The DOI matches its Crossref record; 737 of the 737 references it cites were found in a registry or an index.
Intermetallic Nanocrystals for Fuel-Cells-Based Electrocatalysis
Abstract
Electrocatalysis underpins the renewable electrochemical conversions for sustainability, which further replies on metallic nanocrystals as vital electrocatalysts. Intermetallic nanocrystals have been known to show distinct properties compared to their disordered counterparts, and been long explored for functional improvements. Tremendous progresses have been made in the past few years, with notable trend of more precise engineering down to an atomic level and the investigation transferring into more practical membrane electrode assembly (MEA), which motivates this timely review. After addressing the basic thermodynamic and kinetic fundamentals, we discuss classic and latest synthetic strategies that enable not only the formation of intermetallic phase but also the rational control of other catalysis-determinant structural parameters, such as size and morphology. We also demonstrate the emerging intermetallic nanomaterials for potentially further advancement in energy electrocatalysis. Then, we discuss the state-of-the-art characterizations and representative intermetallic electrocatalysts with emphasis on oxygen reduction reaction evaluated in a MEA setup. We summarize this review by laying out existing challenges and offering perspective on future research directions toward practicing intermetallic electrocatalysts for energy conversions.
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Cites
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Cited by
High-entropy alloy electrocatalysts go to (sub-)nanoscale
Li, M., Lin, F., Zhang, S., Zhao, R., Tao, L., Li, L., Li, J., Zeng, L., Luo, M., & Guo, S. (2024) · Science Advances · doi:10.1126/sciadv.adn2877 · Cited by 177
Self-citationFan, X., Chen, W., Xie, L., Liu, X., Ding, Y., Zhang, L., Tang, M., Liao, Y., Yang, Q., Fu, X., et al. (2024) · Advanced Materials · doi:10.1002/adma.202313179 · Cited by 89
Xiao, Y., Ying, J., Chen, J., Yang, X., Tian, G., Li, J., Janiak, C., & Yang, X. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202418264 · Cited by 47
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Metadata
- Authors
- Lin, F., Li, M., Zeng, L., Luo, M., & Guo, S.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2023-11-01
- Volume
- 123
- Issue
- 22
- Pages
- 12507-12593
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W4388142001
- Cited by
- 257
- References
- 737
- FWCI
- 4.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lin, F., Li, M., Zeng, L., Luo, M., & Guo, S. (2023). Intermetallic Nanocrystals for Fuel-Cells-Based Electrocatalysis. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.3c00382
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