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Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity
Abstract
Hydride complexes of copper, silver, and gold encompass a broad array of structures, and their distinctive reactivity has enabled dramatic recent advances in synthesis and catalysis. This Review summarizes the synthesis, characterization, and key stoichiometric reactions of isolable or observable coinage metal hydrides. It discusses catalytic processes in which coinage metal hydrides are known or probable intermediates, and presents mechanistic studies of selected catalytic reactions. The purpose of this Review is to convey how developments in coinage metal hydride chemistry have led to new organic transformations, and how developments in catalysis have in turn inspired the synthesis of reactive new complexes.
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Cites
Nucleus-Independent Chemical Shifts (NICS) as an Aromaticity Criterion
Chen, Z., Wannere, C. S., Corminboeuf, C., Puchta, R., & Schleyer, P. V. R. (2005) · Chemical Reviews · doi:10.1021/cr030088+ · Cited by 3,847
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Cited by
Atomically precise copper nanoclusters and their applications
Liu, X., & Astruc, D. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.01.001 · Cited by 322
Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications
Jazzar, R., Soleilhavoup, M., & Bertrand, G. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00043 · Cited by 320
C–C and C–X coupling reactions of unactivated alkyl electrophiles using copper catalysis
Cheng, L.-J., & Mankad, N. P. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00316f · Cited by 264
Li, Y., Hammoud, A., Bouteiller, L., & Raynal, M. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b13157 · Cited by 81
Metadata
- Authors
- Jordan, A. J., Lalic, G., & Sadighi, J. P.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-07-25
- Volume
- 116
- Issue
- 15
- Pages
- 8318-8372
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2476839356
- Cited by
- 476
- References
- 2
- FWCI
- 1.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jordan, A. J., Lalic, G., & Sadighi, J. P. (2016). Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.6b00366
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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