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Ionic-Liquid-Based CO2 Capture Systems: Structure, Interaction and Process

Open access
Zeng, Shaojuan, Zhang, Xiangping, Bai, Lu, Zhang, Xiaochun, Wang, Hui, Wang, Jianji, Bao, Di, Li, Mengdie, Liu, Xinyan, Zhang, Suojiang·2017·Chemical Reviews

Abstract

The inherent structure tunability, good affinity with CO 2, and nonvolatility of ionic liquids (ILs) drive their exploration and exploitation in CO 2 separation field, and has attracted remarkable interest from both industries and academia. The aim of this Review is to give a detailed overview on the recent advances on IL-based materials, including pure ILs, IL-based solvents, and IL-based membranes for CO 2 capture and separation from the viewpoint of molecule to engineering. The effects of anions, cations and functional groups on CO 2 solubility and selectivity of ILs, as well as the studies on degradability of ILs are reviewed, and the recent developments on functionalized ILs, IL-based solvents, and IL-based membranes are also discussed. CO 2 separation mechanism with IL-based solvents and IL-based membranes are explained by combining molecular simulation and experimental characterization. Taking into consideration of the applications and industrialization, the recent achievements and developments on the transport properties of IL fluids and the process design of IL-based processes are highlighted. Finally, the future research challenges and perspectives of the commercialization of CO 2 capture and separation with IL-based materials are posed.

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Metadata

Authors
Zeng, S., Zhang, X., Bai, L., Zhang, X., Wang, H., Wang, J., Bao, D., Li, M., Liu, X., & Zhang, S.
Venue
Chemical Reviews
Published
2017-07-07
Volume
117
Issue
14
Pages
9625-9673
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
OpenAlex
W2725074710
Cited by
1,000
References
4
FWCI
12.76
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Ionic-Liquid-Based CO2 Capture Systems: Structure, Interaction and Process. https://app.cochat.ai/papers/10.1021/acs.chemrev.7b00072
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Zeng, S., Zhang, X., Bai, L., Zhang, X., Wang, H., Wang, J., Bao, D., Li, M., Liu, X., & Zhang, S. (2017). Ionic-Liquid-Based CO2 Capture Systems: Structure, Interaction and Process. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.7b00072

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