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Cited by 162

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Boosting the Catalytic Performance of Iron Phosphide Nanorods for the Oxygen Evolution Reaction by Incorporation of Manganese

Open access
Li, Da, Baydoun, Habib, Kulikowski, Bogdan, Brock, Stephanie L.·2017·Chemistry of Materials

Abstract

Abstract The lack of efficient and stable oxygen evolution reaction (OER) catalysts comprising inexpensive Earth-abundant materials limits the viability of water splitting as a clean and renewable source of energy. In this work, we report the synthesis of homogeneous ternary Fe2–xMnxP nanorods with control of Mn incorporation (0 ≤ x ≤ 0.9) from the solution-phase reaction of manganese and iron carbonyl complexes with trioctylphosphine. The OER activity of Fe2–xMnxP nanorods dramatically increases with the incorporation of Mn (overpotential as low as 0.44 V at 10 mA/cm2 for x = 0.9), and the overpotential can be further decreased (by nearly 0.1 V) by postdeposition annealing. The enhanced OER activity and stability, along with the abundance and availability of Fe and Mn, make bimetallic manganese–iron phosphides a promising class of materials for more cost-effective and efficient water oxidation catalysis.

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Metadata

Authors
Li, D., Baydoun, H., Kulikowski, B., & Brock, S. L.
Venue
Chemistry of Materials
Published
2017-03-29
Volume
29
Issue
7
Pages
3048-3054
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2596567502
Cited by
162
References
2
FWCI
6.55
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Boosting the Catalytic Performance of Iron Phosphide Nanorods for the Oxygen Evolution Reaction by Incorporation of Manganese. https://app.cochat.ai/papers/10.1021/acs.chemmater.7b00055
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Li, D., Baydoun, H., Kulikowski, B., & Brock, S. L. (2017). Boosting the Catalytic Performance of Iron Phosphide Nanorods for the Oxygen Evolution Reaction by Incorporation of Manganese. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.7b00055

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