The DOI matches its Crossref record; 519 of the 519 references it cites were found in a registry or an index.
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Open accessAbstract
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency and selectivity. However, the structural complexity and vulnerability hamper the application potentials of enzymes. Driven by the practical demand for chemical conversion, there is a long-sought quest for bioinspired catalysts reproducing and even surpassing the functions of natural enzymes. As nanoporous materials with high surface areas and crystallinity, metal-organic frameworks (MOFs) represent an exquisite case of how natural enzymes and their active sites are integrated into porous solids, affording bioinspired heterogeneous catalysts with superior stability and customizable structures. In this review, we comprehensively summarize the advances of bioinspired MOFs for catalysis, discuss the design principle of various MOF-based catalysts, such as MOF-enzyme composites and MOFs embedded with active sites, and explore the utility of these catalysts in different reactions. The advantages of MOFs as enzyme mimetics are also highlighted, including confinement, templating effects, and functionality, in comparison with homogeneous supramolecular catalysts. A perspective is provided to discuss potential solutions addressing current challenges in MOF catalysis.
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Cites
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Self-citationA New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
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Metadata
- Authors
- Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2023-04-12
- Volume
- 123
- Issue
- 9
- Pages
- 5347-5420
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W4365135900
- Cited by
- 490
- References
- 519
- FWCI
- 4.82
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023). Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.2c00879
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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