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Water-Lean Solvents for Post-Combustion CO2Capture: Fundamentals, Uncertainties, Opportunities, and Outlook
Abstract
This review is designed to foster the discussion regarding the viability of postcombustion CO 2 capture by water-lean solvents, by separating fact from fiction for both skeptics and advocates. We highlight the unique physical and thermodynamic properties of notable water-lean solvents, with a discussion of how such properties could translate to efficiency gains compared to aqueous amines. The scope of this review ranges from the purely fundamental molecular-level processes that govern solvent behavior to bench-scale testing, through process engineering and projections of process performance and cost. Key discussions of higher than expected CO 2 mass transfer, water tolerance, and compatibility with current infrastructure are presented along with current limitations and suggested areas where further solvent development is needed. We conclude with an outlook of the status of the field and assess the viability of water-lean solvents for postcombustion CO 2 capture.
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Laio, A., & Parrinello, M. (2002) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.202427399 · Cited by 5,626
Cited by
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Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Porous materials for carbon dioxide separations
Siegelman, R. L., Kim, E. J., & Long, J. R. (2021) · Nature Materials · doi:10.1038/s41563-021-01054-8 · Cited by 722
Phase change solvents for post-combustion CO2 capture: Principle, advances, and challenges
Zhang, S., Shen, Y., Wang, L., Chen, J., & Lu, Y. (2019) · Applied Energy · doi:10.1016/j.apenergy.2019.01.242 · Cited by 404
Nonaqueous amine-based absorbents for energy efficient CO2 capture
Guo, H., Li, C., Shi, X., Li, H., & Shen, S. (2019) · Applied Energy · doi:10.1016/j.apenergy.2019.02.019 · Cited by 294
Siegelman, R. L., Milner, P. J., Kim, E. J., Weston, S. C., & Long, J. R. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00505f · Cited by 203
Metadata
- Authors
- Heldebrant, D. J., Koech, P. K., Glezakou, V.-A., Rousseau, R., Malhotra, D., & Cantu, D. C.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-19
- Volume
- 117
- Issue
- 14
- Pages
- 9594-9624
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2658763530
- Cited by
- 416
- References
- 1
- FWCI
- 4.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Heldebrant, D. J., Koech, P. K., Glezakou, V.-A., Rousseau, R., Malhotra, D., & Cantu, D. C. (2017). Water-Lean Solvents for Post-Combustion CO2Capture: Fundamentals, Uncertainties, Opportunities, and Outlook. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.6b00768
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