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Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins
Open accessAbstract
Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to complex molecule synthesis. We also provide a mechanistic framework for understanding this compendium of radical reactions.
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Cites
LXXIII.—Oxidation of tartaric acid in presence of iron
Fenton, H. J. H. (1894) · J. Chem. Soc., Trans. · doi:10.1039/ct8946500899 · Cited by 3,179
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Alig, L., Fritz, M., & Schneider, S. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00555 · Cited by 887
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Branch-Selective Hydroarylation: Iodoarene–Olefin Cross-Coupling
Green, S. A., Matos, J. L. M., Yagi, A., & Shenvi, R. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08507 · Cited by 287
Self-citationEnantioselective Chemo‐ and Biocatalysis: Partners in Retrosynthesis
Hönig, M., Sondermann, P., Turner, N. J., & Carreira, E. M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612462 · Cited by 284
Metadata
- Authors
- Crossley, S. W. M., Obradors, C., Martinez, R. M., & Shenvi, R. A.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-07-27
- Volume
- 116
- Issue
- 15
- Pages
- 8912-9000
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2479201755
- Cited by
- 1,128
- References
- 1
- FWCI
- 2.03
- Type
- journal article
- Language
- en
- Open access
- green
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- Crossley, S. W. M., Obradors, C., Martinez, R. M., & Shenvi, R. A. (2016). Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.6b00334
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