Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides with Discrete Metal Complexes: Structure–Property Relationships

Principles of Polymerization

Odian, G. (2004) · doi:10.1002/047147875x · Cited by 7,158

The Path Forward for Biofuels and Biomaterials

Ragauskas, A. J., Williams, C. K., Davison, B. H., Britovsek, G., Cairney, J., Eckert, C. A., Frederick, W. J., Hallett, J. P., Leak, D. J., Liotta, C. L., et al. (2006) · Science · doi:10.1126/science.1114736 · Cited by 5,741

An Overview of Polylactides as Packaging Materials

Auras, R., Harte, B., & Selke, S. (2004) · Macromolecular Bioscience · doi:10.1002/mabi.200400043 · Cited by 3,454

Biodegradable Polymers for the Environment

Gross, R. A., & Kalra, B. (2002) · Science · doi:10.1126/science.297.5582.803 · Cited by 2,029

Biodegradable polyesters for medical and ecological applications

Ikada, Y., & Tsuji, H. (2000) · Macromolecular Rapid Communications · doi:10.1002/(sici)1521-3927(20000201)21:3 · Cited by 1,538

Polyurethanes: Versatile Materials and Sustainable Problem Solvers for Today’s Challenges

Engels, H., Pirkl, H., Albers, R., Albach, R. W., Krause, J., Hoffmann, A., Casselmann, H., & Dormish, J. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201302766 · Cited by 1,236

Applications of life cycle assessment to NatureWorks™ polylactide (PLA) production

Vink, E. T. H., Rábago, K. R., Glassner, D. A., & Gruber, P. R. (2003) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(02)00372-5 · Cited by 1,093

A review of biodegradable polymers: uses, current developments in the synthesis and characterization of biodegradable polyesters, blends of biodegradable polymers and recent advances in biodegradation studies

Amass, W., Amass, A. J., & Tighe, B. J. (1998) · Polymer International · doi:10.1002/(sici)1097-0126(1998100)47:2 · Cited by 1,015

Lactic acid: recent advances in products, processes and technologies — a review

Datta, R., & Henry, M. P. (2006) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.1486 · Cited by 973

New emerging trends in synthetic biodegradable polymers—Polylactide: A critique

Gupta, A. P., & Kumar, V. (2007) · European Polymer Journal · doi:10.1016/j.eurpolymj.2007.06.045 · Cited by 941

Phosphazene/Lewis Acids as Highly Efficient Cooperative Catalyst for Synthesis of High‐Molecular‐Weight Polyesters by Ring‐Opening Alternating Copolymerization of Epoxide and Anhydride

Zhang, J., Wang, L., Liu, S., & Li, Z. (2020) · Journal of Polymer Science · doi:10.1002/pol.20190175 · Cited by 54

Borane catalysis for epoxide (co)polymerization

Naumann, S. (2023) · Polymer Chemistry · doi:10.1039/d3py00018d · Cited by 53

Phosphazene-Catalyzed Alternating Copolymerization of Dihydrocoumarin and Ethylene Oxide: Weaker Is Better

Zhang, H., Hu, S., Zhao, J., & Zhang, G. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b00599 · Cited by 54

Orthogonal functionalization of alternating polyesters: selective patterning of (AB) n sequences

Yi, N., Chen, T. T. D., Unruangsri, J., Zhu, Y., & Williams, C. K. (2019) · Chemical Science · doi:10.1039/c9sc03756j · Cited by 53

Stereocomplexation of Stereoregular Aliphatic Polyesters: Change from Amorphous to Semicrystalline Polymers with Single Stereocenter Inversion

Popowski, Y., Lu, Y., Coates, G. W., & Tolman, W. B. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c02981 · Cited by 52

Cobalt-Catalyzed Trifluoromethoxylation of Epoxides

Liu, J., Wei, Y., & Tang, P. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b10298 · Cited by 54

Well‐Defined Poly(Ester Amide)‐Based Homo‐ and Block Copolymers by One‐Pot Organocatalytic Anionic Ring‐Opening Copolymerization of N‐Sulfonyl Aziridines and Cyclic Anhydrides

Xu, J., & Hadjichristidis, N. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202015339 · Cited by 50

The versatile, functional polyether, polyepichlorohydrin: History, synthesis, and applications

Shukla, G., & Ferrier, R. C. (2021) · Journal of Polymer Science · doi:10.1002/pol.20210514 · Cited by 51

Copolymerization of cyclic esters, epoxides and anhydrides: evidence of the dual role of the monomers in the reaction mixture

Isnard, F., Carratù, M., Lamberti, M., Venditto, V., & Mazzeo, M. (2018) · Catalysis Science & Technology · doi:10.1039/c8cy01174e · Cited by 49

One-Step Synthesis of Sequence-Controlled Polyester-block-Poly(ester-alt-thioester) by Chemoselective Multicomponent Polymerization

Chen, X.-L., Wang, B., Song, D., Pan, L., & Li, Y. (2022) · Macromolecules · doi:10.1021/acs.macromol.1c02303 · Cited by 48

A recyclable polyester library from reversible alternating copolymerization of aldehyde and cyclic anhydride

Zhang, X., Guo, W., Zhang, C., & Zhang, X. (2023) · Nature Communications · doi:10.1038/s41467-023-41136-6 · Cited by 49

Alternating copolymerization of epoxides with carbon dioxide or cyclic anhydrides using bimetallic nickel and cobalt catalysts: Preparation of hydrophilic nanofibers from functionalized polyesters

Chang, C., Tsai, C., Lin, W., Su, Y., Chuang, H., Liu, W., Chen, C., Chen, C.-K., & Ko, B. (2018) · Polymer · doi:10.1016/j.polymer.2018.02.063 · Cited by 49

Molecular bionics – engineering biomaterials at the molecular level using biological principles

Rodríguez‐Arco, L., Poma, A., Ruiz‐Pérez, L., Scarpa, E., Ngamkham, K., & Battaglia, G. (2018) · Biomaterials · doi:10.1016/j.biomaterials.2018.10.044 · Cited by 49

Catalyst Engineering Empowers the Creation of Biomass-Derived Polyesters and Polycarbonates

Brandolese, A., & Kleij, A. W. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.2c00204 · Cited by 49

Bio-Based Polyesters with High Glass-Transition Temperatures and Gas Barrier Properties Derived from Renewable Rigid Tricyclic Diacid or Tetracyclic Anhydride

Zhang, H., Zhou, G., Jiang, M. Y., Zhang, H., Wang, H., Wu, Y., & Wang, R. (2020) · Macromolecules · doi:10.1021/acs.macromol.0c00344 · Cited by 48

Recent Developments in Ring-Opening Copolymerization of Epoxides With CO2 and Cyclic Anhydrides for Biomedical Applications

Xue, L., Tan, F., & Zhu, Y. (2021) · Frontiers in Chemistry · doi:10.3389/fchem.2021.647245 · Cited by 48

Versatile Ring-Opening Copolymerization and Postprinting Functionalization of Lactone and Poly(propylene fumarate) Block Copolymers: Resorbable Building Blocks for Additive Manufacturing

Petersen, S. R., Wilson, J. A., & Becker, M. L. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b01372 · Cited by 45

Cyclic and Linear Polyhydroxylbutyrates from Ring-Opening Polymerization of β-Butyrolactone with Amido-Oxazolinate Zinc Catalysts

Shaik, M., Peterson, J., & Du, G. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b02096 · Cited by 46

Recyclable Sulfur-Rich Polymers with Enhanced Thermal, Mechanical, and Optical Performance

Zhao, J.-Z., Yue, T., Ren, B., Liu, Y., Ren, W., & Lu, X. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01628 · Cited by 45

Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalysts

Zhang, Y., Yang, G., Xie, R. J., Zhu, X., & Wu, G. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c07857 · Cited by 45

Roadmap to the sustainable synthesis of polymers: From the perspective of CO2 upcycling

Sadeghi, K., Jeon, Y., & Seo, J. (2023) · Progress in Materials Science · doi:10.1016/j.pmatsci.2023.101103 · Cited by 45

Enantioselective terpolymerization of racemic and meso -epoxides with anhydrides for preparation of chiral polyesters

Li, J., Liu, Y., Ren, W., & Lu, X. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2005519117 · Cited by 44

Biodegradable Copolymers from CO2, Epoxides, and Anhydrides Catalyzed by Organoborane/Tertiary Amine Pairs: High Selectivity and Productivity

Liang, J., Ye, S., Wang, S., Wang, S., Han, D., Huang, S., Huang, Z., Liu, W., Xiao, M., Sun, L., et al. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01118 · Cited by 43

Synthesis of Sequence‐specific Poly(ester‐carbonate) Copolymers via Chemoselective Terpolymerization Controlled by the Stoichiometric Ratio of Phosphazene/Triethylborane

Ma, Y., You, X.-X., Zhang, J., Wang, X., Kou, X., Liu, S., Zhong, R., & Li, Z. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202303315 · Cited by 44

Reversible Transformation between Amorphous and Crystalline States of Unsaturated Polyesters by Cis–Trans Isomerization

Wan, Z., Ren, W., Yang, S., Li, M., Gu, G., & Lu, X. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201910369 · Cited by 43

Structural Metamorphoses of d -Xylose Oxetane- and Carbonyl Sulfide-Based Polymers In Situ during Ring-Opening Copolymerizations

Tran, D. K., Braaksma, A. N., Andras, A. M., Boopathi, S. K., Darensbourg, D. J., & Wooley, K. L. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c05529 · Cited by 42

Synthesis of Tris-Phosphazene Bases with Triazine as Core and Their Applications for Efficient Ring-Opening Alternating Copolymerization of Epoxide and Anhydride: Notable Effect of Basicity and Molecular Size

Wang, L., Zhang, J., Zhao, N., Ren, C., Liu, S., & Li, Z. (2020) · ACS Macro Letters · doi:10.1021/acsmacrolett.0c00564 · Cited by 42

Ortho -vanillin derived Al( iii ) and Co( iii ) catalyst systems for switchable catalysis using ε-decalactone, phthalic anhydride and cyclohexene oxide

Diment, W. T., Stößer, T., Kerr, R. W. F., Phanopoulos, A., Durr, C. B., & Williams, C. K. (2021) · Catalysis Science & Technology · doi:10.1039/d0cy02164d · Cited by 42

Lithium achieves sequence selective ring-opening terpolymerisation (ROTERP) of ternary monomer mixtures

Rupf, S. M., Pröhm, P., & Plajer, A. J. (2022) · Chemical Science · doi:10.1039/d2sc01776h · Cited by 42

Alternating ring-opening copolymerization of phthalic anhydride with epoxides catalysed by salophen chromium( iii ) complexes. An effect of substituents in salophen ligands

Bester, K., Bukowska, A., Myśliwiec, B., Hus, K., Tomczyk, D., Urbaniak, P., & Bukowski, W. (2018) · Polymer Chemistry · doi:10.1039/c8py00048d · Cited by 41

Mg( ii ) heterodinuclear catalysts delivering carbon dioxide derived multi-block polymers

Rosetto, G., Deacy, A. C., & Williams, C. K. (2021) · Chemical Science · doi:10.1039/d1sc03856g · Cited by 41

Selective Ring‐Opening Polymerization of Non‐Strained γ‐Butyrolactone Catalyzed by A Cyclic Trimeric Phosphazene Base

Zhao, N., Ren, C., Li, H., Li, Y., Liu, S., & Li, Z. (2017) · Angewandte Chemie · doi:10.1002/ange.201707122 · Cited by 43

Ring Opening Copolymerization of Boron-Containing Anhydride with Epoxides as a Controlled Platform to Functional Polyesters

Vidal, F., Smith, S., & Williams, C. K. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c03261 · Cited by 41

Cationic Co–Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide

Hatazawa, M., Takahashi, R., Deng, J., Houjou, H., & Nozaki, K. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01130 · Cited by 40

Fast and Controlled Ring-Opening Polymerization of Cyclic Esters by Alkoxides and Cyclic Amides

Tan, C., Xiong, S., & Chen, C. (2018) · Macromolecules · doi:10.1021/acs.macromol.7b02697 · Cited by 43

Dinuclear iron( iii ) complexes bearing phenylene-bridged bis(amino triphenolate) ligands as catalysts for the copolymerization of cyclohexene oxide with carbon dioxide or phthalic anhydride

Shi, Z. W., Jiang, Q., Song, Z., Wang, Z., & Gao, C. (2018) · Polymer Chemistry · doi:10.1039/c8py00824h · Cited by 41

Design and structure of catalysts: syntheses of carbon dioxide-based copolymers with cyclic anhydrides and/or cyclic esters

Liang, J., Ye, S., Wang, S., Xiao, M., & Meng, Y. (2020) · Polymer Journal · doi:10.1038/s41428-020-0374-1 · Cited by 40

Synthesis of High-Molecular-Weight Maleic Anhydride-Based Polyesters with Enhanced Properties

Hu, L., Zhang, C., Chen, D., Cao, X., Yang, J., & Zhang, X. (2020) · ACS Applied Polymer Materials · doi:10.1021/acsapm.0c01075 · Cited by 39

Heterotrinuclear Ring Opening Copolymerization Catalysis: Structure–activity Relationships

Plajer, A. J., & Williams, C. K. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c04449 · Cited by 39

Polymers from Sugars and Cyclic Anhydrides: Ring-Opening Copolymerization of a d -Xylose Anhydrosugar Oxetane

McGuire, T. M., Clark, E. F., & Buchard, A. (2021) · Macromolecules · doi:10.1021/acs.macromol.1c00365 · Cited by 38

A highly active, thermally robust iron( iii )/potassium( i ) heterodinuclear catalyst for bio-derived epoxide/anhydride ring-opening copolymerizations

Diment, W. T., Rosetto, G., Ezaz-Nikpay, N., Kerr, R. W. F., & Williams, C. K. (2023) · Green Chemistry · doi:10.1039/d2gc04580j · Cited by 38

Well-Designed Unsymmetrical Salphen-Al Complexes: Synthesis, Characterization, and Ring-Opening Polymerization Catalysis

Luo, W., Shi, T., Liu, S., Zuo, W., & Li, Z. (2017) · Organometallics · doi:10.1021/acs.organomet.7b00106 · Cited by 38

Ring‐Opening Copolymerization of Maleic Anhydride with Functional Epoxides: Poly(propylene fumarate) Analogues Capable of Post‐Polymerization Modification

Chen, Y., Wilson, J. A., Petersen, S. R., Luong, D., Sallam, S., Mao, J., Wesdemiotis, C., & Becker, M. L. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201807419 · Cited by 37

Tug‐of‐War between Two Distinct Catalytic Sites Enables Fast and Selective Ring‐Opening Copolymerizations

Wang, J., Zhu, Y., Li, M., Wang, Y., Wang, X., & Tao, Y. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202208525 · Cited by 37

Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes

Buchaca, M. M. D. S., de la Cruz‐Martínez, F., Martı́nez, J., Alonso‐Moreno, C., Fernández‐Baeza, J., Tejeda, J., Niza, E., Castro‐Osma, J. A., Otero, A., & Lara‐Sánchez, A. (2018) · ACS Omega · doi:10.1021/acsomega.8b02759 · Cited by 37

Metal-Free Alternating Copolymerization of Nonstrained γ-Selenobutyrolactone with Epoxides for Selenium-Rich Polyesters

Zhang, C., Cao, X., & Zhang, X. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b02025 · Cited by 36

Ring‐Opening Copolymerization of Styrene Oxide and Cyclic Anhydrides by using Highly Effective Zinc Amido–Oxazolinate Catalysts

Abbina, S., Chidara, V. K., & Du, G. (2017) · ChemCatChem · doi:10.1002/cctc.201601679 · Cited by 36

Recent trends in ring opening of epoxides with sulfur nucleophiles

Ahmad, S., Zahoor, A. F., Naqvi, S. A. R., & Akash, M. S. H. (2017) · Molecular Diversity · doi:10.1007/s11030-017-9796-x · Cited by 35

CO2-Tuned Sequential Synthesis of Stereoblock Copolymers Comprising a Stereoregularity-Adjustable Polyester Block and an Atactic CO2-Based Polycarbonate Block

Han, B., Liu, B., Ding, H., Duan, Z., Wang, X., & Théato, P. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01905 · Cited by 36

The contribution of metalloporphyrin complexes in molecular sensing and in sustainable polymerization processes: a new and unique perspective

Strianese, M., Pappalardo, D., Mazzeo, M., Lamberti, M., & Pellecchia, C. (2021) · Dalton Transactions · doi:10.1039/d1dt00841b · Cited by 35

One‐Step Access to Sequence‐Controlled Block Copolymers by Self‐Switchable Organocatalytic Multicomponent Polymerization

Ji, H., Wang, B., Pan, L., & Li, Y. (2018) · Angewandte Chemie · doi:10.1002/ange.201810083 · Cited by 35

Partners in Epoxide Copolymerization Catalysis: Approach to High Activity and Selectivity

Lu, X., & Ren, B. (2022) · Chinese Journal of Polymer Science · doi:10.1007/s10118-022-2744-y · Cited by 35

Chain end-group selectivity using an organometallic Al( iii )/K( i ) ring-opening copolymerization catalyst delivers high molar mass, monodisperse polyesters

Diment, W. T., & Williams, C. K. (2022) · Chemical Science · doi:10.1039/d2sc02752f · Cited by 35

Switchable Polymerization Triggered by Fast and Quantitative Insertion of Carbon Monoxide into Cobalt–Oxygen Bonds

Wang, Y., Zhao, Y., Zhu, S., Zhou, X., Xu, J., Xie, X., & Poli, R. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201914216 · Cited by 35

[OSSO]-bisphenolate metal complexes: A powerful and versatile tool in polymerization catalysis

Paradiso, V., Capaccio, V., Lamparelli, D. H., & Capacchione, C. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213644 · Cited by 34

Trinuclear salphen–chromium( III )chloride complexes as catalysts for the alternating copolymerization of epoxides and cyclic anhydrides

Cui, L., Ren, B., & Lu, X. (2021) · Journal of Polymer Science · doi:10.1002/pol.20210334 · Cited by 34

A Practical Polymer Electrolyte for Lithium and Sodium Batteries: Poly(pentyl malonate)

Yu, X., Hoffman, Z. J., Lee, J., Fang, C., Gido, L. A., Patel, V., Eitouni, H. B., Wang, R., & Balsara, N. P. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.2c02128 · Cited by 34

Biobased Bifunctional Monomers toward Functionalizable Polycarbonates and Poly(cyclic olefin)s with Tunable Properties

Wu, Y., Fan, H., Zhang, W., Wang, M., Cai, Z., & Zhu, J. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01754 · Cited by 34

Recent Advances in Sequence‐Controlled Ring‐Opening Copolymerizations of Monomer Mixtures

Wang, X., Huo, Z., Xie, X., Shanaiah, N., & Tong, R. (2022) · Chemistry - An Asian Journal · doi:10.1002/asia.202201147 · Cited by 34

Precise cooperative sulfur placement leads to semi-crystallinity and selective depolymerisability in CS2/oxetane copolymers

Fornacon‐Wood, C., Manjunatha, B. R., Stühler, M. R., Gallizioli, C., Müller, C., Pröhm, P., & Plajer, A. J. (2023) · Nature Communications · doi:10.1038/s41467-023-39951-y · Cited by 34

A Facile and Unprecedented Route to a Library of Thermostable Formaldehyde‐Derived Polyesters: Highly Active and Selective Copolymerization of Cyclic Acetals and Anhydrides

Zhang, X., Zhang, C., & Zhang, X. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202117316 · Cited by 33

Mechanistic mapping of (CS2/CO2)/epoxide copolymerization catalysis leads to terpolymers with improved degradability

Stephan, J., Stühler, M. R., Rupf, S. M., Neale, S. E., & Plajer, A. J. (2023) · Cell Reports Physical Science · doi:10.1016/j.xcrp.2023.101510 · Cited by 33

Azopolyesters with Intrinsic Crystallinity and Photoswitchable Reversible Solid‐to‐Liquid Transitions

Li, J., Zhang, Q., & Lu, X. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202311158 · Cited by 33

Epoxides: methods of synthesis, reactivity, practical significance

Mamedova, V. L., Khikmatova, G. Z., Korshin, D. E., Mamedova, S. V., Gavrilova, E. L., & Mamedov, V. A. (2022) · Russian Chemical Reviews · doi:10.57634/rcr5049 · Cited by 32

Synthesis and Characterization of Biobased Polyesters with Tunable Tg by ROCOP of Beta-Elemene Oxides and Phthalic Anhydride

Monica, F. D., & Kleij, A. W. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c09189 · Cited by 32

Bio-based polyesters synthesized by ring-opening copolymerizations of eugenyl glycidyl ether and cyclic anhydrides using a binuclear [OSSO]CrCl complex

Liu, B., Chen, J., Liu, N., Ding, H., Wu, X., Dai, B., & Kim, I. (2020) · Green Chemistry · doi:10.1039/d0gc00469c · Cited by 32

Synergic Catalysis: the Importance of Intermetallic Separation in Co(III)K(I) Catalysts for Ring Opening Copolymerizations

Fiorentini, F., Eisenhardt, K. H. S., Deacy, A. C., & Williams, C. K. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.4c07405 · Cited by 31

Bifunctional Aminotriphenolate Complexes as One‐Component Catalysts for the Ring‐Opening Copolymerization of Cyclic Anhydrides and Epoxides

Martín, C., Pizzolante, A., Escudero‐Adán, E. C., & Kleij, A. W. (2018) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201800142 · Cited by 31

Recent Studies on Single Site Metal Alkoxide Complexes as Catalysts for Ring Opening Polymerization of Cyclic Compounds

Kayan, A. (2020) · Catalysis Surveys from Asia · doi:10.1007/s10563-019-09291-3 · Cited by 32

Sequential Polymerization from Complex Monomer Mixtures: Access to Multiblock Copolymers with Adjustable Sequence, Topology, and Gradient Strength

Xia, X., Gao, T., Li, F., Suzuki, R., Isono, T., & Satoh, T. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01976 · Cited by 31

Highly Regioselective Ring-Opening Polymerization of Cyclic Diester for Alternating Sequence-Controlled Copolymer Synthesis of Mandelic Acid and Glycolic Acid

Wang, Y., Jia, Z., Jiang, J., Mao, X., Pan, X., & Wu, J. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01515 · Cited by 31

Seminormal-BrCH 2 CH 2 OH-mediated electrochemical epoxidation of unactivated olefins

He, H., Lv, Y., Hu, J., Hou, Z., & Wang, L. (2024) · Green Chemistry · doi:10.1039/d3gc04061e · Cited by 30

Switchable Polymerization Catalysis Using a Tin(II) Catalyst and Commercial Monomers to Toughen Poly( l -lactide)

Yuntawattana, N., Gregory, G. L., Carrodeguas, L. P., & Williams, C. K. (2021) · ACS Macro Letters · doi:10.1021/acsmacrolett.1c00216 · Cited by 30

Key progresses of MOE key laboratory of macromolecular synthesis and functionalization in 2022

Deng, X., Chen, K., Pang, K., Liu, X., Gao, M., Ren, J., Yang, G., Wu, G., Zhang, C., Ni, X., et al. (2023) · Chinese Chemical Letters · doi:10.1016/j.cclet.2023.108861 · Cited by 29

Record-High-Molecular-Weight Polyesters from Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides Catalyzed by Hydrogen-Bond-Functionalized Imidazoles

Xie, Z., Yang, Z., Hu, C., Bai, F., Li, N., Wang, Z., Ku, S., Pang, X., Chen, X., & Wang, X. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.5c00426 · Cited by 30

Ti(IV)–Tris(phenolate) Catalyst Systems for the Ring-Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide

Raman, S. K., Deacy, A. C., Carrodeguas, L. P., Reis, N. V., Kerr, R. W. F., Phanopoulos, A., Morton, S., Davidson, M. G., & Williams, C. K. (2020) · Organometallics · doi:10.1021/acs.organomet.9b00845 · Cited by 29

Cobalt‐Mediated Switchable Catalysis for the One‐Pot Synthesis of Cyclic Polymers

Zhao, Y., Zhu, S., Liao, C., Wang, Y., Lam, J. W. Y., Zhou, X., Wang, X., Xie, X., & Tang, B. Z. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202106285 · Cited by 30

Alternating Copolymerization of Isobutylene Oxide and Cyclic Anhydrides: A New Route to Semicrystalline Polyesters

Hu, L., Zhang, X., Cao, X., Chen, D., Sun, Y., Zhang, C., & Zhang, X. (2021) · Macromolecules · doi:10.1021/acs.macromol.1c00793 · Cited by 29

Terpolymerization of CO2 with Epoxides and Cyclic Organic Anhydrides or Cyclic Esters

Lamparelli, D. H., & Capacchione, C. (2021) · Catalysts · doi:10.3390/catal11080961 · Cited by 29

Chemoselective Polymerizations

Zhu, N., Hu, X., Fang, Z. D., & Guo, K. (2021) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2021.101397 · Cited by 30

Synthesis of Unsaturated (Co)polyesters from Ring-Opening Copolymerization by Aluminum Bipyridine Bisphenolate Complexes with Improved Protonic Impurities Tolerance

Chen, X.-L., Wang, B., Pan, L., & Li, Y. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00034 · Cited by 29

Chromium Amino-bis(phenolate) Complexes as Catalysts for Ring-Opening Polymerization of Cyclohexene Oxide

Ambrose, K., Murphy, J. N., & Kozak, C. M. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01381 · Cited by 29

Ring-opening copolymerization of cyclic epoxide and anhydride using a five-coordinate chromium complex with a sterically demanding amino triphenolate ligand

Ryu, H. K., Bae, D. Y., Lim, H., Lee, E., & Son, K. (2020) · Polymer Chemistry · doi:10.1039/d0py00155d · Cited by 29

Al(III)/K(I) Heterodinuclear Polymerization Catalysts Showing Fast Rates and High Selectivity for Polyester Polyols

Shellard, E. J. K., Diment, W. T., Resendiz‐Lara, D. A., Fiorentini, F., Gregory, G. L., & Williams, C. K. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c05712 · Cited by 28

Catalytic challenges and strategies for the carbonylation of σ-bonds

Allah, T. N., Ponsard, L., Nicolas, E., & Cantat, T. (2021) · Green Chemistry · doi:10.1039/d0gc02343d · Cited by 28

Catalytic Ring-Opening Copolymerization of Fatty Acid Epoxides: Access to Functional Biopolyesters

Brandolese, A., Monica, F. D., Pericàs, M. À., & Kleij, A. W. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00321 · Cited by 29

Versatile organoaluminium catalysts based on heteroscorpionate ligands for the preparation of polyesters

Martı́nez, J., Buchaca, M. M. D. S., de la Cruz‐Martínez, F., Alonso‐Moreno, C., Sánchez‐Barba, L. F., Fernández‐Baeza, J., Rodríguez, A. M., Rodríguez‐Diéguez, A., Castro‐Osma, J. A., Otero, A., et al. (2018) · Dalton Transactions · doi:10.1039/c8dt01553h · Cited by 29

Tetracoordinate aluminum complexes bearing phenoxy-based ligands as catalysts for epoxide/anhydride copolymerization: some mechanistic insights

Isnard, F., Santulli, F., Cozzolino, M., Lamberti, M., Pellecchia, C., & Mazzeo, M. (2019) · Catalysis Science & Technology · doi:10.1039/c9cy00806c · Cited by 28

Bimetallic Zinc Catalysts for Ring-Opening Copolymerization Processes

de la Cruz‐Martínez, F., Buchaca, M. M. D. S., Martı́nez, J., Tejeda, J., Fernández‐Baeza, J., Alonso‐Moreno, C., Rodrı́guez, A. M., Castro‐Osma, J. A., & Lara‐Sánchez, A. (2020) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.0c00835 · Cited by 28

Heterodinuclear catalysts Zn( ii )/M and Mg( ii )/M, where M = Na( i ), Ca( ii ) or Cd( ii ), for phthalic anhydride/cyclohexene oxide ring opening copolymerisation

Deacy, A. C., Durr, C. B., Kerr, R. W. F., & Williams, C. K. (2021) · Catalysis Science & Technology · doi:10.1039/d1cy00238d · Cited by 28

Metal-free Lewis pair catalyst synergy for fully alternating copolymerization of norbornene anhydride and epoxides: Biocompatible tests for derived polymers

Kummari, A., Pappuru, S., Gupta, P. K., Chakraborty, D., & Verma, R. S. (2019) · Materials Today Communications · doi:10.1016/j.mtcomm.2019.02.007 · Cited by 27

Ring-Opening Copolymerizaton of Cyclohexene Oxide and Succinic Anhydride by Zinc and Magnesium Schiff-Base Complexes Containing Alkoxy Side Arms

Virachotikul, A., Laiwattanapaisarn, N., Wongmahasirikun, P., Piromjitpong, P., Chainok, K., & Phomphrai, K. (2020) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.0c00839 · Cited by 27

Borane catalyzed polymerization and depolymerization reactions controlled by Lewis acidic strength

Andrea, K. A., Wheeler, M. D., & Kerton, F. M. (2021) · Chemical Communications · doi:10.1039/d1cc02218k · Cited by 27

Origins of Catalyst-Controlled Chemoselectivity in Transition-Metal-Catalyzed Divergent Epoxide Conversion

Wang, X., Yang, K., Wang, Y.-N., Li, S., Wei, D., & Lan, Y. (2023) · ACS Catalysis · doi:10.1021/acscatal.3c01022 · Cited by 27

From oxygenated monomers to well-defined low-carbon polymers

Xia, Y., Zhang, C., Wang, Y., Liu, S., & Zhang, X. (2023) · Chinese Chemical Letters · doi:10.1016/j.cclet.2023.108860 · Cited by 27

Ring-opening alternating copolymerization of epichlorohydrin and cyclic anhydrides using single- and two-component metal-free catalysts

Zhang, B., Li, H., Luo, H., & Zhao, J. (2020) · European Polymer Journal · doi:10.1016/j.eurpolymj.2020.109820 · Cited by 27

High‐Performance Recyclable Polyester Elastomers Through Transient Strain‐Stiffening

Gao, C., Poon, K. C., Concilio, M., Zinn, T., Gregory, G. L., & Williams, C. K. (2025) · Advanced Materials · doi:10.1002/adma.202416674 · Cited by 26

Expanding the scope of organocatalysis for alternating copolymerization of dihydrocoumarin and styrene oxide

Zhang, H., Hu, S., Zhao, J., & Zhang, G. (2017) · European Polymer Journal · doi:10.1016/j.eurpolymj.2017.06.005 · Cited by 28

An Investigation of the Organoborane/Lewis Base Pairs on the Copolymerization of Propylene Oxide with Succinic Anhydride

Hu, L., Chen, D., Yang, J., & Zhang, X. (2020) · Molecules · doi:10.3390/molecules25020253 · Cited by 26

Recent progress in the construction of polymers with advanced chain structures via hybrid, switchable, and cascade chain-growth polymerizations

Chen, G., Xia, L., Wang, F., Zhang, Z., & You, Y. (2021) · Polymer Chemistry · doi:10.1039/d1py00274k · Cited by 27

Organo-catalyzed/initiated ring opening co-polymerization of cyclic anhydrides and epoxides: an emerging story

Ryzhakov, D., Printz, G., Jacques, B., Messaoudi, S., Dumas, F., Dagorne, S., & Bideau, F. L. (2021) · Polymer Chemistry · doi:10.1039/d1py00020a · Cited by 71

Bi-functional and mono-component organocatalysts for the ring-opening alternating co-polymerisation of anhydride and epoxide

Hirschmann, M., Zunino, R., Meninno, S., Falivene, L., & Fuoco, T. (2023) · Catalysis Science & Technology · doi:10.1039/d3cy01424j · Cited by 9

Catalytic Synergy Using Al(III) and Group 1 Metals to Accelerate Epoxide and Anhydride Ring-Opening Copolymerizations

Diment, W. T., Gregory, G. L., Kerr, R. W. F., Phanopoulos, A., Buchard, A., & Williams, C. K. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c04020 · Cited by 80

Commercial Group III–V Metal Alkoxide Catalysts for Selective Epoxide and Anhydride Ring Opening Copolymerization Delivering Poly(ester- alt -ethers)

Kerr, R. W. F., Craze, A. R., & Williams, C. K. (2026) · ACS Catalysis · doi:10.1021/acscatal.5c08568

Development of Highly Active and Regioselective Catalysts for the Copolymerization of Epoxides with Cyclic Anhydrides: An Unanticipated Effect of Electronic Variation

DiCiccio, A. M., Longo, J. M., Rodríguez-Calero, G. G., & Coates, G. W. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b03113 · Cited by 144