The DOI matches its Crossref record; 101 of the 101 references it cites were found in a registry or an index.
Water-Mediated Ion Pairing: Occurrence and Relevance
Open accessAbstract
We present an overview of the studies of ion pairing in aqueous media of the past decade. In these studies, interactions between ions, and between ions and water, are investigated with relatively novel approaches, including dielectric relaxation spectroscopy, far-infrared (terahertz) absorption spectroscopy, femtosecond mid-infrared spectroscopy, and X-ray spectroscopy and scattering, as well as molecular dynamics simulation methods. With these methods, it is found that ion pairing is not a rare phenomenon only occurring for very particular, strongly interacting cations and anions. Instead, for many salt solutions and their interfaces, the measured and calculated structure and dynamics reveal the presence of a distinct concentration of contact ion pairs (CIPs), solvent shared ion pairs (SIPs), and solvent-separated ion pairs (2SIPs). We discuss the importance of specific ion-pairing interactions between cations like Li(+) and Na(+) and anionic carboxylate and phosphate groups for the structure and functioning of large (bio)molecular systems.
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Cites
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Cited by
2D Laminar Membranes for Selective Water and Ion Transport
Kang, Y., Xia, Y., Wang, H., & Zhang, X. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201902014 · Cited by 325
Kinetic pathways of water exchange in the first hydration shell of magnesium
Schwierz, N. (2020) · The Journal of Chemical Physics · doi:10.1063/1.5144258 · Cited by 52
Metadata
- Authors
- van der Vegt, N. F. A., Haldrup, K., Roke, S., Zheng, J., Lund, M., & Bakker, H. J.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-05-06
- Volume
- 116
- Issue
- 13
- Pages
- 7626-7641
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2346666467
- Cited by
- 284
- References
- 101
- FWCI
- 1.05
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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