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Cited by 573

The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.

One-Pot Synthesis of Zeolitic Imidazolate Framework 67-Derived Hollow Co3S4@MoS2 Heterostructures as Efficient Bifunctional Catalysts

Guo, Yanna, Tang, Jing, Qian, Huayu, Wang, Zhongli, Yamauchi, Yusuke·2017·Chemistry of Materials

Abstract

Herein, we present a facile metal–organic framework-engaged strategy to synthesize hollow Co 3 S 4 @MoS 2 heterostructures as efficient bifunctional catalysts for both H 2 and O 2 generation. The well-known cobalt-based metal–organic zeolitic imidazolate frameworks (ZIF-67) are used not only as the morphological template but also as the cobalt precursor. During the two-step temperature-raising hydrothermal process, ZIF-67 polyhedrons are first transformed to hollow cobalt sulfide polyhedrons by sulfidation, and then molybdenum disulfide nanosheets further grow and deposit on the surface of hollow cobalt sulfide polyhedrons at the increased temperature. The crystalline hollow Co 3 S 4 @MoS 2 heterostructures are finally obtained after subsequent thermal annealing under a N 2 atmosphere. Due to the synergistic effects between the hydrogen evolution reaction active catalyst of MoS 2 and the oxygen evolution reaction active catalyst of Co 3 S 4, the obtained hollow Co 3 S 4 @MoS 2 heterostructures exhibit outstanding bifunctional catalytic performances toward both hydrogen and oxygen evolution reactions in acidic and alkaline media.

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Metadata

Authors
Guo, Y., Tang, J., Qian, H., Wang, Z., & Yamauchi, Y.
Venue
Chemistry of Materials
Published
2017-06-15
Volume
29
Issue
13
Pages
5566-5573
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2625512328
Cited by
573
References
12
FWCI
19.07
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: One-Pot Synthesis of Zeolitic Imidazolate Framework 67-Derived Hollow Co3S4@MoS2 Heterostructures as Efficient Bifunctional Catalysts. https://app.cochat.ai/papers/10.1021/acs.chemmater.7b00867
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Guo, Y., Tang, J., Qian, H., Wang, Z., & Yamauchi, Y. (2017). One-Pot Synthesis of Zeolitic Imidazolate Framework 67-Derived Hollow Co3S4@MoS2 Heterostructures as Efficient Bifunctional Catalysts. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.7b00867

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