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Determination of Size and Concentration of Gold Nanoparticles from Extinction Spectra
Abstract
Extinction spectra of colloidal gold can be used for a simple and fast determination of the size and concentration of nanoparticles. It is generally accepted that experimental correlations of the particle size and concentration with the plasmon resonance properties are in agreement with Mie theory simulations. Here, we discuss this point in the context of a long-term collection of published experimental data and our T-matrix simulations, which account for deviations of the particle size from ideal monodisperse spheres. These deviations result in small but quite evident disagreements between the Mie calculations and the experimental calibration curves "particle size vs resonance wavelength". We present a long-term-averaged analytical particle-size calibration and also discuss the effects of the particle dielectric functions, shape and size polydispersity on simulated correlations between the extinction spectra and the average particle size, and concentration.
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Cites
Optical Constants of the Noble Metals
Johnson, P. B., & Christy, R. W. (1972) · Physical Review B · doi:10.1103/physrevb.6.4370 · Cited by 20,094
Nanostructures in Biodiagnostics
Rosi, N. L., & Mirkin, C. A. (2005) · Chemical Reviews · doi:10.1021/cr030067f · Cited by 4,603
Cited by
Gold Nanoparticles in Chemical and Biological Sensing
Saha, K., Agasti, S. S., Kim, C., Li, X., & Rotello, V. M. (2012) · Chemical Reviews · doi:10.1021/cr2001178 · Cited by 4,620
Enzyme-responsive nanoparticles for drug release and diagnostics
de la Rica, R., Aili, D., & Stevens, M. M. (2012) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2012.01.002 · Cited by 765
Hendel, T., Wuithschick, M., Kettemann, F., Birnbaum, A., Rademann, K., & Polte, J. (2014) · Analytical Chemistry · doi:10.1021/ac502053s · Cited by 235
Saraeva, I. N., Kudryashov, S. I., Rudenko, A. A., Zhilnikova, M. I., Ivanov, D. S., Zayarny, D. A., Simakin, A. V., Ionin, A. A., & Garcia, M. E. (2019) · Applied Surface Science · doi:10.1016/j.apsusc.2018.11.199 · Cited by 51
Surface enhanced deep Raman detection of cancer tumour through 71 mm of heterogeneous tissue
Dey, P., Vaideanu, A., Mosca, S., Salimi, M., Gardner, B., Palombo, F., Uchegbu, I., Baumberg, J., Schatzlein, A., Matousek, P., et al. (2022) · Nanotheranostics · doi:10.7150/ntno.71510 · Cited by 34
Metadata
- Authors
- Khlebtsov, N. G.
- Venue
- Analytical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-07-22
- Volume
- 80
- Issue
- 17
- Pages
- 6620-6625
- ISSN
- 0003-2700 (ISSN-L)
- 1520-6882
- OpenAlex
- W2005546798
- Cited by
- 295
- References
- 2
- FWCI
- 3.80
- Type
- journal article
- Language
- en
- Open access
- closed
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