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Cited by 1,766

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

The Statistical Mechanical Theory of Solutions. I

Kirkwood, John G., Buff, Frank P.·1951·The Journal of Chemical Physics
DOI 10.1063/1.1748352
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Abstract

A general statistical mechanical theory of solutions is developed with the aid of the theory of composition fluctuations in the grand canonical ensemble. It is shown that the derivatives of the chemical potentials and osmotic pressure with respect to concentrations, the partial molar volumes, and compressibility may be expressed in terms of integrals of the radial distribution functions of the several types of molecular pairs present in the solution. Explicit coefficients of a q-fraction expansion of the thermodynamic variables are presented in a detailed treatment of the two-component system.

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Metadata

Authors
Kirkwood, J. G., & Buff, F. P.
Venue
The Journal of Chemical Physics
Publisher
AIP Publishing
Published
1951-06-01
Volume
19
Issue
6
Pages
774-777
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
DOI
10.1063/1.1748352
OpenAlex
W2093806300
Cited by
1,766
References
2
FWCI
4.19
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The Statistical Mechanical Theory of Solutions. I. https://app.cochat.ai/papers/10.1063/1.1748352
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Kirkwood, J. G., & Buff, F. P. (1951). The Statistical Mechanical Theory of Solutions. I. The Journal of Chemical Physics. https://doi.org/10.1063/1.1748352

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.