The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode
Abstract
Rechargeable zinc-ion batteries (ZIBs) with high energy densities appear promising to meet the increasing demand for safe and sustainable energy storage devices. However, electrode research on this low-cost and green system are faced with stiff challenges of identifying materials that permit divalent ion-intercalation/deintercalation. Herein, we present layered-type LiV 3 O 8 (LVO) as a prospective intercalation cathode for zinc-ion batteries (ZIBs) with high storage capacities. The detailed phase evolution study during Zn intercalation using electrochemistry, in situ XRD, and simulation techniques reveals the large presence of a single-phase domain that proceeds via a stoichiometric ZnLiV 3 O 8 phase to reversible solid–solution Zn y LiV 3 O 8 ( y > 1) phase. The unique behavior, which is different from the reaction with lithium, contributes to high specific capacities of 172 mAh g –1 and amounts to 75% retention of the maximum capacity achieved in 65 cycles with 100% Coulombic efficiency at a current density of 133 mA g –1 . The remarkable performance makes the development of this low-cost and safe battery technology very promising, and this study also offers opportunities to enhance the understanding on electrochemically induced metastable phases for energy storage applications.
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Cited by
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Blanc, L. E., Kundu, D., & Nazar, L. F. (2020) · Joule · doi:10.1016/j.joule.2020.03.002 · Cited by 2,113
Wan, F., Zhang, L., Dai, X., Wang, X., Niu, Z., & Chen, J. (2018) · Nature Communications · doi:10.1038/s41467-018-04060-8 · Cited by 1,750
Rechargeable Aqueous Zn–V2O5 Battery with High Energy Density and Long Cycle Life
Zhang, N., Dong, Y., Jia, M., Bian, X., Wang, Y., Qiu, M., Xu, J., Liu, Y., Jiao, L., & Cheng, F. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00565 · Cited by 1,052
Sodium Ion Stabilized Vanadium Oxide Nanowire Cathode for High‐Performance Zinc‐Ion Batteries
He, P., Zhang, G., Liao, X., Yan, M., Xu, X., An, Q., Liu, J., & Mai, L. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702463 · Cited by 867
Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface
Kundu, D., Hosseini Vajargah, S., Wan, L., Adams, B., Prendergast, D., & Nazar, L. F. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00378e · Cited by 833
Metadata
- Authors
- Alfaruqi, M. H., Mathew, V., Song, J., Kim, S., Islam, S., Pham, D. T., Jo, J., Kim, S., Baboo, J. P., Xiu, Z., Lee, K.-S., Sun, Y.-K., & Kim, J.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-02-15
- Volume
- 29
- Issue
- 4
- Pages
- 1684-1694
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2588191260
- Cited by
- 577
- References
- 26
- FWCI
- 25.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Alfaruqi, M. H., Mathew, V., Song, J., Kim, S., Islam, S., Pham, D. T., Jo, J., Kim, S., Baboo, J. P., Xiu, Z., Lee, K.-S., Sun, Y.-K., & Kim, J. (2017). Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.6b05092
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