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Water-Lean Solvents for Post-Combustion CO2Capture: Fundamentals, Uncertainties, Opportunities, and Outlook

Heldebrant, David J., Koech, Phillip K., Glezakou, Vassiliki-Alexandra, Rousseau, Roger, Malhotra, Deepika, Cantu, David C.·2017·Chemical Reviews

Abstract

This review is designed to foster the discussion regarding the viability of postcombustion CO 2 capture by water-lean solvents, by separating fact from fiction for both skeptics and advocates. We highlight the unique physical and thermodynamic properties of notable water-lean solvents, with a discussion of how such properties could translate to efficiency gains compared to aqueous amines. The scope of this review ranges from the purely fundamental molecular-level processes that govern solvent behavior to bench-scale testing, through process engineering and projections of process performance and cost. Key discussions of higher than expected CO 2 mass transfer, water tolerance, and compatibility with current infrastructure are presented along with current limitations and suggested areas where further solvent development is needed. We conclude with an outlook of the status of the field and assess the viability of water-lean solvents for postcombustion CO 2 capture.

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Metadata

Authors
Heldebrant, D. J., Koech, P. K., Glezakou, V.-A., Rousseau, R., Malhotra, D., & Cantu, D. C.
Venue
Chemical Reviews
Published
2017-06-19
Volume
117
Issue
14
Pages
9594-9624
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
OpenAlex
W2658763530
Cited by
416
References
1
FWCI
4.24
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Water-Lean Solvents for Post-Combustion CO2Capture: Fundamentals, Uncertainties, Opportunities, and Outlook. https://app.cochat.ai/papers/10.1021/acs.chemrev.6b00768
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Heldebrant, D. J., Koech, P. K., Glezakou, V.-A., Rousseau, R., Malhotra, D., & Cantu, D. C. (2017). Water-Lean Solvents for Post-Combustion CO2Capture: Fundamentals, Uncertainties, Opportunities, and Outlook. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.6b00768

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