879r · Cited by 594
Doyle, R. L., & Lyons, M. E. G. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.015303jes · Cited by 238
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Metadata
- Authors
- Lyons, M. E. G., & Brandon, M. P.
- Venue
- International Journal of Electrochemical Science
- Publisher
- Elsevier BV
- Published
- 2008-12
- Volume
- 3
- Issue
- 12
- Pages
- 1425-1462
- ISSN
- 1452-3981 (ISSN-L)
- OpenAlex
- W4382021540
- Cited by
- 163
- References
- 0
- FWCI
- 3.21
- Type
- journal article
- Language
- en
- Open access
- gold
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- CoChat. (2026). Citation check: The Oxygen Evolution Reaction on Passive Oxide Covered Transition Metal Electrodes in Alkaline Solution Part II - Cobalt. https://app.cochat.ai/papers/10.1016/s1452-3981(23)15532-5
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- Lyons, M. E. G., & Brandon, M. P. (2008). The Oxygen Evolution Reaction on Passive Oxide Covered Transition Metal Electrodes in Alkaline Solution Part II - Cobalt. International Journal of Electrochemical Science. https://doi.org/10.1016/s1452-3981(23)15532-5
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