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Cited by 168

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Preparation of Alkanethiolate-Functionalized Core/Shell Fe3O4@Au Nanoparticles and Its Interaction with Several Typical Target Molecules

Zhao, Xiaoli, Cai, Yaqi, Wang, Thanh, Shi, Yali, Jiang, Guibin·2008·Analytical Chemistry

Abstract

This paper reports the synthesis of alkanethiolate-functionalized core/shell Fe3O4/Au nanoparticles (Fe3O4@Au NPs) that combine the advantages of core/shell magnetic nanoparticles with self-assembled monolayers (SAMs). The alkanethiolates, having carboxylic acid (COOH) and methyl (CH3) terminal groups, can be easily self-assembled on the Fe3O4@Au NPs substrates. The surface composition and structure of 11-mercaptoundecanoic acid (11-MUA) and 1-dodecanethiol (11-DDT) SAMs were characterized in detail using energy-dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). To further study the surface properties of the SAMs, hydrophobic, ionic, and nonionic organic compounds were selected as probe molecules. The results indicated that the hydrophobic interaction caused strong retention of analytes, whereas the repulsive electrostatic interaction between the negatively charged 11-MUA SAMs surface and the negatively charged probe molecule would lead to the decrease of adsorption affinity.

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Metadata

Authors
Zhao, X., Cai, Y., Wang, T., Shi, Y., & Jiang, G.
Venue
Analytical Chemistry
Published
2008-11-01
Volume
80
Issue
23
Pages
9091-9096
ISSN
  • 0003-2700 (ISSN-L)
  • 1520-6882
OpenAlex
W1982826997
Cited by
168
References
1
FWCI
12.90
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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