The DOI matches its Crossref record; 60 of the 60 references it cites were found in a registry or an index.
Interface Stability in Solid-State Batteries
Open accessAbstract
Development of high conductivity solid-state electrolytes for lithium ion batteries has proceeded rapidly in recent years, but incorporating these new materials into high-performing batteries has proven difficult. Interfacial resistance is now the limiting factor in many systems, but the exact mechanisms of this resistance have not been fully explained - in part because experimental evaluation of the interface can be very difficult. In this work, we develop a computational methodology to examine the thermodynamics of formation of resistive interfacial phases. The predicted interfacial phase formation is well correlated with experimental interfacial observations and battery performance. We calculate that thiophosphate electrolytes have especially high reactivity with high voltage cathodes and a narrow electrochemical stability window. We also find that a number of known electrolytes are not inherently stable but react in situ with the electrode to form passivating but ionically conducting barrier layers. As a reference for experimentalists, we tabulate the stability and expected decomposition products for a wide range of electrolyte, coating, and electrode materials including a number of high-performing combinations that have not yet been attempted experimentally.
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“This points to an interesting contraindication in materials design: soft anions such as Te2– and I– readily permit cation transport but do not possess the requisite electrochemical (redox) stability for use as solid electrolytes. Conversely, hard anions such as O2– and F– are redox-stable, but they bind cations strongly, and the resulting materials usually display limited ionic conductivity.”
From Artificial Intelligence Driving Materials Discovery? Perspective on the Article: Scaling Deep Learning for Materials Discovery (2024) · cites this paper as [29]
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Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
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Metadata
- Authors
- Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G.
- Affiliations
- Massachusetts Institute of Technology (US)
- Samsung Advanced Institute of Technology - USA , 255 Main Street, Suite 702 , , ,
- Lawrence Berkeley National Laboratory (US)
- Corresponding author
- Ceder, Gerbrand
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-12-07
- Volume
- 28
- Issue
- 1
- Pages
- 266-273
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2237868774
- Cited by
- 1,652
- References
- 60
- Citations by year
- 2026: 156 · 2025: 188 · 2024: 181 · 2023: 199 · 2022: 204 · 2021: 196 · 2020: 173 · 2019: 141 · 2018: 112 · 2017: 74 · 2016: 28
- FWCI
- 33.24
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Chemistry of Materials (publishedVersion, other-oa)
- DSpace@MIT (Massachusetts Institute of Technology) (submittedVersion, cc-by-nc)
- Funders
- Samsung (NA)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Materials Science › Materials Chemistry › Thermal Expansion and Ionic Conductivity
- Keywords
- solid-state batteries, solid electrolytes, interfacial resistance, interfacial stability, interfacial phase formation, high-voltage cathodes, electrochemical stability window, electrolyte decomposition products, lithium-ion batteries
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